La base faible ClO4− et la chimie du ligand perchlorato. Synthèse et analyse structurale de complexes de germanium(IV): GeCl3ClO4, GeCl2(ClO4)2 et (ClO2)2Ge(ClO4)6

1989 ◽  
Vol 67 (11) ◽  
pp. 1693-1697 ◽  
Author(s):  
Mohieddine Fourati ◽  
Moncef Chaabouni ◽  
Jean Louis Pascal ◽  
Jacqueline Potier
Keyword(s):  
Vibrational Spectroscopy ◽  
Room Temperature ◽  
Complex Mixture ◽  
The Other ◽  
Colorless Liquid ◽  
Polymeric Structure ◽  
The Core ◽  
Yellow Orange ◽  
Analyse Structurale ◽  
Mode Of Coordination

Reaction of Cl2O6 with an excess of GeCl4 at room temperature yields a colorless liquid, a complex mixture. Fractional distillation leads to GeCl3ClO4 and GeCl2(ClO4)2. (ClO2)2Ge(ClO4)6, a yellow-orange solid, is obtained by reacting excess Cl2O6 with GeCl4. It sublimes into unstable crystals above 32 °C. Vibrational spectroscopy shows mainly unidentate perchlorato groups strongly bonded to Ge in the three compounds characterized. Ge is tetrahedrally surrounded in GeCl3ClO4 while it is octahedrally surrounded in the other complexes. GeCl2(ClO4)2 and (ClO2)2Ge(ClO4)6 are individual entities while GeCl2(ClO4)2 has a polymeric structure with Ge–Cl–Ge bridges. The structure of (ClO2)2Ge(ClO4)6 is analogous to that found for (ClO2)2Sn(ClO4)6. Six unidentate perchlorato groups surround the core atom; some of them interact with ClO2+, defining a new mode of coordination for ClO4 groups. Keywords: germanium, chlorine trioxide, perchlorato, syntheses, vibrational spectroscopy.

scholarly journals Photophysical Properties and Kinetic Studies of 2-Vinylpyridine-Based Cycloplatinated(II) Complexes Containing Various Phosphine Ligands

Molecules ◽  
2021 ◽  
Vol 26 (7) ◽  
pp. 2034
Author(s):  
Vahideh Dolatyari ◽  
Hamid R. Shahsavari ◽  
Sepideh Habibzadeh ◽  
Reza Babadi Aghakhanpour ◽  
Sareh Paziresh ◽  
...  
Keyword(s):  
Room Temperature ◽  
Addition Reaction ◽  
Photophysical Properties ◽  
Kinetic Studies ◽  
Phosphine Ligands ◽  
The Other ◽  
Spectroscopic Methods ◽  
Yellow Orange ◽  
Oxidative Addition Reaction ◽  
Cyclometalated Ligand

A series of cycloplatinated(II) complexes with general formula of [PtMe(Vpy)(PR3)], Vpy = 2-vinylpyridine and PR3 = PPh3 (1a); PPh2Me (1b); PPhMe2 (1c), were synthesized and characterized by means of spectroscopic methods. These cycloplatinated(II) complexes were luminescent at room temperature in the yellow–orange region’s structured bands. The PPhMe2 derivative was the strongest emissive among the complexes, and the complex with PPh3 was the weakest one. Similar to many luminescent cycloplatinated(II) complexes, the emission was mainly localized on the Vpy cyclometalated ligand as the main chromophoric moiety. The present cycloplatinated(II) complexes were oxidatively reacted with MeI to yield the corresponding cycloplatinated(IV) complexes. The kinetic studies of the reaction point out to an SN2 mechanism. The complex with PPhMe2 ligand exhibited the fastest oxidative addition reaction due to the most electron-rich Pt(II) center in its structure, whereas the PPh3 derivative showed the slowest one. Interestingly, for the PPhMe2 analog, the trans isomer was stable and could be isolated as both kinetic and thermodynamic product, while the other two underwent trans to cis isomerization.

Electron microscope studies of the plastic deformation of ternary alloys based on GaAs

1990 ◽  
Vol 48 (4) ◽  
pp. 1120-1120
Author(s):  
R. Haswell ◽  
U. Bangert ◽  
P. Charsley
Keyword(s):  
Plastic Deformation ◽  
Electron Microscope ◽  
Room Temperature ◽  
Stacking Faults ◽  
The Other ◽  
Ternary Alloys ◽  
Dislocation Mobility ◽  
Semiconducting Materials ◽  
Micro Indentation

A knowledge of the behaviour of dislocations in semiconducting materials is essential to the understanding of devices which use them . This work is concerned with dislocations in alloys related to the semiconductor GaAs . Previous work on GaAs has shown that microtwinning occurs on one of the <110> rosette arms after indentation in preference to the other . We have shown that the effect of replacing some of the Ga atoms by Al results in microtwinning in both of the rosette arms.In the work to be reported dislocations in specimens of different compositions of Gax Al(1-x) As and Gax In(1-x) As have been studied by using micro indentation on a (001) face at room temperature . A range of electron microscope techniques have been used to investigate the type of dislocations and stacking faults/microtwins in the rosette arms , which are parallel to the [110] and [10] , as a function of composition for both alloys . Under certain conditions microtwinning occurs in both directions . This will be discussed in terms of the dislocation mobility.

The Salvage of Ideas: Schumpeter and the Core Problems Still Confronting Economics

2003 ◽  
pp. 15-26
Author(s):  
P. Wynarczyk
Keyword(s):  
The Other ◽  
The Core ◽  
Other Hand ◽  
The One

Two aspects of Schumpeter' legacy are analyzed in the article. On the one hand, he can be viewed as the custodian of the neoclassical harvest supplementing to its stock of inherited knowledge. On the other hand, the innovative character of his works is emphasized that allows to consider him a proponent of hetherodoxy. It is stressed that Schumpeter's revolutionary challenge can lead to radical changes in modern economics.

The Final ‘Thank You’

Derrida Today ◽  
2010 ◽  
Vol 3 (1) ◽  
pp. 21-36
Author(s):  
Grant Farred
Keyword(s):  
South Africa ◽  
South African ◽  
Jacques Derrida ◽  
Political Transition ◽  
The Other ◽  
World Cup ◽  
The Core ◽  
Nelson Mandela ◽  
Black President ◽  
The Moment

‘The Final “Thank You”’ uses the work of Jacques Derrida and Friedrich Nietzsche to think the occasion of the 1995 rugby World Cup, hosted by the newly democratic South Africa. This paper deploys Nietzsche's Zarathustra to critique how a figure such as Nelson Mandela is understood as a ‘Superman’ or an ‘Overhuman’ in the moment of political transition. The philosophical focus of the paper, however, turns on the ‘thank yous’ exchanged by the white South African rugby captain, François Pienaar, and the black president at the event of the Springbok victory. It is the value, and the proximity and negation, of the ‘thank yous’ – the relation of one to the other – that constitutes the core of the article. 1

Analysis (Hans Morgenthau) to the concept of power and applied to the units of the international system

2019 ◽  
Vol 1 (1) ◽  
pp. 138
Author(s):  
Saif Nasrat Tawfiq Al - Haramazi
Keyword(s):  
Applied Sciences ◽  
International System ◽  
The Other ◽  
Human Sciences ◽  
Basic Requirement ◽  
The Core ◽  
Hans Morgenthau

The theoretical curriculum in all disciplines is a basic requirement that nourishes the minds of the intellectual and cognitive recipients in the various scientific and cognitive stages. This is the framework that distinguishes the academic understanding of the anarchic, which is one of the most important and important keys in thinking and success in that jurisdiction or field, , Because it is unreasonable and logical to get into the core of any subject without searching and searching for its intellectual and historical bases to find out the reasons and reasons that surrounded this idea which was later recognized as an important contribution to the field of human sciences. Applied Sciences and other from the other side.

AFRICAN WOMEN AND FORBIDDEN GROUNDS: FEMALE SEXUALITY AND SELF-DETERMINATION IN AFRICAN LITERATURE

Imbizo ◽  
2017 ◽  
Vol 7 (1) ◽  
pp. 40-54
Author(s):  
Oyeh O. Otu
Keyword(s):  
Female Sexuality ◽  
Sense Of Self ◽  
African Literature ◽  
The Other ◽  
Self Determination ◽  
African Women ◽  
The Core ◽  
The Many ◽  
The One ◽  
Sexual Repression

This article examines how female conditioning and sexual repression affect the woman’s sense of self, womanhood, identity and her place in society. It argues that the woman’s body is at the core of the many sites of gender struggles/ politics. Accordingly, the woman’s body must be decolonised for her to attain true emancipation. On the one hand, this study identifies the grave consequences of sexual repression, how it robs women of their freedom to choose whom to love or marry, the freedom to seek legal redress against sexual abuse and terror, and how it hinders their quest for self-determination. On the other hand, it underscores the need to give women sexual freedom that must be respected and enforced by law for the overall good of society.

HAYNES STELLITE ALLOY No. 98M2

Alloy Digest ◽  
1960 ◽  
Vol 9 (7) ◽  
Keyword(s):  
Fracture Toughness ◽  
Compressive Strength ◽  
Physical Properties ◽  
Room Temperature ◽  
Base Alloy ◽  
Heat Treating ◽  
The Other ◽  
Stellite Alloy ◽  
Cobalt Base Alloy ◽  
Cobalt Base

Abstract HAYNES STELLITE 98M2 Alloy is a cobalt-base alloy having higher compressive strength and higher hardness than all the other cobalt-base alloys at room temperature and in the red heat range. This datasheet provides information on composition, physical properties, hardness, elasticity, tensile properties, and compressive strength as well as fracture toughness. It also includes information on heat treating, machining, and joining. Filing Code: Co-22. Producer or source: Haynes Stellite Company.

Ahara as Pathya and Apathya in Amlapitta - A Review.

2017 ◽  
Vol 2 (1) ◽  
Author(s):  
Rakshith . ◽  
Shivakumar . ◽  
Sreeharsha . ◽  
Divyasree .
Keyword(s):  
Physical Health ◽  
Review Article ◽  
The Other ◽  
Social Health ◽  
Present Review ◽  
Common Disease ◽  
The Core ◽  
Common Disorder ◽  
The Common

The core principles in Ayurveda give prime importance to Agni, Prakriti, Ahara (food) and Vihara (lifestyle) in maintaining health. Present era people are scheduled to one or the other works due to which they are following unrightful food and habits which lead the manifestation of one of the common disorder which troubles person a lot - Amlapitta. By excess “Hurry, Worry and Curry” GIT disorders are the most common, not only affecting physical health but also psychological and social health. Amlapitta is one of that and it is a burning problem of the whole World. Amalpitta is composed of word Amla and Pitta. Amlapitta is a very common disease caused by Vidagdha Pitta with features like Amlodgara, Tiktodgara, Hrit, Kantha Daha etc. Pathya recommended in Amlapitta are Yava, Godhuma, Purana Shali, Mudga Yusha, Lajasaktu etc. Apathya recommended in Amlapitta are Navanna, Avidugdha, Masha, Kulattha, Dadhi and etc. So this present review article throws light on Pathya (conducive) and Apathya (non conducive) in Amlapitta.

The Reactivity of Different Active Forms of Sodium Carbonate with Respect to Sulfur Dioxide

1992 ◽  
Vol 57 (11) ◽  
pp. 2302-2308
Author(s):  
Karel Mocek ◽  
Erich Lippert ◽  
Emerich Erdös
Keyword(s):  
Thermal Decomposition ◽  
Liquid Phase ◽  
Sulfur Dioxide ◽  
Specific Surface ◽  
Surface Area ◽  
Sodium Carbonate ◽  
Room Temperature ◽  
Active Form ◽  
The Other ◽  
Kinetics Of

The kinetics of the reaction of solid sodium carbonate with sulfur dioxide depends on the microstructure of the solid, which in turn is affected by the way and conditions of its preparation. The active form, analogous to that obtained by thermal decomposition of NaHCO3, emerges from the dehydration of Na2CO3 . 10 H2O in a vacuum or its weathering in air at room temperature. The two active forms are porous and have approximately the same specific surface area. Partial hydration of the active Na2CO3 in air at room temperature followed by thermal dehydration does not bring about a significant decrease in reactivity. On the other hand, if the preparation of anhydrous Na2CO3 involves, partly or completely, the liquid phase, the reactivity of the product is substantially lower.

scholarly journals Sustainable Consumer Behavior in Purchasing, Using and Disposing of Clothes

2021 ◽  
Vol 13 (15) ◽  
pp. 8333
Author(s):  
Mirella Soyer ◽  
Koen Dittrich
Keyword(s):  
Consumer Behavior ◽  
The Netherlands ◽  
Multiple Regression ◽  
Significant Role ◽  
Social Motivation ◽  
The Other ◽  
Social Evaluation ◽  
Sustainable Practices ◽  
Usage Phase ◽  
The Core

In this study we investigate how consumers in The Netherlands can be persuaded to adopt sustainable practices when purchasing, using and disposing of clothes. This study investigates the attitude-behavior gap for the sustainable choices for purchase, use and disposing of clothes. For each consumption phase we ran a two-step multiple regression. The findings showed that the importance of the factors vary in the three consumption phases. For purchasing and disposal decisions, the core motivator social motivation predicts sustainable practices best, while it has no role in the usage phase. The factor ability appeared to have a significant role in the disposal phase, but not in the other phases. Finally, the trigger appears to lower the consumers’ ability in the purchasing phase, while it enhances the core motivator social evaluation in the disposal phase.

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