On the reliability of the inversion of the Arrhenius rate law

1979 ◽  
Vol 57 (18) ◽  
pp. 2458-2463 ◽  
Author(s):  
Andrew W. Yau ◽  
Huw O. Pritchard

A numerical test of the reliability of the Slater–Forst procedure for the inversion of the Arrhenius rate law is presented using the theoretical data for the reactions N2O → N2 + O and CO2 → CO + O reported previously: the test results are positive. The sensitivity of the procedure to variations in the Arrhenius parameters is also examined.

2020 ◽  
Vol 10 (4) ◽  
pp. 339-348
Author(s):  
Mahmoud Saleh ◽  
Ádám Nagy ◽  
Endre Kovács

This paper is the second part of a paper-series in which we create and examine new numerical methods for solving the heat conduction equation. Now we present numerical test results of the new algorithms which have been constructed using the known, but non-conventional UPFD and odd-even hopscotch methods in Part 1. Here all studied systems have one space dimension and the physical properties of the heat conducting media are uniform. We also examine different possibilities of treating heat sources.


2021 ◽  
Vol 0 (0) ◽  
pp. 0
Author(s):  
Yanjun Wang ◽  
Shisen Liu

<p style='text-indent:20px;'>This paper is concerned with the joint chance constraint for a system of linear inequalities. We discuss computationally tractble relaxations of this constraint based on various probability inequalities, including Chebyshev inequality, Petrov exponential inequalities, and others. Under the linear decision rule and additional assumptions about first and second order moments of the random vector, we establish several upper bounds for a single chance constraint. This approach is then extended to handle the joint linear constraint. It is shown that the relaxed constraints are second-order cone representable. Numerical test results are presented and the problem of how to choose proper probability inequalities is discussed.</p>


2018 ◽  
Vol 231 ◽  
pp. 01004
Author(s):  
Marcin Budzyński ◽  
Dawid Bruski

Horizontal curves, an element of road infrastructure, have a statistically high number of accidents. Considering that horizontal curves in the last ten years have had app. 10% of all road accidents representing app. 14% of all fatalities on Polish roads, the issue is serious and requires more research and proper road safety treatments. Data for 2007 - 2016 show that in the case of accidents on horizontal curves app. 45% of the fatalities happened as a result of crashing into roadside obstacles such as signs and first of all trees. This shows that horizontal curves require road safety equipment, and specifically, safety barriers. Key to this is using the right equipment and the right parameters. To achieve that, full-scale crash tests should be conducted to be followed by numerical tests. The article will present a synthesis of the available research conducted in Poland and abroad. An assessment will be made of four crash tests of TB32 with barriers that have a steel and cable guardrail. They are the outcome of the RID 3A “Road safety equipment” project called RoSE. Building on these tests, numerical test results will be presented.


Geophysics ◽  
1992 ◽  
Vol 57 (6) ◽  
pp. 805-814 ◽  
Author(s):  
Woon Hyun Cho ◽  
Terry W. Spencer

A new algorithm is developed for estimating the moveout velocities and polarization states in mixed wavefields recorded on multicomponent array data in the presence of random noise. The algorithm is applicable to a spatial and temporal data window in which more than two events are present. Three fundamental attributes of the waves are determined: polarization angle, apparent slowness, and the change in amplitude between adjacent detectors. In implementing the method, it is assumed that data is recorded at equispaced geophones located in a spatial window in which the three parameters are constant. Robustness is achieved by averaging the transfer matrix over all combinations of the subarrays that have the same transfer matrix. Application of a least‐squares criterion reduces the mathematics to an eigenvalue problem. The eigenvalues are complex, and their magnitude determines the amplitude change factor. The phase is a linear function of frequency with slope that determines the vertical slowness. The eigenvectors are the polarizations. The input data consists of the cross‐power spectra between subarrays that contain the same number of elements and are shifted by zero or one geophone separation. Examples illustrate the application of the algorithm to synthetic data. Numerical test results show that the performance of the method is not sensitive either to the time overlap between events or to the degree of similarity between waveforms.


2020 ◽  
Vol 12 (3) ◽  
pp. 586 ◽  
Author(s):  
Bihter Erol ◽  
Mustafa Serkan Işık ◽  
Serdar Erol

The launch of dedicated satellite missions at the beginning of the 2000s led to significant improvement in the determination of Earth gravity field models. As a consequence of this progress, both the accuracies and the spatial resolutions of the global geopotential models increased. However, the spectral behaviors and the accuracies of the released models vary mainly depending on their computation strategies. These strategies are briefly explained in this article. Comprehensive quality assessment of the gravity field models by means of spectral and statistical analyses provides a comparison of the gravity field mapping accuracies of these models, as well as providing an understanding of their progress. The practical benefit of these assessments by means of choosing an optimal model with the highest accuracy and best resolution for a specific application is obvious for a broad range of geoscience applications, including geodesy and geophysics, that employ Earth gravity field parameters in their studies. From this perspective, this study aims to evaluate the GOCE High-Level Processing Facility geopotential models including recently published sixth releases using different validation methods recommended in the literature, and investigate their performances comparatively and in addition to some other models, such as GOCO05S, GOGRA04S and EGM2008. In addition to the validation statistics from various countries, the study specifically emphasizes the numerical test results in Turkey. It is concluded that the performance improves from the first generation RL01 models toward the final RL05 models, which were based on the entire mission data. This outcome was confirmed when the releases of different computation approaches were considered. The accuracies of the RL05 models were found to be similar to GOCO05S, GOGRA04S and even to RL06 versions but better than EGM2008, in their maximum expansion degrees. Regarding the results obtained from these tests using the GPS/leveling observations in Turkey, the contribution of the GOCE data to the models was significant, especially between the expansion degrees of 100 and 250. In the study, the tested geopotential models were also considered for detailed geoid modeling using the remove-compute-restore method. It was found that the best-fitting geopotential model with its optimal expansion degree (please see the definition of optimal degree in the article) improved the high-frequency regional geoid model accuracy by almost 15%.


Geophysics ◽  
1997 ◽  
Vol 62 (2) ◽  
pp. 598-613 ◽  
Author(s):  
Jingping Zhe ◽  
Stewart A. Greenhalgh

Prestack elastic migration by displacement potential extrapolation is a mixed, systematic, and function‐blocked vector wavefield migration algorithm. A new wavefield extrapolation method for inhomogeneous media is introduced here according to the following sequence: displacements ← potentials ← extrapolation of the potentials ← displacements, which is relatively accurate and not computer‐time intensive. Traveltimes of both direct downgoing P‐ and S‐waves, which are necessary in elastic migration, are calculated with a modified convolutional acoustic forward modeling program applicable to complex structures. A new image condition based on the time consistent principle is developed. It involves first obtaining an image condition section. Then two images (P P and S S) are obtained from the product of the extrapolated and decomposed P P‐ and S S‐wave displacement amplitudes and the image condition section. All P P‐, P S‐, S P‐ and S S‐waves are considered when the image condition section is calculated. The image condition section minimizes cross‐talk between modes. Compared to previous treatments, the newly developed image condition formula is superior since it allows migration of multicomponent seismic data produced using a combined P and S source. Numerical test results are very encouraging and clearly demonstrate the robustness of the technique. Further work is continuing so as to overcome ray angle and polarity problems in the image condition.


Author(s):  
S. J. Wright ◽  
J. N. Holt

AbstractA method for solving problems of the form is presented. The approach of Levenberg and Marquardt is used, except that the linear least squares subproblem arising at each iteration is not solved exactly, but only to within a certain tolerance. The method is most suited to problems in which the Jacobian matrix is sparse. Use is made of the iterative algorithm LSQR of Paige and Saunders for sparse linear least squares.A global convergence result can be proven, and under certain conditions it can be shown that the method converges quadratically when the sum of squares at the optimal point is zero.Numerical test results for problems of varying residual size are given.


Author(s):  
Bi-Chu Wu ◽  
Shapour Azarm

Abstract In a previous article, a new and simple reduction method was presented for optimization-based design of nonhierarchically decomposed engineering systems. As a sequel to that work, in this paper we first examine some significant issues in relation to the reduction method: the optimality conditions when the method is applied, the reason why move limits are not required, and some of the factors that might affect the robustness of the cumulative constraints. For verification and validation, we then present some numerical test results in which the method is applied to twenty-one (21) test problems. Based on the test results reported, some guidelines for applying the method are suggested.


Geophysics ◽  
2021 ◽  
Vol 86 (6) ◽  
pp. E391-E405
Author(s):  
Keiichi Ishizu ◽  
Yasuo Ogawa

Coastal freshwater provides a water source for more than one billion people living in coastal regions. For sustainable groundwater management in coastal areas, an understanding of freshwater distribution is necessary. Freshwater distribution in a coastal area can extend across the shoreline and into the offshore region. Offshore-onshore mapping of freshwater helps us to gain a comprehensive understanding of the freshwater distribution in coastal areas. Resistivity imaging using electromagnetic methods has been used to reveal the freshwater distribution in coastal areas because electrical resistivity in these settings is primarily controlled by porosity and porewater salinity. We have considered a controlled-source electromagnetic (CSEM) method for offshore-onshore resistivity imaging of freshwater at a depth range of 0–500 m below the seafloor. Our CSEM method is novel in considering an array of onshore-offshore electromagnetic receivers with onshore electric dipole transmitters. We have conducted a feasibility study to investigate the ability of the CSEM method for offshore-onshore resistivity imaging of freshwater in a coastal area. The test results indicate that the method could image the resistivity distribution of freshwater located at a depth of 500 m below the seafloor. Our model study also indicates that the offshore-onshore CSEM method can detect offshore aquifers up to 5 km from the shoreline. These numerical test results imply that our CSEM method is a promising technique for offshore-onshore resistivity imaging of freshwater in coastal areas.


2013 ◽  
Vol 859 ◽  
pp. 463-467
Author(s):  
Shang Wen Yang ◽  
Yong Jie Yan

To solve the airport arrival and departure flow allocation problem under the condition of uncertain capacity, one of robust optimization methods was applied. Applied technology in Robust Optimization Model with the aim to minimize expected delayed flights at certain robustness level was proposed. The robustness factor constraint, airport capacity curve constraint, fix capacity constraint and airport capacity scenario constraint were included. To test how well the model would be in real world, a numerical test was performed based on the data of a Chinese international airport. Test results show that there is a negative relationship between expected delay flights and robustness level. Compared with typical model, Applied Technology in Robust Optimization Model proposed achieves better effect at the same robustness level.


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