Redox Shuttles for Overcharge Protection of Lithium-Ion Battery

2013 ◽  
Vol 45 (29) ◽  
pp. 57-66 ◽  
Author(s):  
L. Zhang ◽  
Z. Zhang ◽  
K. Amine
Keyword(s):  
Lithium Ion Battery ◽  
Lithium Ion ◽  
Redox Shuttles ◽  
Overcharge Protection

Overcharge protection of lithium-ion batteries with phenothiazine redox shuttles

2021 ◽  
Author(s):  
Susan A. Odom
Keyword(s):  
Lithium Ion Batteries ◽  
Lithium Ion ◽  
Li Ion Batteries ◽  
Phenothiazine Derivatives ◽  
Redox Shuttles ◽  
Li Ion ◽  
Overcharge Protection

Overcharge protection of Li-ion batteries with a variety of phenothiazine derivatives.

Redox Shuttles with Axisymmetric Scaffold for Overcharge Protection of Lithium-Ion Batteries

2016 ◽  
Vol 6 (19) ◽  
pp. 1600795 ◽  
Author(s):  
Wei Weng ◽  
Jinhua Huang ◽  
Ilya A. Shkrob ◽  
Lu Zhang ◽  
Zhengcheng Zhang
Keyword(s):  
Lithium Ion Batteries ◽  
Lithium Ion ◽  
Redox Shuttles ◽  
Overcharge Protection

Lithium Borate Cluster Salts as Redox Shuttles for Overcharge Protection of Lithium-Ion Cells

2010 ◽  
Vol 13 (4) ◽  
pp. A39 ◽  
Author(s):  
Zonghai Chen ◽  
Jun Liu ◽  
A. N. Jansen ◽  
G. GirishKumar ◽  
Bill Casteel ◽  
...  
Keyword(s):  
Lithium Ion ◽  
Lithium Borate ◽  
Lithium Ion Cells ◽  
Redox Shuttles ◽  
Borate Cluster ◽  
Overcharge Protection

On the Stability and Reactivity of Redox Shuttles in Their Neutral and Radical Cation Forms

2015 ◽  
Vol 1740 ◽  
Author(s):  
Susan A. Odom ◽  
Matthew Casselman ◽  
Aman Preet Kaur ◽  
Selin Ergun ◽  
Naijao Zhang
Keyword(s):  
Lithium Ion Batteries ◽  
Radical Cation ◽  
Electrode Materials ◽  
Lithium Ion ◽  
Radical Cations ◽  
Top Performers ◽  
Redox Shuttles ◽  
Redox Shuttle ◽  
The Stability ◽  
Overcharge Protection

ABSTRACTThe performance of aromatic compounds as redox shuttles for overcharge protection in lithium-ion batteries is quite variable and is often difficult to predict. Redox shuttles may decompose in battery electrolyte in their neutral and radical cation forms, both of which are present during overcharge protection. While hundreds of compounds have been evaluated as redox shuttle candidates and a few have stood out as top performers, the reasons for increased stability over similar candidates with slightly different structures is often unclear, and the exploration of decomposition of redox shuttles has been severely limited, restricting our ability to design improved versions of redox shuttles that do not suffer from the same reactions in lithium-ion batteries. To better understand the stability and reactivity of redox shuttles (also relevant to the improvement of positive electrode materials in non-aqueous redox flow batteries) our research has focused on measuring the stability of neutral and oxidized forms of redox shuttle candidates as well as using a variety of spectroscopic methods to analyze the byproducts of decomposition, both from radical cations generated in model solvents and electrolytes from postmortem analysis of failed batteries.

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