Since the middle of last century it has been known that the alloys, obtained by melting together two or more metals, are conglomerates of small crystals. As it is impossible to study them under the polarizing microscope because of their high absorbing power for light, and as they are seldom obtained in crystals with faces sufficiently well developed to allow a measurement of their angles, our crystallographic knowledge has been, until recently, extremely small. When, therefore, the X-ray methods came to the assistance of the metallurgist they were sure of a welcome. In 1922, Bain, using the powder-photograph method of Debye and Hull, carried out some very important pioneering work. In 1924, Owen and Preston, of the National Physical Laboratory, working in conjunction with Rosenhain studied the Cu-Al and Cu-Zn systems. They used a powder method with an ionization spectrometer. Their work marked a great advance, on account of the precision of their measurements and their detailed description of the preparation of the samples of alloys. At the same time Westgren and Phragmen, working in Stockholm with a photographic method, studied independently the same systems as Owen and Preston, and obtained results of equal precision. They extended the work in certain directions by making a more thorough investigation of single crystals. They have now undertaken an extensive research on several alloys and on steels.