The application of iterative optimization techniques to chemical kinetic data of large random error

1976 ◽  
Vol 54 (21) ◽  
pp. 3330-3341 ◽  
Author(s):  
George H. Schmid ◽  
Valeria M. Csizmadia ◽  
Paul G. Mezey ◽  
Imre G. Csizmadia

The possibilities of improving the computational processing of chemical rate measurements, in the frame of linear and non-linear least-square fit methods, are investigated. A simple scaling technique to avoid the distortion of the fitted parameters, inherent in the logarithmic transformation of the rate equation, is tested on several examples, and an iterative discarding method for the selection of accurate data points is recommended.

1998 ◽  
Vol 120 (3) ◽  
pp. 689-694 ◽  
Author(s):  
R. Kashani

A technique based on the innovations approach to linear least square identification is proposed for experimental state space modeling of flexible structures. Upon the selection of the model structure and order, the unknown parameters are identified by minimizing the sum of squares of the innovations process. Contrary to having a black-box approach to experimental modeling, this technique uses physical parameterization of the structural dynamics, as well as measurement noise properties. The innovations approach to experimental modeling of the flexible structures automates the identification of unknown parameters in the model and reduces the number of these unknowns to its minimum resulting in small variances in their estimated values. The effectiveness of this experimental modeling technique is demonstrated by accurately identifying the modal information of a rectangular flexible plate, free at two sides and fixed at the other two. The plate is patched with PZT actuators and nearly-collocated sensors at two locations.


2019 ◽  
Vol 105 (6) ◽  
pp. 1217-1227 ◽  
Author(s):  
Tom Colinot ◽  
Philippe Guillemain ◽  
Jean-Baptiste Doc ◽  
Christophe Vergez ◽  
Michael Jousserand

This paper explores the analogy between a saxophone resonator and a bicylindrical resonator, sometimes called transverse saxophone or cylindrical saxophone. The dimensions of a bicylindrical resonator are optimized numerically to approximate a saxophone impedance. The target is the impedance measured on an usual saxophone. A classical gradient-based non-linear least-square fit function is used. Several cost functions corresponding to distances to the target impedance are assessed, according to their influence on the optimal geometry. Compromises appear between the frequency regions depending on the cost function. It is shown that the chosen cost functions are differentiable and locally convex. The convexity region contains the initial geometrical dimensions obtained by crude approximation of the first resonance frequency of the target. One optimal geometry is submitted to further analysis using descriptors of the impedance. Its deviations from the target saxophone are put into perspective with the discrepancies between the target saxophone and a saxophone from a different manufacture. Descriptors such as harmonicity or impedance peak ratio set the bicylindrical resonator apart from saxophone resonators, despite a good agreement of the resonance frequencies. Therefore, a reed instrument with a bicylindrical resonator could be tuned to produce the same notes as a saxophone, but due to differences in the intrinsic characteristics of the resonator, it should be considered not as a saxophone but as a distinct instrument.


2019 ◽  
Vol 201 (1) ◽  
pp. 155-162
Author(s):  
S. Bharadwaj ◽  
Suman Kumar Burnwal ◽  
Subimal Deb ◽  
S. Ragini ◽  
S. R. Murthy

We present a comparative study of the variation in dielectric relaxation for the additives SiO2, TiO2 and ZrO2 in cobalt ferrite. CoFe2O4 was prepared using microwave hydrothermal system and sintered at 900 °C/30 min using microwave sintering method. Real and imaginary parts of permittivity were measured in the frequency range of 1 MHz to 1.8 GHz for these samples. A shift in the dielectric relaxation towards higher frequencies for doped samples is observed as expected in percolating systems. A non-linear least square fit of the electron oscillator model is used to parameterize absorption in the samples.


Author(s):  
Kjersti Gjønnes ◽  
Jon Gjønnes

Electron diffraction intensities can be obtained at large scattering angles (sinθ/λ ≥ 2.0), and thus structure information can be collected in regions of reciprocal space that are not accessable with other diffraction methods. LACBED intensities in this range can be utilized for determination of accurate temperature factors or for refinement of coordinates. Such high index reflections can usually be treated kinematically or as a pertubed two-beam case. Application to Y Ba2Cu3O7 shows that a least square refinememt based on integrated intensities can determine temperature factors or coordinates.LACBED patterns taken in the (00l) systematic row show an easily recognisable pattern of narrow bands from reflections in the range 15 < l < 40 (figure 1). Integrated intensities obtained from measured intensity profiles after subtraction of inelastic background (figure 2) were used in the least square fit for determination of temperature factors and refinement of z-coordinates for the Ba- and Cu-atoms.


GEOMATIKA ◽  
2020 ◽  
Vol 26 (2) ◽  
pp. 107
Author(s):  
Leni Sophia Heliani ◽  
Cecep Pratama ◽  
Parseno Parseno ◽  
Nurrohmat Widjajanti ◽  
Dwi Lestari

<p><em>Sangihe-Moluccas region is the most active seismicity in Indonesia. Between 2015 to 2018 there is four M6 class earthquake occurred close to the Sangihe-Moluccas region. These seismic active regions representing active deformation which is recorded on installed GPS for both campaign and continuous station. However, the origin of those frequent earthquakes has not been well understood especially related to GPS-derived secular motion. Therefore, we intend to estimate the secular motion inside and around Sangihe island. On the other hand, we also evaluate the effect of seismicity on GPS sites. Since our GPS data were conducted on yearly basis, we used an empirical global model of surface displacement due to coseismic activity. We calculate the offset that may be contained in the GPS site during its period</em><em>. </em><em>We remove the offset and estimate again the secular motion using linear least square. Hence, in comparison with the secular motion without considering the seismicity, we observe small change but systematically shifting the motion. We concluded the seismicity in the Molucca sea from 2015 to 2018 systematically change the secular motion around Sangihe Island at the sub-mm level. Finally, we obtained the secular motion toward each other between the east and west side within 1 to 5.5 cm/year displacement. </em></p>


Sensors ◽  
2021 ◽  
Vol 21 (3) ◽  
pp. 920
Author(s):  
Neha Chaudhary ◽  
Othman Isam Younus ◽  
Luis Nero Alves ◽  
Zabih Ghassemlooy ◽  
Stanislav Zvanovec ◽  
...  

The accuracy of the received signal strength-based visible light positioning (VLP) system in indoor applications is constrained by the tilt angles of transmitters (Txs) and receivers as well as multipath reflections. In this paper, for the first time, we show that tilting the Tx can be beneficial in VLP systems considering both line of sight (LoS) and non-line of sight transmission paths. With the Txs oriented towards the center of the receiving plane (i.e., the pointing center F), the received power level is maximized due to the LoS components on F. We also show that the proposed scheme offers a significant accuracy improvement of up to ~66% compared with a typical non-tilted Tx VLP at a dedicated location within a room using a low complex linear least square algorithm with polynomial regression. The effect of tilting the Tx on the lighting uniformity is also investigated and results proved that the uniformity achieved complies with the European Standard EN 12464-1. Furthermore, we show that the accuracy of VLP can be further enhanced with a minimum positioning error of 8 mm by changing the height of F.


Author(s):  
Deepika Saini ◽  
Sanoj Kumar ◽  
Manoj K. Singh ◽  
Musrrat Ali

AbstractThe key job here in the presented work is to investigate the performance of Generalized Ant Colony Optimizer (GACO) model in order to evolve the shape of three dimensional free-form Non Uniform Rational B-Spline (NURBS) curve using stereo (two) views. GACO model is a blend of two well known meta-heuristic optimization algorithms known as Simple Ant Colony and Global Ant Colony Optimization algorithms. Basically, the work talks about the solution of NURBS-fitting based reconstruction process. Therefore, GACO model is used to optimize the NURBS parameters (control points and weights) by minimizing the weighted least-square errors between the data points and the fitted NURBS curve. The algorithm is applied by first assuming some pre-fixed values of NURBS parameters. The experiments clearly show that the optimization procedure is a better option in a case where good initial locations of parameters are selected. A detailed experimental analysis is given in support of our algorithm. The implemented error analysis shows that the proposed methodology perform better as compared to the conventional methods.


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