The sulfohaloform reaction. The stepwise conversion of dialkyl sulfides into alkanesulfonyl chlorides

1977 ◽  
Vol 55 (3) ◽  
pp. 407-420 ◽  
Author(s):  
J. Stuart Grossert ◽  
Richard F. Langler
Keyword(s):  
Oxidative Cleavage ◽  
Cleavage Reaction ◽  
Structural Requirements ◽  
Sulfonyl Chlorides ◽  
Oxidative Chlorination ◽  
Dialkyl Sulfides ◽  
General Synthesis

A thorough examination of the aqueous oxidative chlorination of 1,3,5-trithiane is described. The results are utilized to explore and delineate the scope of a general, stepwise, oxidative cleavage reaction of dialkyl sulfides in which they are successively halogenated and oxidized to α-polychlorosulfoxides; subsequently, these cleave to form sulfinyl chlorides, which hydrolyze and become further oxidized to yield alkanesulfonyl chlorides. The overall stepwise process is named the 'Sulfohaloform reaction' and the structural requirements of the substrates at each step are explored in detail. A practical, general synthesis of sulfonyl chlorides is presented.

A new catalytic oxidative cleavage reaction to furnish lactones

2008 ◽  
pp. 6411 ◽  
Author(s):  
Stefanie Roth ◽  
Christian B. W. Stark
Keyword(s):  
Oxidative Cleavage ◽  
Cleavage Reaction

scholarly journals Oxidative Cleavage Reaction of 3-Substituted Indoles Catalyzed by CuCl–Pyridine Complex under Oxygen

1981 ◽  
Vol 54 (8) ◽  
pp. 2369-2373 ◽  
Author(s):  
Jiro Tsuji ◽  
Hiroaki Kezuka ◽  
Hiroshi Takayanagi ◽  
Keiji Yamamoto
Keyword(s):  
Oxidative Cleavage ◽  
Cleavage Reaction ◽  
Pyridine Complex

Oxidative Cleavage Reaction of Substituted Indoles Catalyzed by Plant Cell Cultures.

ChemInform ◽  
2007 ◽  
Vol 38 (39) ◽  
Author(s):  
Masumi Takemoto ◽  
Yasutaka Iwakiri ◽  
Kiyoshi Tanaka
Keyword(s):  
Plant Cell ◽  
Cell Cultures ◽  
Oxidative Cleavage ◽  
Plant Cell Cultures ◽  
Cleavage Reaction

Synthesis of 3-[(coumarinyl)carbonyl]-3a,8b-dihyroindeno[1,2-b]pyrrole-4(1H)-ones and their conversion to coumarin bearing spiro[isobenzofuran-1,2′-pyrrole] moiety compounds via oxidative cleavage reaction

RSC Advances ◽  
2015 ◽  
Vol 5 (98) ◽  
pp. 80518-80525 ◽  
Author(s):  
Abdolali Alizadeh ◽  
Rashid Ghanbaripour ◽  
Masoumeh Feizabadi ◽  
Long-Guan Zhu ◽  
Michal Dusek
Keyword(s):  
Oxidative Cleavage ◽  
Coumarin Derivatives ◽  
Cleavage Reaction ◽  
Sequential Reaction

The synthesis of substituted coumarin derivatives bearing indenopyrrole and spiro[isobenzofuran-1,2′-pyrrole] in a four-component sequential reaction and following oxidative cleavage reaction.

scholarly journals A novel oxidative cleavage reaction with Pb(OAc)4 via dithioacetal derivatives.

1980 ◽  
Vol 28 (2) ◽  
pp. 558-566 ◽  
Author(s):  
KUNIO HIROI ◽  
SHUKO SATO ◽  
KAZUHIDE MATSUO
Keyword(s):  
Oxidative Cleavage ◽  
Cleavage Reaction
Sign in / Sign up

Export Citation Format

Share Document