The intercalation of bromine fluorosulfates into graphite

1983 ◽  
Vol 61 (12) ◽  
pp. 2638-2642 ◽  
Author(s):  
S. Karunanithy ◽  
F. Aubke
Keyword(s):  
Electrical Conductivity ◽  
Sulfuric Acid ◽  
Raman Spectra ◽  
Room Temperature ◽  
Chemical Species ◽  
Intercalation Compounds ◽  
X Ray ◽  
Compound C ◽  
Lattice Mode ◽  
Identity Period

The action of bromine(1)fluorosulfate on graphite has led to the synthesis of several novel intercalation compounds. The intercalation of bromine(1)fluorosulfate at room temperature results in a first stage compound, C12BrSO3F, while at higher temperatures (~110 °C) C20BrF(SO3F)2 forms instead. Oxidation of C12BrSO3F with S2O6F2 yields C16Br(SO3F)3 and this reaction can be reversed by reacting the latter with an excess of Br2.Graphite trifluoromethylsulfate C12SO3CF3 is formed in the solvolysis of C12BrSO3F with an excess of trifluoromethyl-sulfuric acid. First stage nature of these compounds has been confirmed by the X-ray identity period along C axis and [Formula: see text], vibrational lattice mode in the Raman spectra. The use of 19F nmr in identifying the chemical species in the inter-lamellar space has been demonstrated. The planar electrical conductivity of these compounds has been observed to be three to six times higher than that of graphite.

Structure and Conductivity of Iodine-Doped C60 Thin Films

1994 ◽  
Vol 359 ◽  
Author(s):  
Jun Chen ◽  
Haiyan Zhang ◽  
Baoqiong Chen ◽  
Shaoqi Peng ◽  
Ning Ke ◽  
...  
Keyword(s):  
Thin Films ◽  
Electrical Conductivity ◽  
Room Temperature ◽  
Conductivity Measurements ◽  
X Ray Diffraction ◽  
Temperature Conductivity ◽  
Room Temperature Conductivity ◽  
X Ray ◽  
Thermally Activated ◽  
Order Of Magnitude

ABSTRACTWe report here the results of our study on the properties of iodine-doped C60 thin films by IR and optical absorption, X-ray diffraction, and electrical conductivity measurements. The results show that there is no apparent structural change in the iodine-doped samples at room temperature in comparison with that of the undoped films. However, in the electrical conductivity measurements, an increase of more that one order of magnitude in the room temperature conductivity has been observed in the iodine-doped samples. In addition, while the conductivity of the undoped films shows thermally activated temperature dependence, the conductivity of the iodine-doped films was found to be constant over a fairly wide temperature range (from 20°C to 70°C) exhibiting a metallic feature.

The Vibrational Spectra and Crystal Structure of Acenaphthylene

1973 ◽  
Vol 51 (3) ◽  
pp. 402-404 ◽  
Author(s):  
A. Bree ◽  
R. A. Kydd ◽  
V. V. B. Vilkos ◽  
R. S. Williams
Keyword(s):  
Crystal Structure ◽  
Single Crystals ◽  
Raman Spectra ◽  
Vibrational Spectra ◽  
Room Temperature ◽  
Infrared And Raman Spectra ◽  
Depolarization Ratio ◽  
X Ray

A study of the polarized infrared and Raman spectra of acenaphthylene single crystals has been made. These results, together with Gordon and Yang's preliminary X-ray work, suggest that the molecules pack in some disordered arrangement in the solid at room temperature. Most of the A1 fundamentals were identified in the Raman solution spectrum from their low depolarization ratio, and a few tentative assignments of nontotally symmetric fundamentals were made.

Platelet Adhesion Study and Characteristic of Hydrogenated Carbon Films Synthesized by PIII-D

2005 ◽  
Vol 288-289 ◽  
pp. 323-326 ◽  
Author(s):  
Feng Wen ◽  
Nan Huang ◽  
H. Sun ◽  
Ping Yang ◽  
Jin Wang
Keyword(s):  
Thin Films ◽  
Mechanical Properties ◽  
Raman Spectra ◽  
Room Temperature ◽  
Platelet Adhesion ◽  
Carbon Films ◽  
Photoelectron Spectra ◽  
X Ray ◽  
Composition And Structure ◽  
Amorphous Hydrogenated Carbon

Amorphous hydrogenated carbon (a-C:H) thin films were deposited on silicon wafers and Ti6Al4V substrate using plasma ion immersion implantation and deposition (PIII-D) at room temperature (R.T.). The composition and structure of a-C:H films were employed by X-ray photoelectron spectra (XPS) and Raman spectra. Nano-indenter tests measured the hardness of the films. In addition, wettability and bloodcompatibility were investigated. In this paper, the effects of hydrogen content on structure, mechanical properties, surface wettability and haemocompatibility were discussed.

Elektrische Leitfähigkeitsmessungen und Bestimmung des G(freie Ionen)-Wertes bei röntgenbestrahlten Flüssigkeiten verschiedener Molekularstruktur

1968 ◽  
Vol 23 (2) ◽  
pp. 126-133 ◽  
Author(s):  
Werner F. Schmidt
Keyword(s):  
Electrical Conductivity ◽  
Room Temperature ◽  
Absorbed Dose ◽  
Recombination Coefficient ◽  
Conductivity Measurements ◽  
Absorbed Dose Rate ◽  
X Ray ◽  
Free Ions ◽  
Radiation Induced

Electrical conductivity measurements were made for the determination of G (free ions) in some hydrocarbons. The radiation source was a x-ray tube operated at 55 kV. Four quantities were measured for each liquid: 1. the stationary electrical conductivity at low electric field strength during irradiation, 2. the mobilities of the radiation-induced ions, 3. the volume recombination coefficient, and 4. the absorbed dose rate.All measurements were performed with aerated liquids at room temperature. The following G-values were obtained: n-pentane 0,1; n-hexane and n-heptane 0,09; iso-octane 0,11; cyclohexane 0,06; benzene 0,07; decalin 0,04. The standard deviation was estimated to ± 25 per cent.

CRYSTAL STRUCTURE, ELECTRICAL CONDUCTIVITY AND THERMAL EXPANSION OF Pr1-xSrxFeO3-δ(0 ≤ x ≤ 0.6)

2012 ◽  
Vol 26 (32) ◽  
pp. 1250174 ◽  
Author(s):  
V. PRASHANTH KUMAR ◽  
Y. S. REDDY ◽  
P. KISTAIAH ◽  
C. VISHNUVARDHAN REDDY
Keyword(s):  
Crystal Structure ◽  
Electrical Conductivity ◽  
Thermal Expansion ◽  
Room Temperature ◽  
Small Polaron ◽  
Linear Thermal Expansion ◽  
Lattice Parameter ◽  
Polaron Hopping ◽  
X Ray ◽  
Perovskite Type

The crystal structure at room temperature (RT), thermal expansion from RT to 1000°C and electrical conductivity, from RT to 600°C, of the perovskite-type oxides in the system Pr 1-x Sr x FeO 3(x = 0, 0.2, 0.4, 0.6) were studied. All the compounds have the orthorhombic perovskite GdFeO 3-type structure with space group Pbnm. The lattice parameters were determined by X-ray powder diffraction. The Pseudo cubic lattice parameter decreases with an increase in x, while the coefficient of linear thermal expansion increases. The thermal expansion is almost linear for x = 0 and 0.2. The electrical conductivity increases with increasing x while the activation energy decreases. The electrical conductivity can be described by the small polaron hopping conductivity model.

scholarly journals [HMIM][Br9]: a Room-temperature Ionic Liquid Based on a Polybromide Anion

2013 ◽  
Vol 68 (10) ◽  
pp. 1103-1107 ◽  
Author(s):  
Heike Haller ◽  
Michael Hog ◽  
Franziska Scholz ◽  
Harald Scherer ◽  
Ingo Krossing ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Raman Spectroscopy ◽  
Ionic Liquid ◽  
Nmr Spectroscopy ◽  
Single Crystal ◽  
Room Temperature ◽  
High Electrical Conductivity ◽  
Conductivity Measurements ◽  
X Ray Diffraction ◽  
X Ray

[HMIM][Br9] ([HMIM]=1-hexyl-3-methylimidazolium) has been investigated by Raman spectroscopy, single-crystal X-ray diffraction and NMR spectroscopy. Conductivity measurements show a high electrical conductivity like other polybromides.

scholarly journals CALCULATION OF THE VALUES OF THERMODYNAMIC FUNCTIONS OF THE SULFURIC ACID DECOMPOSITION OF THE PHOSPHORITE CONCENTRATE OF THE RIVAT DEPOSIT OF TAJIKISTAN

2021 ◽  
pp. 37-44
Author(s):  
Шодком Ахмадбоевич Курбонов ◽  
Бехзод Аминович Обидов ◽  
Шонавруз Рахимович Самихов ◽  
Холмахмад Исроилович Холов
Keyword(s):  
Sulfuric Acid ◽  
Thermodynamic Functions ◽  
Room Temperature ◽  
Mineralogical Composition ◽  
Main Constituent ◽  
Laboratory Studies ◽  
Acid Decomposition ◽  
X Ray ◽  
Carbonate Fluorapatite ◽  
Sulfuric Acid Decomposition

В статье обобщены полученные результаты лабораторных исследований и расчета значений термодинамических функций процесса сернокислотного разложения фосфоритного концентрата месторождения Риват. Установлен минералогический состав концентрата рентгенофазовым анализом. Показано, что основной составной частью концентрата является карбонат-фторапатит. В ходе исследования показано, что повышение температуры неблагополучно влияет на сернокислотное разложение концентрата и оно протекает самопроизвольно при комнатной температуре. The article summarizes the results of laboratory studies and calculation of the values of thermodynamic functions of the process of sulfuric acid decomposition of phosphorite concentrate from the Rivat deposit. The mineralogical composition of the concentrate was determined by X-ray phase analysis. It is shown that the main constituent of the concentrate is carbonate - fluorapatite. In the course of the study, it was shown that an increase in temperature adversely affects the sulfuric acid decomposition of the concentrate and it proceeds spontaneously at room temperature.

scholarly journals Crystal structure of 4,4′-bis[3-(piperidin-1-yl)prop-1-yn-1-yl]-1,1′-biphenyl

2017 ◽  
Vol 73 (6) ◽  
pp. 864-866 ◽  
Author(s):  
Anqi Walbaum ◽  
E. Kim Fifer ◽  
Sean Parkin ◽  
Peter A. Crooks
Keyword(s):  
Room Temperature ◽  
Model Compound ◽  
Chair Conformation ◽  
Slow Evaporation ◽  
Compound I ◽  
X Ray ◽  
Analgesic Effects ◽  
Compound C ◽  
Head Groups ◽  
Benzene Rings

The title compound, C28H32N2, (I), is one of a second generation of compounds designed and synthesized based on a very potent and selective α9α10 nicotinic acetylcholine receptor antagonist ZZ161C {1,1′-[[1,1′-biphenyl]-4,4′-diylbis(prop-2-yne-3,1-diyl)]bis(3,4-dimethylpyridin-1-ium) bromide}, which has shown analgesic effects in a chemotherapy-induced neuropathy animal model. Compound (I) was synthesized by the reaction of 4,4′-bis(3-bromoprop-1-yn-1-yl)-1,1′-biphenyl with piperidine at room temperature in acetonitrile. The single-crystal used for X-ray analysis was obtained by dissolving (I) in a mixture of dichloromethane and methanol, followed by slow evaporation of the solvent. In the crystal of (I), the biphenyl moiety has a twisted conformation, with a dihedral angle of 25.93 (4)° between the benzene rings. Both piperidine head groups in (I) are in the chair conformation and are oriented so that the N-atom lone pairs of each piperidine group point away from the central biphenyl moiety.

FACILE PREPARATION AND CHARACTERIZATION OF GRAPHENE NANOSHEET/POLYANILINE NANOFIBER THERMOELECTRIC COMPOSITES

2013 ◽  
Vol 06 (05) ◽  
pp. 1340002 ◽  
Author(s):  
YONG DU ◽  
KEFENG CAI ◽  
SHIRLEY ZHIQI SHEN
Keyword(s):  
Electrical Conductivity ◽  
Room Temperature ◽  
Oxidative Polymerization ◽  
X Ray Diffraction ◽  
Composite Powders ◽  
Graphene Nanosheet ◽  
X Ray ◽  
Pani Composite ◽  
Composite Pellets

Graphene nanosheet (GNs)/polyaniline (PANI) nanofiber composites were prepared by oxidative polymerization of aniline in a GNs dispersed 1 mol/L HCl solution. The phase composition of the composites was analyzed by Fourier Transform Infrared Spectroscopy and X-ray Diffraction. The thermoelectric properties of the composite powders, after cold pressing into pellets, were measured at room temperature. As the content of GNs increased from 0 to 40 wt.%, the electrical conductivity and Seebeck coefficient of the composite pellets increased simultaneously; especially the electrical conductivity increased dramatically from 15.4 to 120.1 S/cm. The highest power factor (~ 394.4 × 10-8 Wm-1K-2) was obtained from the 40 wt.% GNs/PANI composite sample, which is ~200 times as high as that of HCl -doped PANI.

Infrared and Raman Spectra of Bis(Melaminium) Sulfate Dihydrate

2003 ◽  
Vol 2003 (8) ◽  
pp. 518-521 ◽  
Author(s):  
M.K. Marchewka
Keyword(s):  
Raman Spectra ◽  
Vibrational Spectra ◽  
Crystalline State ◽  
Room Temperature ◽  
Spectral Features ◽  
Infrared And Raman Spectra ◽  
X Ray ◽  
Internal Vibrations

Room temperature powder infrared and Raman measurements for the new melaminium salt, bis(2,4,6-triamino-1,3,5-triazin-1-ium) sulfate dihydrate, 2C3H7N6+·SO42-·2H2O, in the crystalline state, were carried out. The vibrational spectra in the region of internal vibrations of the ions corroborate recent X-ray data of Janczak et al. Some spectral features of this new crystal are referred to those of other crystalline melaminium salts.

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