Effect of CdI2 on electrical conductivity and phase transition behavior in AgI

1981 ◽  
Vol 59 (18) ◽  
pp. 2685-2688 ◽  
Author(s):  
Mahadeva Natarajan ◽  
Etalo A. Secco

The phase transitions occurring in AgI containing dissolved CdI2 have been examined by differential thermal analysis (DTA), electrical conductivity technique, and X-ray diffractometry. The electrical conductivity and polymorphic behavior of AgI is significantly modified by low concentrations of CdI2. The results are interpreted in terms of substitutional Cd2+ and Ag+ vacancies in AgI sublattice.

1979 ◽  
Vol 57 (20) ◽  
pp. 2703-2706 ◽  
Author(s):  
Mahadeva Natarajan ◽  
Etalo A. Secco

The phase transformations occurring in K2Cr2O7 have been examined by differential thermal analysis (DTA), differential scanning calorimetry (DSC), specific heat measurements, electrical conductivity technique, and X-ray diffractometry. The results show that the polymorphic behavior of K2Cr2O7 is very sensitive to the thermal and preparative history of the sample.


2019 ◽  
Vol 33 (28) ◽  
pp. 1950339 ◽  
Author(s):  
Y. I. Aliyev ◽  
P. R. Khalilzade ◽  
Y. G. Asadov ◽  
T. M. Ilyasli ◽  
F. M. Mammadov ◽  
...  

AgCu[Formula: see text]Fe[Formula: see text]S compounds were synthesized by partial Cu[Formula: see text][Formula: see text][Formula: see text]Fe replacement in the AgCuS crystal at a concentration range of 0[Formula: see text][Formula: see text][Formula: see text]x[Formula: see text][Formula: see text][Formula: see text]0.03. In the differential thermal analysis spectrum obtained at a temperature range of 300 K[Formula: see text][Formula: see text][Formula: see text]T[Formula: see text][Formula: see text][Formula: see text]1300 K, endoeffect corresponding to the structural phase transition in the AgCuS compound was observed at the temperature T[Formula: see text]=[Formula: see text]938 K. It has been determined that this result is also observed in the AgCu[Formula: see text]Fe[Formula: see text]S compound obtained by partial replacement of Cu atoms by Fe atoms. However, in the compound of AgCu[Formula: see text]Fe[Formula: see text]S this effect was observed at higher temperatures. The thermal capacities and enthalpies of phase transitions were calculated for the given compounds.


2009 ◽  
Vol 180 (17-19) ◽  
pp. 1034-1039 ◽  
Author(s):  
Takeshi Ohzeki ◽  
Shinya Hasegawa ◽  
Misa Shimizu ◽  
Takuya Hashimoto

1992 ◽  
Vol 31 (Part 1, No. 9B) ◽  
pp. 3241-3244 ◽  
Author(s):  
Makoto Kuwabara ◽  
Seiji Takahashi ◽  
Koji Goda ◽  
Kenji Oshima ◽  
Koichiro Watanabe

Sign in / Sign up

Export Citation Format

Share Document