Magnetic Properties of Filled Skutterudite Phosphides with Heavy Lanthanides Synthesized under High Pressure

2008 ◽  
Vol 77 (Suppl.A) ◽  
pp. 135-141 ◽  
Author(s):  
Chihiro Sekine ◽  
Hirotoshi Ando ◽  
Yohei Sugiuchi ◽  
Ichimin Shirotani ◽  
Kazuyuki Matsuhira ◽  
...  
2019 ◽  
Vol 289 ◽  
pp. 85-92
Author(s):  
Chihiro Sekine ◽  
Toshihide Osanai ◽  
Hariharan Ponmani ◽  
Atachariya Phuangyod ◽  
Yukihiro Kawamura ◽  
...  

We have succeeded in synthesizing new arsenic-based filled skutterudite compounds CaFe4As12and BaOs4As12under high pressure. These compounds have lattice constants of 8.3288 and 8.5809 Å, respectively. The magnetic properties of CaFe4As12and BaOs4As12have been studied by means of electrical resistivity, magnetic susceptibility and magnetization measurements. The electrical resistivity and magnetic measurements indicate that CaFe4As12is a nearly ferromagnetic metal with spin fluctuations of Fe 3delectrons and BaOs4As12is a new superconductor with a transition temperature around 3 K.


ChemInform ◽  
2007 ◽  
Vol 38 (11) ◽  
Author(s):  
Ichimin Shirotani ◽  
Keiki Takeda ◽  
Chihiro Sekine ◽  
Junichi Hayashi ◽  
Ryusuke Nakada ◽  
...  

2000 ◽  
Vol 62 (17) ◽  
pp. 11581-11584 ◽  
Author(s):  
C. Sekine ◽  
T. Uchiumi ◽  
I. Shirotani ◽  
K. Matsuhira ◽  
T. Sakakibara ◽  
...  

Crystals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 378
Author(s):  
Li Zhao ◽  
Zhiwei Hu ◽  
Hanjie Guo ◽  
Christoph Geibel ◽  
Hong-Ji Lin ◽  
...  

We report on the synthesis and physical properties of cm-sized CoGeO3 single crystals grown in a high pressure mirror furnace at pressures of 80 bar. Direction dependent magnetic susceptibility measurements on our single crystals reveal highly anisotropic magnetic properties that we attribute to the impact of strong single ion anisotropy appearing in this system with TN∼33.5 K. Furthermore, we observe effective magnetic moments that are exceeding the spin only values of the Co ions, which reveals the presence of sizable orbital moments in CoGeO3.


1999 ◽  
Vol 46 (9) ◽  
pp. 1014-1019
Author(s):  
Takashi Saito ◽  
Masaki Azuma ◽  
Mikio Takano ◽  
Zenji Hiroi ◽  
Yasuo Narumi ◽  
...  

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