x–y Coriolis interaction in the ν5 and ν8 bands of propyne-d3

1993 ◽  
Vol 71 (10) ◽  
pp. 1684-1688 ◽  
Author(s):  
Geetha Rajappan ◽  
V.A. Job

High resolution Fourier transform spectra of the ν5 and ν8 bands of CD3C≡CH have been recorded and analyzed taking into account the strong x–y Coriolis interaction between these fundamentals. Fermi resonance of the ν8 state with the ν9 + ν10 state, l-type doubling interaction between the ± l components of ν8 and a weak k-type doubling interaction between the ν5 and ν8 states have also been included in the perturbation treatment. The parameters of the ν5 and ν8 states as well as some of the parameters of the unobserved ν9 + ν10 state have been determined. An estimate of the relative value of the transition moments has been obtained from the line intensities, which are strongly affected by the x–y Coriolis interaction.

1985 ◽  
Vol 50 (11) ◽  
pp. 2480-2492 ◽  
Author(s):  
Soňa Přádná ◽  
Dušan Papoušek ◽  
Jyrki Kauppinen ◽  
Sergei P. Belov ◽  
Andrei F. Krupnov ◽  
...  

Fourier transform spectra of the ν2 band of PH3 have been remeasured with 0.0045 cm-1 resolution. Ground state combination differences from these data have been fitted simultaneously with the microwave and submillimeterwave data to determine the ground state spectroscopical parameters of PH3 including the parameters of the Δk = ± 3n interactions. The correlation between the latter parameters has been discussed from the point of view of the existence of two equivalent effective rotational operators which are related by a unitary transformation. The ΔJ = 0, +1, ΔK = 0 (A1 ↔ A2, E ↔ E) rotational transitions in the ν2 and ν4 states have been measured for the first time by using a microwave spectrometer and a radiofrequency spectrometer with acoustic detection.


2000 ◽  
Vol 202 (2) ◽  
pp. 229-248 ◽  
Author(s):  
O.N. Ulenikov ◽  
H. Bürger ◽  
W. Jerzembeck ◽  
G.A. Onopenko ◽  
E.A. Zhabina ◽  
...  

ChemInform ◽  
2010 ◽  
Vol 22 (46) ◽  
pp. no-no
Author(s):  
O. N. ULENIKOV ◽  
A. B. MALIKOVA ◽  
G. A. SHEVCHENKO ◽  
G. GUELACHVILI ◽  
M. MORILLON-CHAPEY

1993 ◽  
Vol 157 (1) ◽  
pp. 141-160 ◽  
Author(s):  
O.N. Ulenikov ◽  
A.E. Cheglokov ◽  
G.A. Shevchenko ◽  
M. Winnewisser ◽  
B.P. Winnewisser

2013 ◽  
Vol 91 (11) ◽  
pp. 906-909 ◽  
Author(s):  
M. Ngom ◽  
J.-M. Flaud ◽  
F. Kwabia Tchana ◽  
W.J. Lafferty ◽  
X. Landsheere ◽  
...  

Seven Fourier transform spectra of the ν3 band of oxirane (ethylene oxide) have been recorded with different pressures and used to derive individual line intensities. These line intensities were satisfactorily fit leading to accurate transition moment constants. An atlas of line positions and intensities has been generated.


1984 ◽  
Vol 62 (12) ◽  
pp. 1369-1373 ◽  
Author(s):  
Josef Pliva ◽  
J. W. C. Johns

The absorption spectrum of cyclopropane, C3H6, was measured in the region between 790 and 950 cm−1 on a high-resolution Fourier transform spectrometer. The section containing the Q-branches of the perpendicular band of the ν11 vibration of species E′ was deconvolved to an effective line width of 0.0020–0.0025 cm−1. The structure of the ν11 band is strongly affected by l-type resonance. A total of 88 sub-bands with KΔK = −42 to 45 have been assigned in this band. The K = 4–3 and 2–3 sub-bands both exhibit K doubling of the lines with high J resulting from a combined effect of the off-diagonal matrix elements [Formula: see text], [Formula: see text], and [Formula: see text] with the l doubling in the K = 1, l = 1 state. Otherwise, the ν11 band is found to be free of perturbations by other vibrational states, in spite of the fact that a Jx,y Coriolis interaction is allowed by selection rules with the ν7 band (species [Formula: see text]) whose band origin is only 14.38 cm−1 below that of ν11. This shows that the value of [Formula: see text] is essentially zero. Also, the allowed Jz Coriolis interaction with the ν10 state, which lies 160.01 cm−1 above ν11, does not noticeably affect the two bands. A Hamiltonian matrix, including the matrix elements responsible for the K doubling and l-type resonance, was used for the treatment of the ν11 band. A set of accurate ground state constants and spectroscopic constants for the upper state ν11 is reported that reproduces 3240 observed lines of this band with a standard deviation of 0.0009 cm−1. Lines of the parallel band ν7 are just barely seen between the ν11 lines, which are perhaps 30–50 times stronger. Spectroscopic constants for the ν7 band have been obtained from 135 individual lines assigned to the Q- and R-branches of sub-bands with K = 6–21.


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