Molecular Weight Dependences of Critical Amplitudes in Polymer Solutions

1981 ◽  
Vol 50 (6) ◽  
pp. 1817-1818 ◽  
Author(s):  
Kenji Shinozaki ◽  
Takuhei Nose
Keyword(s):  
Molecular Weight ◽  
Polymer Solutions ◽  
Critical Amplitudes

Molecular weight scaling in critical polymer solutions

1999 ◽  
Vol 48 (4) ◽  
pp. 372-377 ◽  
Author(s):  
Y. B Melnichenko ◽  
G. D Wignall ◽  
W. A. Van Hook
Keyword(s):  
Molecular Weight ◽  
Polymer Solutions ◽  
Weight Scaling

scholarly journals Evaporation-induced Rayleigh–Taylor instabilities in polymer solutions

2020 ◽  
Vol 378 (2174) ◽  
pp. 20190533 ◽  
Author(s):  
E. J. Mossige ◽  
V. Chandran Suja ◽  
M. Islamov ◽  
S. F. Wheeler ◽  
Gerald. G. Fuller
Keyword(s):  
Molecular Weight ◽  
Time Scales ◽  
Polymer Solutions ◽  
Critical Concentration ◽  
Polymer Concentration ◽  
Onset Time ◽  
Dense Layer ◽  
Strong Concentration ◽  
Aqueous Polymer ◽  
Gravitational Instabilities

Understanding the mechanics of detrimental convective instabilities in drying polymer solutions is crucial in many applications such as the production of film coatings. It is well known that solvent evaporation in polymer solutions can lead to Rayleigh-Bénard or Marangoni-type instabilities. Here, we reveal another mechanism, namely that evaporation can cause the interface to display Rayleigh–Taylor instabilities due to the build-up of a dense layer at the air–liquid interface. We study experimentally the onset time ( t p ) of the instability as a function of the macroscopic properties of aqueous polymer solutions, which we tune by varying the polymer concentration ( c 0 ), molecular weight and polymer type. In dilute solutions, t p shows two limiting behaviours depending on the polymer diffusivity. For high diffusivity polymers (low molecular weight), the pluming time scales as c 0 − 2 / 3 . This result agrees with previous studies on gravitational instabilities in miscible systems where diffusion stabilizes the system. On the other hand, in low diffusivity polymers the pluming time scales as c 0 − 1 . The stabilizing effect of an effective interfacial tension, similar to those in immiscible systems, explains this strong concentration dependence. Above a critical concentration, c ^ , viscosity delays the growth of the instability, allowing time for diffusion to act as the dominant stabilizing mechanism. This results in t p scaling as ( ν / c 0 ) 2/3 . This article is part of the theme issue ‘Stokes at 200 (Part 1)’.

Effects of molecular weight and concentration on flow properties of concentrated polymer solutions

2007 ◽  
Vol 15 (1) ◽  
pp. 381-406 ◽  
Author(s):  
Shigeharu Onogi ◽  
Shigezo Kimura ◽  
Takashi Kato ◽  
Toshiro Masuda ◽  
Nobuyuki Miyanaga
Keyword(s):  
Molecular Weight ◽  
Polymer Solutions ◽  
Flow Properties
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