Adsorption of dissolved nitrogen by forest mineral soils

2009 ◽  
Vol 39 (12) ◽  
pp. 2381-2390 ◽  
Author(s):  
D.N. Kothawala ◽  
T.R. Moore
Keyword(s):  
Soil Properties ◽  
Dissolved Organic Nitrogen ◽  
Organic Nitrogen ◽  
Mineral Soil ◽  
Organic Soil ◽  
Nutrient Sources ◽  
Dissolved Nitrogen ◽  
Soil Solutions ◽  
Mineral Soils ◽  
Similar Soil

Dissolved nitrogen (N) species, including ammonium (NH4+-N), nitrate (NO3–-N), and dissolved organic nitrogen (DON), are important nutrient sources in soils. The mobility of DON and NH4+-N in soil solutions is influenced by abiotic adsorption to mineral soil particle surfaces. We determined relationships between soil properties and their ability to adsorb NH4+-N, NO3–-N, and DON, using batch experiments. A range of 41 mineral horizons was collected from across Canada, including Podzols, Brunisols, Luvisols, Gleysols, and an organic soil. The adsorption of DON and dissolved organic carbon (DOC) were positively correlated (R2 = 0.86), and both were best explained by the amount of iron and aluminum associated with poorly crystalline phases. Adsorption of NH4+-N was strongest in Gleysols and Luvisols, while adsorption of NO3–-N was weak in all soils. A reduction in the DOC:DON ratio was observed for most mineral horizons (89%) after equilibration from an original ratio of 35:1. Mineral horizons with a net desorption of DON had a significantly greater reduction in the final DOC:DON ratios than horizons with a net adsorption of DON. The results from this study found that while similar soil properties could predict DOC and DON adsorption, DON was slightly more mobile than DOC.

scholarly journals Characteristics of Dissolved Organic Nitrogen in the Sediments of Six Water Sources in Taihu Lake, China

2019 ◽  
Vol 16 (6) ◽  
pp. 929 ◽  
Author(s):  
Xiaofan Yang ◽  
Xueyu Wei ◽  
Xiaoping Xu ◽  
Yu Zhang ◽  
Jincheng Li ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Drinking Water ◽  
Dissolved Organic Nitrogen ◽  
Organic Nitrogen ◽  
Taihu Lake ◽  
Water Sources ◽  
Dissolved Nitrogen ◽  
Total Dissolved Nitrogen ◽  
Endogenous Release ◽  
Molecular Weight Fractions

KCl-extractable sediment dissolved organic nitrogen (KS-DON) extracted from sediments near drinking water intakes of six drinking water sources in Taihu Lake in China was partitioned into hydrophobic and hydrophilic fractions and high/low molecular weight fractions. The results showed that the total dissolved nitrogen (TDN) contents of the extracts ranged from 67.78 to 128.27 mg/kg. KS-DON was the main TDN species, accounting for more than 50%, with NH4+-N and NO3−-N averaging 30% and 20%, respectively. The molecular weight fractions of <1 kDa accounted for almost half of KS-DON. Hydrophilic compounds accounted for more than 75% of KS-DON. Three fluorescence peaks were identified: soluble microbial byproducts (A); protein-like substances (B); and humic acid-like substances (C). It is concluded that the KS-DON in Taihu Lake sources has higher bioavailability and higher risk of endogenous release. Ecological dredging and establishment of constructed wetlands are possible measures to reduce the release of endogenous nitrogen.

Effect of boron on clubroot of canola in organic and mineral soils and on residual toxicity to rotational crops

2014 ◽  
Vol 94 (1) ◽  
pp. 109-118 ◽  
Author(s):  
A. Deora ◽  
B. D. Gossen ◽  
S. F. Hwang ◽  
D. Pageau ◽  
R. J. Howard ◽  
...  
Keyword(s):  
Plasmodiophora Brassicae ◽  
Mineral Soil ◽  
Organic Soil ◽  
Field Trials ◽  
Growth And Yield ◽  
Broadcast Application ◽  
Residual Toxicity ◽  
Negative Effect ◽  
Soil Site ◽  
Mineral Soils

Deora, A., Gossen, B. D., Hwang, S. F., Pageau, D., Howard, R. J., Walley, F. and McDonald, M. R. 2014. Effect of boron on clubroot of canola in organic and mineral soils and on residual toxicity to rotational crops. Can. J. Pant Sci. 94: 109–118. Application of boron (B) has been reported to reduce clubroot severity in various Brassica spp., but residual B can have phytotoxic effects on other crops in the rotation. The objective of this study was to test the efficacy of broadcast application of B for clubroot suppression in canola (B. napus) and the effect of residual B on wheat, barley, field pea and canola. Field trials to assess clubroot suppression by B at various rates (1 to 64 kg B ha−1) were conducted in organic (Ontario) and mineral soils (Alberta, Quebec) heavily infested with Plasmodiophora brassicae in 2011 and 2012. Phytotoxicity was not observed in canola until applications rates exceeded 48 kg B ha−1. Boron did not reduce clubroot incidence at any site, irrespective of rate, and only reduced severity at the organic soil site at 6 wk after seeding. There was a small increase in shoot weight and yield of canola with increasing B application rates at the organic soil site. The potential phytotoxicity of residual B (4 to 16 kg B ha−1) was assessed in mineral soils in Ontario and Saskatchewan in 2012. Toxicity symptoms were noted initially in most of the crops, but seedlings recovered quickly and there was no significant reduction in fresh weight at harvest or seed yield of most of the cultivars. The present study indicates that pre-plant broadcast application of B delays clubroot development and increases vegetative growth and yield compared with non-treated plants in organic soil. Also, even high residual rates (16 kg ha−1) of application are unlikely to have a negative effect on crops in rotation in mineral soil. However, the effect of B application on canola yield found in this study was not sufficient to justify application for commercial canola production, even where clubroot is prevalent.

scholarly journals Organic Matter Causes Chemical Pollutant Dissipation Along With Adsorption and Microbial Degradation

2021 ◽  
Vol 9 ◽  
Author(s):  
A. Vilhelmiina Harju ◽  
Ilkka Närhi ◽  
Marja Mattsson ◽  
Kaisa Kerminen ◽  
Merja H. Kontro
Keyword(s):  
Organic Matter ◽  
Microbial Degradation ◽  
Mineral Soil ◽  
Organic Soil ◽  
Organic Soils ◽  
First Response ◽  
Chemical Pollutant ◽  
Mineral Soils ◽  
Soil And Sediment

Views on the entry of organic pollutants into the organic matter (OM) decaying process are divergent, and in part poorly understood. To clarify these interactions, pesticide dissipation was monitored in organic and mineral soils not adapted to contaminants for 241 days; in groundwater sediment slurries adapted to pesticides for 399 days; and in their sterilized counterparts with and without peat (5%) or compost-peat-sand (CPS, 15%) mixture addition. The results showed that simazine, atrazine and terbuthylazine (not sediment slurries) were chemically dissipated in the organic soil, and peat or CPS-amended soils and sediment slurries, but not in the mineral soil or sediment slurries. Hexazinone was chemically dissipated best in the peat amended mineral soil and sediment slurries. In contrast, dichlobenil chemically dissipated in the mineral soil and sediment slurries. The dissipation product 2,6-dichlorobenzamide (BAM) concentrations were lowest in the mineral soil, while dissipation was generally poor regardless of plant-derived OM, only algal agar enhanced its chemical dissipation. Based on sterilized counterparts, only terbutryn appeared to be microbially degraded in the organic soil, i.e., chemical dissipation of pesticides would appear to be utmost important, and could be the first response in the natural cleansing capacity of the environment, during which microbial degradation evolves. Consistent with compound-specific dissipation in the mineral or organic environments, long-term concentrations of pentachloroaniline and hexachlorobenzene were lowest in the mineral-rich soils, while concentrations of dichlorodiphenyltrichloroethane (DTT) and metabolites were lowest in the organic soils of old market gardens. OM amendments changed pesticide dissipation in the mineral soil towards that observed in the organic soil; that is OM accelerated, slowed down or stopped dissipation.

OXYGEN FLUX MEASUREMENTS IN ORGANIC SOIL

1980 ◽  
Vol 60 (4) ◽  
pp. 641-650 ◽  
Author(s):  
JAMES A. CAMPBELL
Keyword(s):  
Applied Voltage ◽  
Mineral Soil ◽  
Organic Soil ◽  
Oxygen Flux ◽  
Organic Soils ◽  
Wide Range ◽  
Effective Voltage ◽  
Flux Measurements ◽  
Mineral Soils ◽  
Almost All

Many measurements of oxygen flux in mineral soils have been reported; however, few such measurements have been made in organic soil. Almost all reported measurements of oxygen flux are at constant applied voltage, despite criticism of this technique, possibly due to the complexity of existing techniques for measuring oxygen flux at effective voltage. Equipment suitable for measuring oxygen flux at applied and effective voltage in organic soil was designed, and simplified techniques were developed and tested. As reported for mineral soils, soil resistance is relatively constant spatially and with depth in individual soils. Limited poisoning of the platinum electrode surface occurred after long periods of time and, contrary to previous assumptions, cannot be detected by erratic readings. Unlike mineral soil, the amperage-voltage slopes are constant over a wide range of organic soils, simplifying the technique for estimating oxygen flux at constant effective volatage. Comparison of simultaneous measurements of oxygen flux at constant and effective voltage indicates that oxygen flux measurements at effective voltage were twice those at applied voltage and strongly correlated (r2 = 0.96, n = 22).

scholarly journals Generalized models to estimate carbon and nitrogen stocks of organic soil layers in Interior Alaska

2019 ◽  
Author(s):  
Kristen Manies ◽  
Mark Waldrop ◽  
Jennifer Harden
Keyword(s):  
Soil Properties ◽  
Land Surface ◽  
Mineral Soil ◽  
Organic Soil ◽  
Stand Age ◽  
Soil Layers ◽  
Carbon And Nitrogen ◽  
Interior Alaska ◽  
C Stocks ◽  
Global Soil

Abstract. Boreal ecosystems comprise about one tenth of the world's land surface and contain over 20 % of the global soil carbon (C) stocks. Boreal soils are unique in that the mineral soil is covered by what can be quite thick layers of organic soil. These organic soil layers, or horizons, can differ in their state of decomposition, source vegetation, and disturbance history. These differences result in varying soil properties (bulk density, C content, and nitrogen (N) content) among soil horizons. Here we summarize these soil properties, as represented by over 3000 samples from Interior Alaska, and examine how soil drainage and stand age affect these attributes. The summary values presented here can be used to gap-fill large datasets when important soil properties were not measured, provide data to initialize process-based models, and validate model results. These data are available at https://doi.org/10.5066/P960N1F9 (Manies, 2019).

scholarly journals The importance of riparian zones on stream carbon and nitrogen export in a temperate, agricultural dominated landscape

2012 ◽  
Vol 9 (6) ◽  
pp. 7465-7497 ◽  
Author(s):  
T. Wohlfart ◽  
J.-F. Exbrayat ◽  
K. Schelde ◽  
B. Christen ◽  
T. Dalgaard ◽  
...  
Keyword(s):  
Organic Carbon ◽  
Dissolved Organic Carbon ◽  
Dissolved Organic Nitrogen ◽  
Organic Nitrogen ◽  
Agricultural Land ◽  
Stream Water ◽  
Soil Types ◽  
Organic Soils ◽  
Dissolved Nitrogen ◽  
Total Dissolved Nitrogen

Abstract. The surrounding landscape of a stream has crucial impacts on the aquatic environment. This study pictures the hydro-biogeochemical situation of the Tyrebaekken creek catchment in central Jutland, Denmark. The intensively managed agricultural landscape is dominated by rotational croplands. One northern and one southern stream run through the catchment before converging to form a second order brook. The small catchments mainly consist of sandy soil types besides organic soils along the riparian zone of the streams. The aim of the study was to characterise the relative influence of soil type and land use on stream water quality. Nine snapshot sampling campaigns were undertaken during the growing season of 2009. On each sampling day, 20 points along the stream were sampled as well as eight drain outlets and two groundwater wells. Total dissolved nitrogen, nitrate, ammonium nitrogen and dissolved organic carbon (DOC) concentrations were measured and dissolved organic nitrogen (DON) was calculated for each grabbed sample. Electro-conductivity, pH and flow velocity were measured during sampling. Statistical analyses showed significant differences between the northern, southern and converged stream parts, especially for nitrate concentrations with average values of 9.6 mg N l−1, 1.4 mg N l−1 and 3.0 mg N l−1, respectively. Furthermore, throughout the sampling period DON concentrations increased from 0.1 mg N l−1 to 2.8 mg N l−1 and from 0.1 mg N l−1 to 0.8 mg N l−1in the northern and southern streams, respectively. This corresponded to a contribution of up to 81% to total dissolved nitrogen. Multiple-linear regression analyses performed between chemical data and landscape charateristics showed a significant negative influence of organic soils on instream N concentrations and corresponding losses in spite of their overall minor share of the agricultural land (12.9%). On the other hand, organic soil frequency was positively correlated to the corresponding dissolved organic carbon concentrations. Croplands also had a significant influence but with weaker correlations. For our case study we conclude that soil types and corresponding biogeochemical properties have a major influence on stream water chemistry. Meanwhile, the contribution of dissolved organic nitrogen to the total nitrogen budget was substantial in this agricultural dominated landscape.

scholarly journals Generalized models to estimate carbon and nitrogen stocks of organic soil horizons in Interior Alaska

2020 ◽  
Vol 12 (3) ◽  
pp. 1745-1757
Author(s):  
Kristen Manies ◽  
Mark Waldrop ◽  
Jennifer Harden
Keyword(s):  
Soil Properties ◽  
Land Surface ◽  
Nitrogen Concentration ◽  
Mineral Soil ◽  
Organic Soil ◽  
Stand Age ◽  
Soil Horizons ◽  
Interior Alaska ◽  
C Stocks ◽  
Global Soil

Abstract. Boreal ecosystems comprise one-tenth of the world's land surface and contain over 20 % of the global soil carbon (C) stocks. Boreal soil is unique in that its mineral soil is covered by what can be quite thick layers of organic soil. These organic soil layers, or horizons, can differ in their state of decomposition, source vegetation, and disturbance history. These differences result in varying soil properties (bulk density, C concentration, and nitrogen concentration) among soil horizons. Here we summarize these soil properties, as represented by over 3000 samples from Interior Alaska, and examine how soil drainage and stand age affect these attributes. The summary values presented here can be used to gap-fill large datasets when important soil properties were not measured, provide data to initialize process-based models, and validate model results. These data are available at https://doi.org/10.5066/P960N1F9 (Manies, 2019).

Proteins are a major component of dissolved organic nitrogen (DON) leached from terrestrially aged Eucalyptus camaldulensis leaves

2016 ◽  
Vol 13 (5) ◽  
pp. 877 ◽  
Author(s):  
Clayton W. Harris ◽  
Ewen Silvester ◽  
Gavin N. Rees ◽  
John Pengelly ◽  
Ljiljana Puskar
Keyword(s):  
Leaf Litter ◽  
Dissolved Organic Nitrogen ◽  
Organic Nitrogen ◽  
Eucalyptus Camaldulensis ◽  
Aquatic Systems ◽  
Nutrient Source ◽  
Nitrogen Pool ◽  
Dissolved Nitrogen ◽  
Ftir Microspectroscopy ◽  
Proteinaceous Material

Environmental contextDissolved organic nitrogen often constitutes the largest portion of the dissolved nitrogen pool yet is a commonly overlooked nutrient source in aquatic systems. Terrestrially aged Eucalyptus camaldulensis, a common lowland leaf litter species, rapidly released proteinaceous dissolved organic nitrogen during the first 24h of leaching. The results indicate that terrestrial leaf litter may play an important role in satisfying nutrient demand within aquatic systems through both direct deposition and floodplain interactions. AbstractUnderstanding sources and forms of dissolved nitrogen is of critical importance to the management of aquatic systems worldwide. Dissolved organic nitrogen (DON) often constitutes the largest portion of the dissolved nitrogen pool, yet is commonly overlooked as a nutrient source to aquatic food webs, likely owing to its bound nature within organic material and the non-specific methods by which it is measured. In this study, we determined the protein and peptide (dissolved combined amino acid (DCAA)) contribution to DON leached from Eucalyptus camaldulensis leaves over 24h. The distribution of proteinaceous material in unleached and leached leaves was characterised using Fourier-transform infrared (FTIR) microspectroscopy to determine the likely source of DCAA within the leaf tissue. DCAAs were found to be a significant component (38.5%) of the leached DON; however, >90% of the leaf protein remained in the leaves after 24h. FTIR microspectroscopy shows that proteinaceous material is strongly partitioned to fungal colonised palisade cells in the leaf mesophyll, with evidence for depletion of this material after leaching. Comparison of leaching kinetics in the presence and absence of a microbial inhibitor (sodium azide) suggests that microbial uptake or adsorption commences within the timescales of these leaching experiments. The work shows that DON in the form of peptides and proteins leached from leaf litter is a likely source of bioavailable nutrients to in-stream and floodplain systems.

Sign in / Sign up

Export Citation Format

Share Document