Rate of siderite precipitation in Lake Nyos, Cameroon

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1990 ◽  
Vol 346 (6282) ◽  
pp. 322-323 ◽  
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YUKIHIRO NOJIRI ◽  
MlNORU KUSAKABE ◽  
JUN-ICHI HlRABAYASHI ◽  
HIROAKI SATO ◽  
YUJI SANO ◽  
...  
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Geology ◽  
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Magdalena Goryl ◽  
Barbara Kremer ◽  
Beata Marciniak-Maliszewska ◽  
Leszek Marynowski ◽  
...  

Abstract Ediacaran siderite-bearing sedimentary rocks from the western part of the East European craton exhibit features typical of redoximorphic paleosols, including pedogenic siderite (e.g., sphaerosiderite) with uniform and negative δ18O and highly variable δ13C values. The siderite precipitated in water-logged soils in a hot and humid climate, and represents a rare example of pedogenic siderite formed before the rise of vascular plants. Morphology of soil microorganisms was preserved in three dimensions due to the early siderite precipitation. These are mainly filamentous and tube-like threads, which might belong to cyanobacteria or fungi, and spherical structures resembling green algae. This microbial life fostered development of strongly reducing soils in tropical wetlands on the Baltica paleocontinent. The Ediacaran sediments of the western East European craton, traditionally regarded as marine, are reinterpreted as containing sections affected by freshwater conditions, documenting the presence of microbial life on the Ediacaran land.


1990 ◽  
Vol 127 (2) ◽  
pp. 169-176 ◽  
Author(s):  
A. U. Gehring

AbstractBerthierine, siderite and pyrite are the major ferriferous phases in the Northampton ironstone (NIS). Mineralogical and chemical data suggest a formation of these phases in a diagenetic marine environment changing from post-oxic to sulphidic conditions. Berthierine was formed first when the Fe2+ activity in the diagenetic system increased. Later, this phase was partially replaced by siderite and/or pyrite. A second stage of the diagenetic development in the NIS with increasing CO2 partial pressure (PCO2 ) is documented by siderite. The isotopic composition (δ18O mean value: –1.7‰PDB; δ13C mean value: –8.6‰PDB) points to siderite precipitation from a marine porewater environment with a microbial CO2 source. The shift from post-oxic to sulphidic conditions is indicated by the occurrence of pyrite and can be considered as a final stage. The diagenetic processes in the marine environment and the formation of the ferriferous phases were stopped by the influx of brackish or fresh water when the Midland Shelf turned estuarine.


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