Molecular to atomic transformation in solid iodine under high pressure

1988 ◽  
Vol 66 (4) ◽  
pp. 812-818 ◽  
Author(s):  
Tadeusz Luty ◽  
John C. Raich

Structural transformations in solid iodine under high pressure are analyzed from the point of view of symmetries of possible charge density distortions coupled to phonons. The transition from the high pressure atomic phase to the low pressure molecular phase is interpreted in terms of phonon softening and formation of molecular bonds and is seen as a condensation of a charge density distortion wave coupled to a phonon mode.

1989 ◽  
Vol 40 (11) ◽  
pp. 8064-8067 ◽  
Author(s):  
M. Petravić ◽  
L. Forró ◽  
J. R. Cooper

CrystEngComm ◽  
2011 ◽  
Vol 13 (8) ◽  
pp. 2930 ◽  
Author(s):  
Ivan S. Bushmarinov ◽  
Orudzh G. Nabiev ◽  
Remir G. Kostyanovsky ◽  
Mikhail Yu. Antipin ◽  
Konstantin A. Lyssenko

2020 ◽  
Author(s):  
Ruobin Dai ◽  
Hongyi Han ◽  
Tianlin Wang ◽  
Jiayi Li ◽  
Chuyang Y. Tang ◽  
...  

Commercial polymeric membranes are generally recognized to have low sustainability as membranes need to be replaced and abandoned after reaching the end of their life. At present, only techniques for downcycling end-of-life high-pressure membranes are available. For the first time, this study paves the way for upcycling fouled/end-of-life low-pressure membranes to fabricate new high-pressure membranes for water purification, forming a closed eco-loop of membrane recycling with significantly improved sustainability.


2021 ◽  
Vol 103 (5) ◽  
Author(s):  
M. Trigo ◽  
P. Giraldo-Gallo ◽  
J. N. Clark ◽  
M. E. Kozina ◽  
T. Henighan ◽  
...  

2021 ◽  
Author(s):  
Naotaka Yoshikawa ◽  
Hiroki Suganuma ◽  
Hideki Matsuoka ◽  
Yuki Tanaka ◽  
Pierre Hemme ◽  
...  

2021 ◽  
Vol 118 (22) ◽  
pp. 221603
Author(s):  
G. Storeck ◽  
K. Rossnagel ◽  
C. Ropers

Crystals ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 34
Author(s):  
Akun Liang ◽  
Robin Turnbull ◽  
Enrico Bandiello ◽  
Ibraheem Yousef ◽  
Catalin Popescu ◽  
...  

We report the first high-pressure spectroscopy study on Zn(IO3)2 using synchrotron far-infrared radiation. Spectroscopy was conducted up to pressures of 17 GPa at room temperature. Twenty-five phonons were identified below 600 cm−1 for the initial monoclinic low-pressure polymorph of Zn(IO3)2. The pressure response of the modes with wavenumbers above 150 cm−1 has been characterized, with modes exhibiting non-linear responses and frequency discontinuities that have been proposed to be related to the existence of phase transitions. Analysis of the high-pressure spectra acquired on compression indicates that Zn(IO3)2 undergoes subtle phase transitions around 3 and 8 GPa, followed by a more drastic transition around 13 GPa.


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