On the Electronic States of the Doubly-charged Negative Ions of Oxygen in Oxide Crystals

1952 ◽  
Vol 7 (3) ◽  
pp. 261-263 ◽  
Author(s):  
Jiro Yamashita ◽  
Masao Kojima
Author(s):  
John H. D. Eland ◽  
Raimund Feifel

Double ionisation of the triatomic molecules presented in this chapter shows an added degree of complexity. Besides potentially having many more electrons, they have three vibrational degrees of freedom (three normal modes) instead of the single one in a diatomic molecule. For asymmetric and bent triatomic molecules multiple modes can be excited, so the spectral bands may be congested in all forms of electronic spectra, including double ionisation. Double photoionisation spectra of H2O, H2S, HCN, CO2, N2O, OCS, CS2, BrCN, ICN, HgCl2, NO2, and SO2 are presented with analysis to identify the electronic states of the doubly charged ions. The order of the molecules in this chapter is set first by the number of valence electrons, then by the molecular weight.


2017 ◽  
Vol 23 (49) ◽  
pp. 11752-11756 ◽  
Author(s):  
Anna Troiani ◽  
Marzio Rosi ◽  
Stefania Garzoli ◽  
Chiara Salvitti ◽  
Giulia de Petris

1998 ◽  
Vol 81 (24) ◽  
pp. 5302-5305 ◽  
Author(s):  
H. B. Pedersen ◽  
N. Djurić ◽  
M. J. Jensen ◽  
D. Kella ◽  
C. P. Safvan ◽  
...  
Keyword(s):  

1982 ◽  
Vol 26 (1) ◽  
pp. 654-657 ◽  
Author(s):  
David Spence ◽  
W. A. Chupka ◽  
C. M. Stevens

Nature ◽  
1966 ◽  
Vol 212 (5069) ◽  
pp. 1453-1453 ◽  
Author(s):  
J. H. FREMLIN
Keyword(s):  

2003 ◽  
Vol 17 (10) ◽  
pp. 2023-2034 ◽  
Author(s):  
Z. AN ◽  
C. Q. WU

Within a tight-binding Su–Schrieffer–Heeger model, the elementary excitations and optical absorption of a polyacene chain are investigated. The polyacene chain composed of a number of aromatic rings is considered as two strongly coupled polyacetylene chains with an open boundary condition. First of all we found an interchain-coupled neutral soliton in a pristine chain as a consequence of odd-number sites in each chain. There are two localized electronic states accompanying the soliton and appearing in the conduction and valence bands, respectively. Moreover, an injected electron or hole will induce a polaron-like deformation mixed with the interchain soliton, while two extra electrons or holes will result in three separate solitons, among which one is doubly charged and other two are neutral. The optical absorption due to these elementary excitations are obtained.


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