π-Facial diastereoselectivity in the Diels–Alder reactions of cis-cyclohexa-3,5-diene-1,2-diol and derivatives with N-phenylmaleimide

1992 ◽  
Vol 70 (5) ◽  
pp. 1296-1307 ◽  
Author(s):  
James R. Gillard ◽  
D. Jean Burnell

N-Phenylmaleimide undergoes Diels–Alder cycloaddition predominantly to the face of cis-cyclohexa-3,5-diene-1,2-diol (3) syn to the oxygen functions. Derivatization can be used to alter the π-facial diastereoselectivity in a synthetically useful manner. The best cases are the exclusive, high yield, production of the syn-addition product with the trimethylsilyl ether derivative (8), and the exo-benzylidine derivative (26) gave a 96:4 anti/syn ratio of adducts.

2015 ◽  
Vol 51 (14) ◽  
pp. 2806-2809 ◽  
Author(s):  
Zhe Ji ◽  
Ji Chen ◽  
Liang Huang ◽  
Gaoquan Shi

A reversible covalent strategy based on the Diels–Alder reaction of graphite and tetracyanoethylene has been developed for the high-yield production of high-quality few-layer graphene.


animal ◽  
2021 ◽  
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Author(s):  
J. Simões ◽  
J.A. Abecia ◽  
A. Cannas ◽  
J.A. Delgadillo ◽  
D. Lacasta ◽  
...  

2021 ◽  
pp. 2101017
Author(s):  
Frank Mickoleit ◽  
Sabine Rosenfeldt ◽  
Mauricio Toro‐Nahuelpan ◽  
Miroslava Schaffer ◽  
Anna S. Schenk ◽  
...  

2012 ◽  
Vol 97 (8) ◽  
pp. 3343-3353 ◽  
Author(s):  
Claudia Korneli ◽  
Rebekka Biedendieck ◽  
Florian David ◽  
Dieter Jahn ◽  
Christoph Wittmann

2021 ◽  
Author(s):  
Benjamin Schmuck ◽  
Gabriele Greco ◽  
Andreas Barth ◽  
Nicola M. Pugno ◽  
Jan Johansson ◽  
...  

2017 ◽  
Vol 19 (20) ◽  
pp. 4804-4810 ◽  
Author(s):  
S. H. Shinde ◽  
C. V. Rode

A new and effective unique two-phase reaction system for the high yield production of tri(furyl)methane from furfural and furan.


ACS Nano ◽  
2009 ◽  
Vol 3 (12) ◽  
pp. 3839-3844 ◽  
Author(s):  
Sailaja Tetali ◽  
Mujtaba Zaka ◽  
Ronny Schönfelder ◽  
Alicja Bachmatiuk ◽  
Felix Börrnert ◽  
...  

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