A New Method of Calculation of Dipole Moment and Relaxation Time for Dilute Solutions at Microwave Frequency

1984 ◽  
Vol 53 (2) ◽  
pp. 802-806 ◽  
Author(s):  
G. K. Johri
1967 ◽  
Vol 45 (5) ◽  
pp. 1617-1620
Author(s):  
G. P. Srivastava ◽  
P. C. Mathur

The relaxation time and dipole moment of cis-dichloroethylene has been determined in the X-band microwave-frequency region from its dilute solutions in a nonpolar solvent. The dielectric loss tangent δ is found to vary linearly with concentration only for very dilute solutions.


2015 ◽  
Vol 70 (7) ◽  
pp. 507-512
Author(s):  
A. Mushtaq Ahmed Khan ◽  
M. Subramanian

AbstractThe molecular structure and molecular forces in liquids and solutions, in particular, have been investigated by dielectric relaxation studies. The nature and strength of the molecular interactions have been established as the main cause for the chemical behaviour of compounds. The dielectric behaviour of dimethyl phthalate with heptanol in benzene solution has been studied at a microwave frequency of 9.36 GHz at different temperatures 303, 308, and 313 K. Different dielectric quantities such as dielectric constant (ε′), dielectric loss (ε″), static dielectric constant (ε0), and dielectric constant at optical frequency (ε∞) have been determined. The relaxation time τ has been calculated by both Higasi’s method and Cole–Cole method. The dielectric relaxation process can be treated as a rate process just like the viscous flow process. The complex system investigated shows the maximum relaxation time values at high temperatures by both Higasi’s method and Cole–Cole method. The molar free energies of activation of dipole moment (ΔFτ) and viscous force (ΔFη) have also been reported. The excess dipole moment is also determined. The excess dipole moment is a qualitative index for the presence of a hydrogen bond in the ternary system. The value of Δμ obtained in our study indicates the presence of hydrogen bonds between the components of the mixture. The system investigated shows that the relaxation time value increases with the increase in the concentration of solute.


2005 ◽  
Author(s):  
Artyom M. Grigoryan ◽  
Veerabhadra S. Bhamidipati ◽  
Srikrishna Alla

1983 ◽  
Vol 26 (2) ◽  
pp. 77-84 ◽  
Author(s):  
S.M. Khameshara ◽  
M.S. Kavadia ◽  
M.S. Lodha ◽  
D.C. Mathur ◽  
V.K. Vaidya

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