The dependence of acid dissociation constants in water on temperature as expressed by the Gurney equation

Michael J. Blandamer; John Burgess; Philip P. Duce; Ross E. Robertson; John W. M. Scott

doi:10.1139/v81-412

The dependence of acid dissociation constants in water on temperature as expressed by the Gurney equation

Canadian Journal of Chemistry ◽

10.1139/v81-412 ◽

1981 ◽

Vol 59 (19) ◽

pp. 2845-2847 ◽

Cited By ~ 6

Author(s):

Michael J. Blandamer ◽

John Burgess ◽

Philip P. Duce ◽

Ross E. Robertson ◽

John W. M. Scott

Keyword(s):

Carboxylic Acids ◽

Newton Method ◽

Dissociation Constants ◽

Acid Dissociation ◽

Acid Dissociation Constants

The dependence on temperature of the acid dissociation constants in water for a range of carboxylic acids has been fitted to the Gurney equation using a modified Gauss–Newton method. The equation fits the data reasonably well and identifies the dependence on temperature of the electrical and non-electrical contributions to ln K.

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Analysis of the dependence on temperature of the acid dissociation constants for mono-carboxylic acids in water in terms of a two-stage mechanism

Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases ◽

10.1039/f19817702281 ◽

1981 ◽

Vol 77 (9) ◽

pp. 2281 ◽

Cited By ~ 3

Author(s):

Michael J. Blandamer ◽

John Burgess ◽

Philip P. Duce ◽

Ross E. Robertson ◽

John W. M. Scott

Keyword(s):

Carboxylic Acids ◽

Dissociation Constants ◽

Acid Dissociation ◽

Two Stage ◽

Acid Dissociation Constants

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Solvent extraction equilibria of copper(II) by carboxylic acids with high acid dissociation constants

Hydrometallurgy ◽

10.1016/0304-386x(88)90005-9 ◽

1988 ◽

Vol 21 (2) ◽

pp. 203-212 ◽

Cited By ~ 7

Author(s):

Yoshinari Baba ◽

Katsutoshi Inoue

Keyword(s):

Solvent Extraction ◽

Carboxylic Acids ◽

Dissociation Constants ◽

Acid Dissociation ◽

Acid Dissociation Constants ◽

High Acid ◽

Extraction Equilibria

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The Measurement and Correlation of Acid Dissociation Constants for Carboxylic Acids in the System Ethanol-Water. Activity Coefficients and Empirical Activity Functions1a

Journal of the American Chemical Society ◽

10.1021/ja01154a139 ◽

1951 ◽

Vol 73 (10) ◽

pp. 4939-4944 ◽

Cited By ~ 91

Author(s):

Ernest Grunwald ◽

Benjamin J. Berkowitz

Keyword(s):

Carboxylic Acids ◽

Water Activity ◽

Activity Coefficients ◽

Dissociation Constants ◽

Acid Dissociation ◽

Acid Dissociation Constants

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THE POTENTIOMETRIC MEASUREMENT OF ACID DISSOCIATION CONSTANTS ANDpH IN THE SYSTEM METHANOL-WATER.pKAVALUES FOR CARBOXYLIC ACIDS AND ANILINIUM IONS

The Journal of Organic Chemistry ◽

10.1021/jo01124a007 ◽

1955 ◽

Vol 20 (6) ◽

pp. 747-762 ◽

Cited By ~ 106

Author(s):

A. L. BACARELLA ◽

ERNEST. GRUNWALD ◽

H. P. MARSHALL ◽

E. LEE. PURLEE

Keyword(s):

Carboxylic Acids ◽

Dissociation Constants ◽

Acid Dissociation ◽

Acid Dissociation Constants ◽

Potentiometric Measurement

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The Measurement of Acid Dissociation Constants and Ion-pair Dissociation Constants in Solvents of Intermediate Dielectric Constant. Carboxylic Acids and their Sodium and Potassium Salts in 70% Dioxane-30% Water1

Journal of the American Chemical Society ◽

10.1021/ja01563a030 ◽

1957 ◽

Vol 79 (6) ◽

pp. 1372-1376

Author(s):

E. Lee Purlee ◽

Ernest Grunwald

Keyword(s):

Dielectric Constant ◽

Carboxylic Acids ◽

Dissociation Constants ◽

Ion Pair ◽

Acid Dissociation ◽

Potassium Salts ◽

Acid Dissociation Constants ◽

Sodium And Potassium

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Analyses of the Acid Dissociation Constants of Multisubstituted Diarylamines Measured in Solvents and Micellar System

Bulletin of the Chemical Society of Japan ◽

10.1246/bcsj.67.800 ◽

1994 ◽

Vol 67 (3) ◽

pp. 800-806 ◽

Cited By ~ 1

Author(s):

Ze-jian Guo ◽

Hideto Miyoshi ◽

Toshio Fujita

Keyword(s):

Dissociation Constants ◽

Acid Dissociation ◽

Micellar System ◽

Acid Dissociation Constants

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ChemInform Abstract: Determination of the Acid Dissociation Constants for Some Mycotoxins of the Alternaria alternata genus.

ChemInform ◽

10.1002/chin.199852305 ◽

2010 ◽

Vol 29 (52) ◽

pp. no-no

Author(s):

P. G. MOLINA ◽

M. A. ZON ◽

H. FERNANDEZ

Keyword(s):

Alternaria Alternata ◽

Dissociation Constants ◽

Acid Dissociation ◽

Acid Dissociation Constants

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Acid dissociation constants and pH values for standard “bes” and “tricine” buffer solutions in 30, 40, and 50 mass% dimethyl sulfoxide/water between 25 and −25 °C

Cryobiology ◽

10.1016/0011-2240(85)90036-7 ◽

1985 ◽

Vol 22 (6) ◽

pp. 589-600 ◽

Cited By ~ 6

Author(s):

Rabindra N. Roy ◽

James J. Gibbons ◽

Gigi E. Baker

Keyword(s):

Dimethyl Sulfoxide ◽

Dissociation Constants ◽

Acid Dissociation ◽

Acid Dissociation Constants ◽

Buffer Solutions ◽

Ph Values

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Formation and Reactivity of a Porphyrin Iridium Hydride in Water: Acid Dissociation Constants and Equilibrium Thermodynamics Relevant to Ir–H, Ir–OH, and Ir–CH2– Bond Dissociation Energetics

Inorganic Chemistry ◽

10.1021/ic201553k ◽

2011 ◽

Vol 50 (21) ◽

pp. 11011-11020 ◽

Cited By ~ 24

Author(s):

Salome Bhagan ◽

Bradford B. Wayland

Keyword(s):

Dissociation Constants ◽

Acid Dissociation ◽

Equilibrium Thermodynamics ◽

Acid Dissociation Constants ◽

Bond Dissociation

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Acid dissociation constants and copper chelate formation constants of thiazolylthiourea derivatives

BUNSEKI KAGAKU ◽

10.2116/bunsekikagaku.10.1122 ◽

1961 ◽

Vol 10 (10) ◽

pp. 1122-1124 ◽

Cited By ~ 1

Author(s):

Toyozo UNO ◽

Sumiyuki AKIHAMA ◽

Kuniko TERADA

Keyword(s):

Dissociation Constants ◽

Formation Constants ◽

Acid Dissociation ◽

Copper Chelate ◽

Acid Dissociation Constants ◽

Chelate Formation

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