13C nuclear magnetic resonance spectra of some C-19-hydroxy, C-5,6 epoxy, C-24 ethyl, and C-19-norsteroids

1978 ◽  
Vol 56 (24) ◽  
pp. 3121-3127 ◽  
Author(s):  
Herbert L. Holland ◽  
Peter R. P. Diakow ◽  
Gregg J. Taylor

The carbon magnetic resonance spectra of a series of C-19 hydroxy, C-5β,6β epoxy, C-5α,6α epoxy, and C-24 ethyl steroids have been assigned. Shift parameters for the C-19 hydroxyl function are listed. The data presented has led to a reassignment of the published spectra of several C5α,6 α epoxy steroids. In addition, 13Cmr spectral data for several bicyclic enones and a Δ5(10)-3-estrone are presented.

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