A Model of Bond-and-Band for the Behavior of Nitrides

1997 ◽  
Vol 11 (23) ◽  
pp. 1021-1029 ◽  
Author(s):  
Chang Q. Sun

A bond-and-band model is developed to incorporate the chemical bond and the energy band of nitrides. It is suggested that the symmetrical difference of the tetrahedral bond-structure and the similarity in the energy-band determine the performance of these compounds. The presence of bonding, nonbonding lone-pair and the lone-pair-induced antibonding features are of key importance to these materials. Well acclaimed by existing evidence, this model provided preliminary understanding of the physical properties of some nitrides and oxides and particularly, some insight into the origins of the N-enhanced magnetization, the blue-shift in nitride and oxide light emitting as well as the ultrahard and super elastic materials.

2021 ◽  
Vol 502 (3) ◽  
pp. 3294-3311
Author(s):  
Yuanming Wang ◽  
Artem Tuntsov ◽  
Tara Murphy ◽  
Emil Lenc ◽  
Mark Walker ◽  
...  

ABSTRACT We present the results from an Australian Square Kilometre Array Pathfinder search for radio variables on timescales of hours. We conducted an untargeted search over a 30 deg2 field, with multiple 10-h observations separated by days to months, at a central frequency of 945 MHz. We discovered six rapid scintillators from 15-min model-subtracted images with sensitivity of $\sim\! 200\, \mu$Jy/beam; two of them are extreme intra-hour variables with modulation indices up to $\sim 40{{\ \rm per\ cent}}$ and timescales as short as tens of minutes. Five of the variables are in a linear arrangement on the sky with angular width ∼1 arcmin and length ∼2 degrees, revealing the existence of a huge plasma filament in front of them. We derived kinematic models of this plasma from the annual modulation of the scintillation rate of our sources, and we estimated its likely physical properties: a distance of ∼4 pc and length of ∼0.1 pc. The characteristics we observe for the scattering screen are incompatible with published suggestions for the origin of intra-hour variability leading us to propose a new picture in which the underlying phenomenon is a cold tidal stream. This is the first time that multiple scintillators have been detected behind the same plasma screen, giving direct insight into the geometry of the scattering medium responsible for enhanced scintillation.


1987 ◽  
Vol 40 (12) ◽  
pp. 1923 ◽  
Author(s):  
ID Rae ◽  
ID Rae ◽  
A Staffa ◽  
A Staffa ◽  
AC Diz ◽  
...  

In order to obtain a deeper insight into the title effect, several compounds with an F atom very close to a C-H of a nearby functional group were synthesized and the relevant couplings measured. The most conspicuous case was that of 8-fluoro-2-hydroxynaphthalene-1-carbaldehyde where a close proximity between the F and H atoms is the result of fluorine-oxygen repulsion and the formation of an intramolecular hydrogen bond between the hydroxyl and carbonyl groups. The experimental four-bond J(F,CHO) coupling is 26.2 Hz. A compound very similar to this one, but without the OH group, was chosen on which to perform a polarization propagator analysis of the through-space (TS) coupling pathways, at the RPA-INDO level. The expression for the TS coupling in terms of the projected polarization propagator and perturbators was numerically analysed. It is found that this coupling is completely dominated by a TS component of the Fermi contact (FC) term, the main features of which are: ( i ) It decays exponentially with the F-H distance; (ii) Its main contribution comes from an electron excitation involving the F lone-pair, the C-H bond of the CHO moiety and its corresponding antibonding orbital;(iii) The π-type lone-pair does not contribute to the TS coupling pathway of the FC term.


Photonics ◽  
2021 ◽  
Vol 8 (2) ◽  
pp. 42
Author(s):  
Jie Zhao ◽  
Weijiang Li ◽  
Lulu Wang ◽  
Xuecheng Wei ◽  
Junxi Wang ◽  
...  

We fabricated InGaN/GaN nanorod light emitting diode (LED) on (-201) β-Ga2O3 substrate via the SiO2 nanosphere lithography and dry-etching techniques. The InGaN/GaN nanorod LED grown on β-Ga2O3 can effectively suppress quantum confined Stark effect (QCSE) compared to planar LED on account of the strain relaxation. With the enhancement of excitation power density, the photoluminescence (PL) peak shows a large blue-shift for the planar LED, while for the nanorod LED, the peak position shift is small. Furthermore, the simulations also show that the light extraction efficiency (LEE) of the nanorod LED is approximately seven times as high as that of the planar LED. Obviously, the InGaN/GaN/β-Ga2O3 nanorod LED is conducive to improving the optical performance relative to planar LED, and the present work may lay the groundwork for future development of the GaN-based vertical light emitting diodes (VLEDs) on β-Ga2O3 substrate.


Author(s):  
Shaoqiang Dong ◽  
Zhen Li

In last decades, open-shell organic materials have attracted scientists’ great attention for their new chemical and physical properties, as well as their possible applications in new generation of organic light-emitting...


2021 ◽  
Vol 6 (3) ◽  
pp. 191-198
Author(s):  
Hao-Long Chen ◽  
Hung-Rung Shih ◽  
Sean Wu ◽  
Yee-Shin Chang

The objective of this paper is to enhance the emission intensity of La0.97Pr0.03VO4 single-phased white light emitting phosphor. The Bi3+ ion-doped La0.97Pr0.03VO4 single-phased white light emitting phosphors are synthesized using a sol-gel method. The structure and photoluminescence properties of (La0.97-yBiy)Pr0.03VO4 (y = 0-0.05) phosphor are also examined. The XRD results show that the structure of La0.97Pr0.03VO4 phosphors with different concentrations of Bi3+ ion doping keeps the monoclinic structure. The SEM results show that the phosphor particles become smoother when the Bi3+ ion is doped. The excitation band for La0.97Pr0.03VO4 phosphor exhibits a blue shift from 320 nm to 308 nm as the Bi3+ ion contents are increased. The maximum emission intensity is achieved for a Bi3+ ion content of 0.5 mol%, which is about 30% greater than that with no Bi3+ ion doped. The CIE chromaticity coordinates are all located in the near white light region for different Bi3+ ion-doped La0.97Pr0.03VO4 phosphors.


Author(s):  
Jiakui Yan ◽  
Bizheng Dong ◽  
Yabo Xu ◽  
Bo Zhao ◽  
Fangming Jin ◽  
...  

In this work, the effects of different ratios of donor/acceptor and spacer host materials on exciplex organic light emitting diodes (OLED) based DMAC-DPS:PO-T2T were explored, an obvious spectral blue-shift and...


2021 ◽  
Author(s):  
Baoying Dai ◽  
Gill M. Biesold ◽  
Meng Zhang ◽  
Haiyang Zou ◽  
Yong Ding ◽  
...  

The piezo-phototronic effect plays an ingenious and robust role in modulating the optoelectronic processes of photocatalysis, solar cells, photodetectors and light-emitting diodes by tuning energy band structures and photoinduced carrier behaviors.


Author(s):  
Norman Herz ◽  
Ervan G. Garrison

Archaeological ceramics refers to products made primarily of clay and containing variable amounts of lithic and other materials as well. The term ceramic is derived from the Greek keramos, which has been translated as "earthenware" or "burned stuff." Ceramics include products that have been fired, primarily pottery but also brick, tile, glass, plaster, and cement as well. Since pottery is by far the most important archaeologically, and the methods of sampling and study are largely applicable to the others, this chapter is devoted primarily to pottery. Pottery then is the general term used here for artifacts made entirely or largely of clay and hardened by heat. Today, a distinction is sometimes made between pottery, applied to lower-quality ceramic wares, and the higher-grade product porcelain. No such distinction will be made here, so the term pottery alone will be used. Raw material that goes into the making of a pot includes primarily clay, but also varying amounts of temper, which is added to make the material more manageable and to help preserve the worked shape of the pot during firing. Of primary interest in ceramic studies are 1. the nature and the source of the raw materials—clays, temper, and slip (applied surface pigment)—and a reconstruction of the working methods of ancient potters; 2. the physical properties of the raw materials, from their preparation as a clay-temper body through their transformations during manufacture into a final ceramic product; 3. the nature of the chemical and mineral reactions that take place during firing as a clue to the technology available to the potter; and 4. the uses, provenance, and trade of the wares produced. Much of the information needed to answer these questions is available through standard geochemical and petrographic analysis of ceramic artifacts. Insight into the working methods of ancient potters also has been obtained through ethnographic studies of cultures where, because of isolation or conservative traditions or both, ancient methods have been preserved.


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