Studies on Dielectric Properties of Binary Mixtures of Butanols in Nonpolar Solvents–Linear Correlation Factor, Excess Molar Polarization and Excess Free Energy

1986 ◽  
Vol 25 (Part 1, No. 2) ◽  
pp. 209-214 ◽  
Author(s):  
B. B. Swain ◽  
G. S. Ray
Keyword(s):  
Free Energy ◽  
Dielectric Properties ◽  
Binary Mixtures ◽  
Linear Correlation ◽  
Excess Free Energy ◽  
Correlation Factor ◽  
Nonpolar Solvents ◽  
Molar Polarization

scholarly journals Dielectric properties of benzylamine in 1,2,6-hexanetriol mixture using time domain reflectometry technique

2016 ◽  
Vol 06 (04) ◽  
pp. 1650034
Author(s):  
M. B. Swami ◽  
P. G. Hudge ◽  
V. P. Pawar
Keyword(s):  
Dielectric Constant ◽  
Dielectric Properties ◽  
Binary Mixtures ◽  
Time Domain ◽  
Complex Permittivity ◽  
Intramolecular Interaction ◽  
Correlation Factor ◽  
Time Domain Reflectometry ◽  
Least Square ◽  
Kirkwood Correlation Factor

The dielectric properties of binary mixtures of benzylamine-1,2,6-hexantriol mixtures at different volume fractions of 1,2,6-hexanetriol have been measured using Time Domain Reflectometry (TDR) technique in the frequency range of 10 MHz to 30 GHz. Complex permittivity spectra were fitted using Havriliak–Negami equation. By using least square fit method the dielectric parameters such as static dielectric constant ([Formula: see text]), dielectric constant at high frequency ([Formula: see text]), relaxation time [Formula: see text] (ps) and relaxation distribution parameter ([Formula: see text]) were extracted from complex permittivity spectra at 25[Formula: see text]C. The intramolecular interaction of different molecules has been discussed using the Kirkwood correlation factor, Bruggeman factor. The Kirkwood correlation factor ([Formula: see text]) and effective Kirkwood correlation factor ([Formula: see text]) indicate the dipole ordering of the binary mixtures.

Evaluation of Excess Correlation Factor in Dilute Binary Mixtures of Tri-N-Butyl Phosphate (TBP) in Nonpolar Solvents

1996 ◽  
Vol 32 (4) ◽  
pp. 211-217 ◽  
Author(s):  
Suparna Ray ◽  
Biswadas Mohanty ◽  
Sandip Kumar Ray ◽  
Gouri Sankar Roy
Keyword(s):  
Binary Mixtures ◽  
Correlation Factor ◽  
Nonpolar Solvents

Evaluation of linear correlation factor in dilute binary mixtures: Alcohols and amines with non-polar solvents

1993 ◽  
Vol 55 ◽  
pp. 137-143 ◽  
Author(s):  
S. Tripathy ◽  
S.K. Dash ◽  
K. Garabadu ◽  
G.S. Ray ◽  
B.B. Swain
Keyword(s):  
Binary Mixtures ◽  
Linear Correlation ◽  
Correlation Factor ◽  
Polar Solvents

Characterization of Textured Aluminum Lines and Modelling of Stress Voiding

1994 ◽  
Vol 343 ◽  
Author(s):  
S.C. Wardle ◽  
B.L. Adams ◽  
C.S. Nichols ◽  
D.A. Smith
Keyword(s):  
Free Energy ◽  
Excess Free Energy ◽  
Mean Field ◽  
High Energy ◽  
Polycrystalline Structure ◽  
Field Approach ◽  
Bamboo Structure ◽  
Automated Technique ◽  
Theory And Modeling

ABSTRACTIt is well known from studies of individual interfaces that grain boundaries exhibit a spectrum of properties because their structure is misorientation dependent. Usually this variability is neglected and properties are modeled using a mean field approach. The limitations inherent in this approach can be overcome, in principle, using a combination of experimental techniques, theory and modeling. The bamboo structure of an interconnect is a particularly simple polycrystalline structure that can now be readily characterized experimentally and modeled in the computer. The grain misorientations in a [111] textured aluminum line have been measured using the new automated technique of orientational imaging microscopy. By relating boundary angle to diffusivity the expected stress voiding failure processes can be predicted through the link between misorientation angle, grain boundary excess free energy and diffusivity. Consequently it can be shown that the high energy boundaries are the favored failure sites thermodynamically and kinetically.

Higher Order Conditional Probabilities and Thermodynamics of Binary Molten Alloys

1997 ◽  
Vol 11 (02n03) ◽  
pp. 93-106 ◽  
Author(s):  
O. Akinlade
Keyword(s):  
Free Energy ◽  
Experimental Evidence ◽  
Cluster Model ◽  
Excess Free Energy ◽  
Higher Order ◽  
Thermodynamic Quantities ◽  
Equiatomic Composition ◽  
Conditional Probabilities ◽  
Energy Of Mixing ◽  
Free Energy Of Mixing

The recently introduced four atom cluster model is used to obtain higher order conditional probabilities that describe the atomic correlations in some molten binary alloys. Although the excess free energy of mixing for all the systems studied are almost symmetrical about the equiatomic composition, most other thermodynamic quantities are not and thus, the study enables us to explain the subtle differences in their physical characteristics required to describe the mechanism of the observed strong heterocoordination in Au–Zn or homocoordination in Cu–Ni within the same framework. More importantly, we obtain all calculated quantities for the whole concentration range thus complimenting experimental evidence.

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