Oxometalate- and Soft-Oxometalate-Based Hybrid Materials: From Synthesis to Catalytic Applications

2021 ◽  
pp. 2030002
Author(s):  
Kousik Das ◽  
Soumyajit Roy
Keyword(s):  
Rational Choice ◽  
Catalytic Property ◽  
Hybrid Materials ◽  
Soft Matter ◽  
Organic Ligand ◽  
Structural Flexibility ◽  
Catalytic Applications

Multi-component hybrid materials are intriguing. They have the potential to act as a platform to manifest the properties of their components. In this review, we discuss the catalytic applications of few such hybrids that are based on oxometalates (OMs). Due to the structural flexibility and enormous properties, OMs are unrivaled in the field of catalysis. Thus, here we primarily focus on the synthesis and catalysis of such OM-based hybrids. The present overview shows that it is possible to improve the catalytic property of bare oxometalates and even that of their soft-matter state namely soft-oxometalates (SOMs) through rational choice of organic ligand and oxometalates.

Pt-porous ZnO nanoribbon hybrid materials with enhanced catalytic performances

CrystEngComm ◽  
2015 ◽  
Vol 17 (8) ◽  
pp. 1765-1768 ◽  
Author(s):  
Zhiqiang Cheng ◽  
Mingyue Yu ◽  
Guixia Yang ◽  
Lijuan Kang
Keyword(s):  
Photocatalytic Degradation ◽  
Co Oxidation ◽  
Hybrid Materials ◽  
Catalytic Properties ◽  
Seeded Growth ◽  
Hybrid Nanomaterial ◽  
Growth Method ◽  
Catalytic Applications ◽  
Catalytic Performances

With the help of bio-molecule l-lysine, a seeded growth method has been developed and Pt–ZnO porous nanoribbons have been successfully obtained. For the catalytic applications of CO oxidation and the photocatalytic degradation of MO, the hybrid nanomaterial exhibits remarkably enhanced catalytic properties.

Encapsulation of Lanthanide β-diketone Hybrids in Organic Oligomer Poly(ethylene glycol) 400

2015 ◽  
Vol 1102 ◽  
pp. 125-128
Author(s):  
Hua Ti Li ◽  
Dong Liu ◽  
Ying Li ◽  
Jie Lin Wang ◽  
Xia Wang
Keyword(s):  
Thermal Stability ◽  
Ethylene Glycol ◽  
Hybrid Materials ◽  
Mesoporous Material ◽  
Organic Ligand ◽  
Poly Ethylene Glycol ◽  
Characteristic Emission ◽  
Hybrid Precursor ◽  
Poly Ethylene ◽  
The Eu

The organic ligand 2-Thenoyltrifluoroacetone (TTA) which was selected as molecular bridge for sensitization of europium and terbium ions were modified by 3-(triethoxysilyl)-propylisocyanate (TEPIC) to obtain the hybrid precursor TTA-Si. Then the solution of Eu(NO3)3 and Tb(NO3)3 were added in the presence of tetraethylorthosilicate (TEOS). The binary lanthanide organic/inorganic hybrid material were obtained. The ternary hybrid materials were obtained by adding the solution of Eu(NO3)3 and Tb(NO3)3 and Poly (ethylene glycol) (PEG400). We investigated the thermal stability and luminescence properties of hybrids and found that the ternary hybrid materials exhibit better thermal stability and stronger emission intensity. Furthermore, compared with the binary mesoporous material Eu-(TTA-Si)3 and Tb-(TTA-Si)3, the ternary mesoporous material Eu-(TTA-Si)3-PEG and Tb-(TTA-Si)3-PEG exhibits the characteristic emission of the Eu3+ and Tb3+ ion with a higher luminescence intensity, suggesting that the introduction of PEG is of benefit for the sensitization of Eu3+ and Tb3+ luminescence, by replacing H2O groups that can quench the luminescence of Eu3+ and Tb3+ ions.

DNA-Based Materials as Chemical Reactors for Synthesis of Metal Nanoparticles1, "Высокомолекулярные соединения. Серия С"

2017 ◽  
pp. 21-32
Author(s):  
Zinchenko Anatoly ◽  
G. Sergeyev Vladimir
Keyword(s):  
Hybrid Materials ◽  
Recent Progress ◽  
Chemical Reactors ◽  
Advantages And Disadvantages ◽  
Inorganic Nanomaterials ◽  
Catalytic Applications

In this mini-review we highlight a recent progress in preparation of DNA-based matrices that can be used as reactors for templating of inorganic nanomaterials and, in particular, highlight catalytic applications of such hybrid materials. We also discuss advantages and disadvantages of DNA utilization as a material and outline prospects of DNA-based technologies in future.

Metal Halide/N‐Donor Organic Ligand Hybrid Materials with Confined Energy Gaps and Emissions

2008 ◽  
Vol 2008 (19) ◽  
pp. 3040-3045 ◽  
Author(s):  
Wei Wang ◽  
Juan Qiao ◽  
Guifang Dong ◽  
Liduo Wang ◽  
Lian Duan ◽  
...  
Keyword(s):  
Hybrid Materials ◽  
Organic Ligand ◽  
Metal Halide ◽  
Energy Gaps

Enhanced Room-Temperature Phosphorescence of an Organic Ligand in 3D Hybrid Materials Assisted by Adjacent Halogen Atom

2020 ◽  
Vol 59 (2) ◽  
pp. 972-975 ◽  
Author(s):  
Ying Mu ◽  
Jun-Qing Wang ◽  
Song-De Han ◽  
Jie Pan ◽  
Jin-Hua Li ◽  
...  
Keyword(s):  
Hybrid Materials ◽  
Room Temperature ◽  
Halogen Atom ◽  
Organic Ligand ◽  
Room Temperature Phosphorescence
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