The oxidation of haplophytine

1978 ◽  
Vol 56 (8) ◽  
pp. 1052-1058 ◽  
Author(s):  
Peter Yates ◽  
Frederick N. MacLachlan ◽  
Ian D. Rae
Keyword(s):  
Hydrogen Peroxide ◽  
Potassium Permanganate ◽  
Spectroscopic Data ◽  
Bond Cleavage ◽  
Cleavage Product ◽  
Alkaline Hydrogen Peroxide ◽  
Carbon Bond ◽  
Carbon Carbon Bond ◽  
Acid Cleavage

Oxidation of haplophytine (1) with alkaline potassium permanganate has been shown to give the seco product 16. This assignment is based on spectroscopic data and comparison of these with spectroscopic data for the analogous seco product 8 formed on similar oxidation of aspidophytine (3), an acid cleavage product of haplophytine. The course of these oxidations contrasts with that of the oxidation of haplophytine and aspidophytine with alkaline hydrogen peroxide, which gives 4 and 6, respectively, without carbon–carbon bond cleavage.

Synthesis of 2-(Cyanomethyl)benzoic Esters via Carbon–Carbon Bond Cleavage of Indanones

2021 ◽  
Author(s):  
Xiangtai Meng ◽  
Dengfeng Chen ◽  
Rui Liu ◽  
Ping Jiang ◽  
Shenlin Huang
Keyword(s):  
Bond Cleavage ◽  
Carbon Bond ◽  
Carbon Carbon Bond

Aerobic Dehydrogenative α-Diarylation of Benzyl Ketones with Aromatics through Carbon–Carbon Bond Cleavage

2014 ◽  
Vol 16 (3) ◽  
pp. 804-807 ◽  
Author(s):  
Nagnath Yadav More ◽  
Masilamani Jeganmohan
Keyword(s):  
Bond Cleavage ◽  
Carbon Bond ◽  
Carbon Carbon Bond
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