The orientational ordering of solute molecules in nematic solvents: cyanobenzenes, bromobenzenes, and p-benzoquinone in EBBA and 1132

1990 ◽  
Vol 68 (6) ◽  
pp. 875-880 ◽  
Author(s):  
C. T. Yim ◽  
D. F. R. Gllson

The orientational order parameters of benzonitrile and o-, m-, and p-dicyanobenzene, monobromo- and p-dibromobenzene, and p-benzoquinone, dissolved in two nematic solvents, 1132 and EBBA, have been measured as functions of temperature, and used to determine the potential energy parameters for each solute–solvent pair. These parameters have been correlated with a short-range interaction based upon a shape and size function of the solute molecule and a long-range contribution due to the interaction between the solute molecular quadrupole moment and the average electric field gradient. Keywords: nematic liquid crystals, orientational ordering of solutes.

1989 ◽  
Vol 67 (1) ◽  
pp. 54-59 ◽  
Author(s):  
C. T. Yim ◽  
D. F. R. Gilson

The orientational order parameters of ortho-, meta-, and para-dichlorobenzene, dissolved in the nematic solvents EBBA and 1132, have been measured as functions of temperature and concentration, and used to determine the values of the potential energy parameters for each solute–solvent pair. These potentials have been interpreted in terms of a short-range contribution, which depends upon the shape and size of the solute molecule, plus a long-range term due to the interaction between the average electric field gradient from the solvent and the molecular quadrupole moment of the solute. Keywords: dichlorobenzenes, nematic solvents, liquid crystals, orientation, potential energy parameters.


1978 ◽  
Vol 56 (1) ◽  
pp. 139-148 ◽  
Author(s):  
Yoshitake Yamazaki

Critical behaviors in quenched random-spin systems with N-spin component are studied in the limit M → 0 of the non-random MN-component models by means of the renormalization group theory. As the static critical phenomena the stability of the fixed points is investigated and the critical exponents η[~ O(ε3); ε ≡ 4 – d], γ, α, and crossover index [Formula: see text] and the equation of state [~ O(ε)] are obtained. Within the approximation up to the order ε2, even the random-spin systems with N = 2 or 3 are unstable in the three dimensions and the pure systems are stable there.


2018 ◽  
Vol 173 ◽  
pp. 06008 ◽  
Author(s):  
Eugene A. Koval ◽  
Oksana A. Koval

We report numerical investigation of the short range interaction influence on the two-dimensional quantum scattering of two dipoles. The model simulates two ultracold polar molecules collisions in two spatial dimensions. The used algorithm allows us to quantitatively analyse the scattering of two polarized dipoles with account for strongly anisotropic nature of dipolar interaction. The strong dependence of the scattering total cross section on the short range interaction radius was discovered for threshold collision energies. We also discuss differences of calculated scattering cross section dependencies for different polarisation axis tilt angles.


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