Étude structurale de l'amino-5 dibenzyl-4,4 one-3 2H-thiadiazine-1,2,6 dioxyde-1,1

1988 ◽  
Vol 66 (10) ◽  
pp. 2477-2482 ◽  
Author(s):  
Pierre Brouant ◽  
Jacques Barbe ◽  
Pilar Goya ◽  
Carmen Ochoa

5-Amino-4,4-dibenzyl-3-one-2H-1,2,6-thiadiazine-1,1-dioxide was structurally characterized in the solid state by X-ray diffraction. The structure shows that the title compound exists in the solid in a sheet-packed form and as the amino tautomer. The unconjugated heterocyclic ring, which in the structures of related compounds is usually folded, is planar in the present structure. 1H nuclear magnetic resonance and dipole moment data indicate that the title compound has the same structure in the solid state and in solution.

1985 ◽  
Vol 63 (8) ◽  
pp. 2176-2180 ◽  
Author(s):  
F. W. B. Einstein ◽  
E. Kiehlmann ◽  
E. K. Wolowidnyk

The title compound has been synthesized by selective debromination of 6,8-dibromocatechin and indirect methylation of the resulting 6-bromocatechin via its pentaacetate. The structure of C20H23BrO6 has been determined by X-ray crystallography. The compound crystallizes in the space group P1 with a = 9.589(3) Å, b = 11.576(3) Å, c = 11.326(3) Å, α = 118.80(3)°, β = 93.23(3)°, γ = 111.44(3)°, ρc = 1.481 g cm−3, and Z = 2. Intensities were measured for 2584 independent reflections (2θ < 45°) of which 2213 were observed (I > 3.0σ(I)) and used in subsequent refinement (final R values were R = 0.0268 and Rw = 0.0344). Crystallographic and pmr data confirm the position of the bromine atom at C-6, the trans-diaxial arrangement of H-2/H-3 and the quasi-equatorial orientation of the 3,4-dimethoxyphenyl group (ring B). The two heterocyclic ring conformations are consistent with the expected flexibility of the molecule.


2011 ◽  
Vol 34 (5-6) ◽  
pp. 153-153
Author(s):  
Libasse Diop

Abstract Solid-state and solution 117Sn nuclear magnetic resonance studies of C2O4(SnPh3)2 have been carried out and found to be in good agreement with the tetrahedral environment of the tin (IV) atom as found from the solid state structure, previously determined by a single crystal X-ray diffraction analysis.


1981 ◽  
Vol 46 (16) ◽  
pp. 3302-3305 ◽  
Author(s):  
Edmund J. Eisenbraun ◽  
Clinton E. Browne ◽  
Ernest L. Eliel ◽  
David L. Harris ◽  
Asadur Rahman ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document