Prospects for solar synthesis. II. Study of the photocyclization of α-(o-tolyl)acetophenone in solution and in crosslinked ethylene – vinyl acetate beads

1985 ◽  
Vol 63 (6) ◽  
pp. 1333-1336 ◽  
Author(s):  
J. E. Guillet ◽  
W. K. MacInnis ◽  
A. E. Redpath
Keyword(s):  
Solar Radiation ◽  
Energy Distribution ◽  
Vinyl Acetate ◽  
Polymer Matrix ◽  
Solar Spectrum ◽  
Ethylene Vinyl Acetate ◽  
Solid Polymer ◽  
Quantum Yields ◽  
Photochemical Transformations ◽  
Photon Energy Distribution

Studies of the photocyclization of α-(o-tolyl)acetophenone dissolved in crosslinked ethylene–vinyl acetate beads show that quantum yields close to unity can be achieved, even in the solid polymer matrix. In preliminary experiments using solar radiation it was demonstrated that the rates of photochemical transformations are close to those calculated from the photon energy distribution of the solar spectrum.

Electrical and Mechanical Properties of Ethylene Vinyl Acetate Based Composites

2012 ◽  
Vol 714 ◽  
pp. 193-199 ◽  
Author(s):  
Klaudia Czaniková ◽  
Zdenko Špitalský ◽  
Igor Krupa ◽  
Mária Omastová
Keyword(s):  
Mechanical Properties ◽  
Carbon Nanotubes ◽  
Electrical Conductivity ◽  
Multiwalled Carbon Nanotubes ◽  
Vinyl Acetate ◽  
Polymer Matrix ◽  
Ethylene Vinyl Acetate ◽  
Multiwalled Carbon ◽  
Scanning Electron ◽  
Properties Of Composites

In this study various composites based on the commercial ethylene vinyl acetate polymer matrix and multiwalled carbon nanotubes were prepared by casting from solution in the form of thick films. The degree of dispergation of carbon nanotubes in the polymer matrix was examined by scanning electron microscopy. Electrical conductivity and mechanical properties of those composites were investigated. It was observed that the electrical conductivity of composites increases with an increase of multiwalled carbon nanotubes content. The mechanical properties of composites were only slightly changed when compared with properties of neat ethylene vinyl acetate matrix.

COMPARATIVE STUDIES OF ETHYLENE VINYL ACETATE FILMS WITH VARIOUS SILICATE NANOCOMPOSITES

2019 ◽  
Vol 12 (04) ◽  
pp. 1803-1809
Author(s):  
A. Kaviarasi ◽  
M.V.L. Kumari ◽  
A.R. Prabakaran ◽  
A. Anandavadivel
Keyword(s):  
Vinyl Acetate ◽  
Comparative Studies ◽  
Ethylene Vinyl Acetate ◽  
Silicate Nanocomposites

Study of Ethylene Vinyl Acetate (EVA) Films used in Photovoltaic Modules

2018 ◽  
Vol 10 (5) ◽  
pp. 05043-1-05043-3 ◽  
Author(s):  
Rahul Kumar ◽  
◽  
Shashwata Chattopadhyay ◽  
Chetan Singh Solanki ◽  
Sarita Zele ◽  
...  
Keyword(s):  
Vinyl Acetate ◽  
Ethylene Vinyl Acetate ◽  
Photovoltaic Modules

scholarly journals Wastes from Agricultural Silage Film Recycling Line as a Potential Polymer Materials

Polymers ◽  
2021 ◽  
Vol 13 (9) ◽  
pp. 1383
Author(s):  
Jerzy Korol ◽  
Aleksander Hejna ◽  
Klaudiusz Wypiór ◽  
Krzysztof Mijalski ◽  
Ewelina Chmielnicka
Keyword(s):  
Vinyl Acetate ◽  
Thermal Performance ◽  
Mechanical Performance ◽  
Ethylene Vinyl Acetate ◽  
Tensile Tests ◽  
Solid Particles ◽  
Polymer Materials ◽  
Slight Reduction ◽  
Scanning Calorimetry ◽  
Crystallinity Degree

The recycling of plastics is currently one of the most significant industrial challenges. Due to the enormous amounts of plastic wastes generated by various industry branches, it is essential to look for potential methods for their utilization. In the presented work, we investigated the recycling potential of wastes originated from the agricultural films recycling line. Their structure and properties were analyzed, and they were modified with 2.5 wt % of commercially available compatibilizers. The mechanical and thermal performance of modified wastes were evaluated by tensile tests, thermogravimetric analysis, and differential scanning calorimetry. It was found that incorporation of such a small amount of modifiers may overcome the drawbacks caused by the presence of impurities. The incorporation of maleic anhydride-grafted compounds enhanced the tensile strength of wastes by 13–25%. The use of more ductile compatibilizers—ethylene-vinyl acetate and paraffin increased the elongation at break by 55–64%. The presence of compatibilizers also reduced the stiffness of materials resulting from the presence of solid particles. It was particularly emphasized for styrene-ethylene-butadiene-styrene and ethylene-vinyl acetate copolymers, which caused up to a 20% drop of Young’s modulus. Such effects may facilitate the further applications of analyzed wastes, e.g., in polymer film production. Thermal performance was only slightly affected by compatibilization. It caused a slight reduction in polyethylene melting temperatures (up to 2.8 °C) and crystallinity degree (up to 16%). For more contaminated materials, the addition of compatibilizers caused a minor reduction in the decomposition onset (up to 6 °C). At the same time, for the waste after three washing cycles, thermal stability was improved. Moreover, depending on the desired properties and application, materials do not have to go through the whole recycling line, simplifying the process, reducing energy and water consumption. The presented results indicate that it is possible to efficiently use the materials, which do not have to undergo the whole recycling process. Despite the presence of impurities, they could be applied in the manufacturing of products which do not require exceptional mechanical performance.

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