Ternary charge-transfer complexes. III. Complexes with Group V elements in the anion

1986 ◽  
Vol 64 (8) ◽  
pp. 1661-1667 ◽  
Author(s):  
Sydney Brownstein ◽  
Eric Gabe ◽  
Florence Lee ◽  
Andrej Piotrowski
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Charge Transfer ◽  
Magnetic Resonance ◽  
Crystal Structures ◽  
Charge Transfer Complexes ◽  
Spectral Parameters ◽  
Group V ◽  
Nuclear Magnetic

NOMX6•aromatic charge-transfer complexes are formed where M may be P, As, orSb, X maybe For Cl, and aromatic may be benzene or a methyl-substituted benzene. Nuclear magnetic resonance and optical spectral parameters are given and three crystal structures reported. Appreciable conductivity is found for NOSbCl6•polystyrene and NOSbF6•hexamethylbenzene.

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