Spin–lattice relaxation in MBBA and MBBA – carbon tetrachloride mixtures

1980 ◽  
Vol 58 (21) ◽  
pp. 2246-2249 ◽  
Author(s):  
Margaret A. Heldman ◽  
D. F. R. Gilson

The spin–lattice relaxation time has been measured at 33 MHz as a function of temperature for the liquid crystal MBBA and mixtures with carbon tetrachloride. The behaviour of T1, close to the nematic–isotropic transition can be explained if the correct order fluctuation dependence is included. Diffusion constants calculated from fits to the self-diffusion contribution to relaxation are in agreement with existing results.

2000 ◽  
Vol 55 (3-4) ◽  
pp. 412-414 ◽  
Author(s):  
Hiroyuki Ishida

Abstract The reorientation of the tetrahedral complex anion ZnCl42- and the self-diffusion of the cation in (CH3NH3)2ZnCl4 were studied by 1H NMR spin-lattice relaxation time (1H T1) experiments. In the second highest-temperature phase, the temperature dependence of 1H T1 observed at 8.5 MHz could be explained by a magnetic dipolar-electric quadrupolar cross relaxation between 1H and chlorine nuclei, and the activation energy of the anion motion was determined to be 105 kJ mol -1 . In the highest-temperature phase, the activation energy of the self-diffusion of the cation was determined to be 58 kJ mol -1 from the temperature and frequency dependence of 1H T1


1978 ◽  
Vol 39 (C6) ◽  
pp. C6-1215-C6-1216
Author(s):  
H. Ahola ◽  
G.J. Ehnholm ◽  
S.T. Islander ◽  
B. Rantala

1988 ◽  
Vol 11 (2) ◽  
pp. 97-102 ◽  
Author(s):  
Kiichiro Matsumura ◽  
Imaharu Nakano ◽  
Nobuo Fukuda ◽  
Hiroo Ikehira ◽  
Yukio Tateno ◽  
...  

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