Off-Centre Instability of Cu+ Ions in Alkali Chlorides Due to a Charge-Transfer Excitation

1982 ◽  
Vol 51 (3) ◽  
pp. 898-905 ◽  
Author(s):  
Shin-ichiro Nagasaka
Keyword(s):  
Charge Transfer ◽  
Charge Transfer Excitation ◽  
A Charge ◽  
Alkali Chlorides ◽  
Cu Ions

Polarization and momentum dependence of a charge-transfer excitation inNd2CuO4

2000 ◽  
Vol 61 (3) ◽  
pp. 1836-1840 ◽  
Author(s):  
K. Hämäläinen ◽  
J. P. Hill ◽  
S. Huotari ◽  
C.-C. Kao ◽  
L. E. Berman ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Momentum Dependence ◽  
Charge Transfer Excitation ◽  
A Charge

Extension of the spectral responsivity of the photocurrent in solution-processed small molecule composite via a charge transfer excitation

2011 ◽  
Vol 99 (16) ◽  
pp. 163306 ◽  
Author(s):  
Gerardo Hernandez-Sosa ◽  
Minghong Tong ◽  
Nelson E. Coates ◽  
Sebastian Valouch ◽  
Daniel Moses
Keyword(s):  
Charge Transfer ◽  
Small Molecule ◽  
Spectral Responsivity ◽  
Solution Processed ◽  
Charge Transfer Excitation ◽  
A Charge

Determination of Epsilon Aminocaproic Acid Based on Charge Transfer Complexation with p-Nitrophenlol by Spectrophotometry

2020 ◽  
Vol 16 ◽  
Author(s):  
Sheng-Yun Li ◽  
Fang Tian
Keyword(s):  
Charge Transfer ◽  
Aminocaproic Acid ◽  
Concentration Limit ◽  
Official Method ◽  
Good Precision ◽  
Pharmaceutical Dosage Forms ◽  
Relative Standard ◽  
A Charge ◽  
Epsilon Aminocaproic Acid

: A spectrophotometry was investigated for the determination of epsilon aminocaproic acid (EACA) with p-nitrophenol (PNP). The method was based on a charge transfer (CT) complexation of this drug as n-electron donor with π-acceptor PNP. Experiment indicated that the CT complexation was carried out at room temperature for 10 minutes in dimethyl sulfoxide solvent. The spectrum obtained for EACA/PNP system showed the maximum absorption band at wavelength of 425 nm. The stoichiometry of the CT complex was found to be 1:1 ratio by Job’s method between the donor and the acceptor. Different variables affecting the complexation were carefully studied and optimized. At the optimum reaction conditions, Beer’s law was obeyed in a concentration limit of 1～6 µg mL-1. The relative standard deviation was less than 2.9%. The apparent molar absoptivity was determined to be 1.86×104 L mol-1cm-1 at 425 nm. The CT complexation was also confirmed by both FTIR and 1H NMR measurements. The thermodynamic properties and reaction mechanism of the CT complexation have been discussed. The developed method could be applied successfully for the determination of the studied compound in its pharmaceutical dosage forms with a good precision and accuracy compared to official method as revealed by t- and F-tests.

Fluorescence Quenching of Aminodiphenylamines with Chloromethanes

2002 ◽  
Vol 67 (8) ◽  
pp. 1154-1164 ◽  
Author(s):  
Nachiappan Radha ◽  
Meenakshisundaram Swaminathan
Keyword(s):  
Charge Transfer ◽  
Fluorescence Quenching ◽  
Ground State ◽  
Rate Constants ◽  
Quenching Mechanism ◽  
Quenching Rate ◽  
Charge Transfer Interaction ◽  
Electronically Excited ◽  
A Charge

The fluorescence quenching of 2-aminodiphenylamine (2ADPA), 4-aminodiphenylamine (4ADPA) and 4,4'-diaminodiphenylamine (DADPA) with tetrachloromethane, chloroform and dichloromethane have been studied in hexane, dioxane, acetonitrile and methanol as solvents. The quenching rate constants for the process have also been obtained by measuring the lifetimes of the fluorophores. The quenching was found to be dynamic in all cases. For 2ADPA and 4ADPA, the quenching rate constants of CCl4 and CHCl3 depend on the viscosity, whereas in the case of CH2Cl2, kq depends on polarity. The quenching rate constants for DADPA with CCl4 are viscosity-dependent but the quenching with CHCl3 and CH2Cl2 depends on the polarity of the solvents. From the results, the quenching mechanism is explained by the formation of a non-emissive complex involving a charge-transfer interaction between the electronically excited fluorophores and ground-state chloromethanes.

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