Raman spectra of sodium sulphamate single crystal

1983 ◽  
Vol 61 (9) ◽  
pp. 2048-2052 ◽  
Author(s):  
P. Muthusubramanian ◽  
A. Sundara Raj
Keyword(s):  
Hydrogen Bonding ◽  
Single Crystal ◽  
Single Crystals ◽  
Raman Spectra ◽  
Room Temperature ◽  
Polycrystalline Sample ◽  
Vibrational Assignments ◽  
Polarized Raman ◽  
Sulphamic Acid ◽  
Infrared Data

Vibrational assignments are proposed for solid NaNH2SO3 on the basis of room temperature polarized Raman spectra of single crystals. Infrared data for the region 4000–50 cm−1 of the polycrystalline sample are also presented. The results indicate that (1) there is no water of crystallization, (2) the hydrogen bonding is extremely weak, and (3) the strength of N—S bond is stronger than in sulphamic acid.

scholarly journals Raman Spectra of 6LiRbSO4 and 7LiRbSO4

1993 ◽  
Vol 47 (7) ◽  
pp. 999-1006 ◽  
Author(s):  
Kyung Hui Oh ◽  
Joon Hyung Cho ◽  
Seung-Bin Kim
Keyword(s):  
Irreducible Representation ◽  
Single Crystal ◽  
Raman Spectra ◽  
Room Temperature ◽  
Lithium Ion ◽  
Lithium Isotope ◽  
Sulfate Ion ◽  
Vibrational Coupling ◽  
Coupling Interaction ◽  
Polarized Raman

The polarized Raman spectra of single-crystal 6LiRbSO4 and 7LiRbSO4 at room temperature are reported. On the basis of these data, symmetry-based band assignments are given for both internal and external optic modes. The translational optic modes of the lithium ion appear in the region between 444 and 364 cm−1. Vibrational coupling interactions are noted between the sulfate ion ν2 and the lithium translational optic modes in the same irreducible representation. Coupling interactions are negligible or small in 7LiRbSO4, while in 6LiRbSO4 the lithium isotope effect shifts the lithium translational modes into more coupling interaction with the sulfate ion ν2 modes.

The Characteristic of the La3Ga5SiO14 Single Crystal Grown by Vertical Bridgman Method in Ar Atmosphere

2006 ◽  
Vol 510-511 ◽  
pp. 842-845 ◽  
Author(s):  
Noriko Bamba ◽  
Kentaro Kato ◽  
Toshinori Taishi ◽  
Takayuki Hayashi ◽  
Keigo Hoshikawa ◽  
...  
Keyword(s):  
Melting Point ◽  
Single Crystal ◽  
Single Crystals ◽  
Room Temperature ◽  
Color Change ◽  
Piezoelectric Materials ◽  
Lead Free ◽  
Piezoelectric Constant ◽  
Interstitial Oxygen ◽  
Vertical Bridgman

Langasite (La3Ga5SiO14: denoted by LGS) single crystal is one of the lead free piezoelectric materials with high piezoelectricity that is maintained up to its melting point (1470°C). Although LGS single crystals have usually been grown by Czochralski (CZ) method in oxygen contained atmosphere to prevent evaporation of Ga, they were grown by the vertical Bridgman (VB) method in Ar atmosphere without oxygen, and their properties were evaluated in this work. Transparent and colorless LGS single crystals were successfully obtained without Ga evaporation by the VB method in Ar atmosphere, and their resistivity at room temperature was much higher than that grown by conventional CZ method. Piezoelectric constant d11 of the crystal grown by the VB method was 6 x 10-12 C/N, which was close to that of the crystal grown by CZ method. The colorless transparent LGS single crystal turned to orange and its resistivity decreased by annealing in air. Since an orange-colored transparent LGS single crystal has been grown by conventional CZ method, this indicates that color change and the resistivity decrease of LGS crystal is caused by extra interstitial oxygen atoms in the crystal.

Growth of Yb:Y2O3 single crystals by the micro-pulling-down method

2004 ◽  
Vol 848 ◽  
Author(s):  
A. Novoselov ◽  
J. H. Mun ◽  
A. Yoshikawa ◽  
G. Boulon ◽  
T. Fukuda
Keyword(s):  
Single Crystal ◽  
Single Crystals ◽  
Raman Spectra ◽  
Lattice Constant ◽  
Decay Time ◽  
Dopant Distribution ◽  
High Homogeneity ◽  
Linear Decrease ◽  
Crystal Laser

ABSTRACT(Ybx Y1-x)2O3 (x = 0.0, 0.005, 0.05, 0.08 and 0.15) promising single crystal laser rods of 4.2 mm in diameter and 15–20 mm in length have been grown from the rhenium crucible by the micro-pulling-down method in Ar + H2(3–4%) atmosphere. Linear decrease of lattice constant with the increase of Yb3+-content was observed. High homogeneity of the Yb3+-dopant distribution has been demonstrated. Absorption, emission and Raman spectra have been recorded and decay time was approximated.

scholarly journals THE POLARIZED RAMAN SPECTRA FOR SINGLE CRYSTAL LiB3O5

1996 ◽  
Vol 45 (5) ◽  
pp. 885
Author(s):  
JANG YI-JIAN ◽  
WANG YUE ◽  
ZENG LING-ZHI ◽  
LIU YU-LONG
Keyword(s):  
Single Crystal ◽  
Raman Spectra ◽  
Polarized Raman

Some New 1-D Compounds with Metal-Halide Chain

1981 ◽  
Vol 36 (1) ◽  
pp. 83-86 ◽  
Author(s):  
D. Layek ◽  
G. C. Papavassiliou
Keyword(s):  
Single Crystals ◽  
Raman Spectra ◽  
Mixed Valence ◽  
Metal Halide ◽  
Anisotropic Character ◽  
Chemical Behaviour ◽  
Polarized Raman ◽  
Mixed Valence Compounds

Abstract Some new mixed valence compounds of the type [M(L-L)2M(L-L)2X2]Y4 (where M = Pt or Pd, L-L = 2NH3 or ethylenediamine, X = Cl, Br or I and Y = HSO4, 1/2 SO4, ClO4 or 1/2 PtCl4) have been synthesized. The polarized Raman spectra of single crystals show the anisotropic character and the presence of ---M(II)---X-M(IV)-X chains. The method of preparation and the chemical behaviour correspond to the mechanism of the formation of Magnus green salt oxidized product.

Raman study of the structural properties of KNO3(II)

1977 ◽  
Vol 55 (7) ◽  
pp. 1242-1250 ◽  
Author(s):  
M. H. Brooker
Keyword(s):  
Single Crystals ◽  
Structural Properties ◽  
Raman Spectra ◽  
Excellent Agreement ◽  
Room Temperature ◽  
Group Analysis ◽  
Factor Group ◽  
Spectral Features ◽  
Space Group ◽  
Raman Study

Raman spectra of oriented single crystals of KNO3(II) have been recorded at 298 and 77 K. At both temperatures the data are in excellent agreement with the factor group analysis based on the generally accepted Pmcn space group. Additional spectral features observed near room temperature suggest the presence of a significant number of disordered nitrate groups on alternate lattice sites, although the majority of nitrate groups occupy the ordered sites. As the temperature is lowered, the disordered groups freeze out until near the temperature of reported electrical anomalies (213 K) only the ordered sites are occupied. Improved resolution has resulted in detection of a number of new spectral features while improved depolarization data have resulted in reassignment of several peaks.

Refinement of the layered titanosilicate AM-1 from single-crystal X-ray diffraction data

2007 ◽  
Vol 63 (11) ◽  
pp. i186-i186 ◽  
Author(s):  
Stanislav Ferdov ◽  
Uwe Kolitsch ◽  
Christian Lengauer ◽  
Ekkehart Tillmanns ◽  
Zhi Lin ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Hydrogen Bonding ◽  
Single Crystal ◽  
Single Crystals ◽  
Diffraction Data ◽  
X Ray Diffraction ◽  
X Ray ◽  
First Time ◽  
Ir And Raman ◽  
Bonding Scheme

The structure of the layered noncentrosymmetric titanosilicate AM-1 (also known as JDF-L1, disodium titanium tetrasilicate dihydrate), Na4Ti2Si8O22·4H2O, grown as small single crystals without the use of organics, has been refined from single-crystal X-ray diffraction data. The H atom has been located for the first time, and the hydrogen-bonding scheme is also characterized by IR and Raman spectroscopy. All atoms are in general positions except for the Na, the Ti, one Ti-bound O, one Si-bound O and the water O atoms (site symmetries 2, 4, 4, 2 and 2, respectively).

Identification of hydrogen bond modes in polarized Raman spectra of single crystals of α-oxalic acid dihydrate

2009 ◽  
Vol 40 (11) ◽  
pp. 1605-1614 ◽  
Author(s):  
Vlasta Mohaček-Grošev ◽  
Jože Grdadolnik ◽  
Jernej Stare ◽  
Dušan Hadži
Keyword(s):  
Hydrogen Bond ◽  
Oxalic Acid ◽  
Single Crystals ◽  
Raman Spectra ◽  
Oxalic Acid Dihydrate ◽  
Polarized Raman

Characteristic Investigations of Stoichiometric LiNbO3 Single Crystal Fiber Co-Doped with Tb and Mn

2004 ◽  
Vol 449-452 ◽  
pp. 985-988
Author(s):  
S.M. Lee ◽  
J.W. Shur ◽  
T.I. Shin ◽  
W.S. Yang ◽  
G.Y. Kim ◽  
...  
Keyword(s):  
Absorption Band ◽  
Single Crystal ◽  
Optical Microscopy ◽  
Single Crystals ◽  
Absorption Spectra ◽  
Room Temperature ◽  
Crystal Fiber ◽  
Ft Ir ◽  
Homogeneous Distributions ◽  
Co Doped

[MnO2(1.0mol%) : Tb4O7(0.5mo%)] doped stoichiometric LiNbO3 (Mn:Tb:SLN) single crystals of 0.5~1.0 mm in diameter and 30~35 mm in length were grown by micro pulling down(µ-PD) method. We investigated the photoluminescence (PL) properties of Mn:Tb:SLN single crystal. The OH- absorption band of the single crystals observed infrared the absorption spectra by using an FT-IR spectrophotometer at room temperature. Homogeneous distributions of Mn and Tb concentration were confirmed by the EPMA and observed defects by optical microscopy.

Polarized Raman spectra of superconducting and semiconducting YBa2Cu3Ox single crystals

1988 ◽  
Vol 153-155 ◽  
pp. 290-291 ◽  
Author(s):  
V.G. Hadjiev ◽  
M.N. Iliev ◽  
P.G. Vassilev
Keyword(s):  
Single Crystals ◽  
Raman Spectra ◽  
Polarized Raman
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