Alkylation of the dimethylglyoximato ligands in reduced cobaloxime

1976 ◽  
Vol 54 (9) ◽  
pp. 1425-1427 ◽  
Author(s):  
Richard B. Silverman ◽  
D. Dolphin
Keyword(s):  
Methyl Ether ◽  
Alkyl Halides ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Atom Transfer Reactions

Cobalt(II) cobaloximes can undergo atom transfer reactions with certain alkyl halides to give the corresponding alkyl cobalt(III) cobaloximes. However, in the presence of powerfully electrophilic alkyl halides, such as chloromethyl methyl ether, reaction at the periphery, and not at the cobalt, occurs to give dimethylglyoxime-O-methoxymethyl ether.

Nonclassical oxygen atom transfer reactions of an eight-coordinate dioxomolybdenum(vi) complex

2021 ◽  
Author(s):  
Leila G. Ranis ◽  
Jacqueline Gianino ◽  
Justin M. Hoffman ◽  
Seth N. Brown
Keyword(s):  
Oxygen Atom ◽  
Transfer Reaction ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Oxygen Atom Transfer Reactions ◽  
Atom Transfer Reactions ◽  
Oxygen Atoms

Eight-coordinate MoO2(DOPOQ)2 can donate two oxygen atoms to substrates such as phosphines in a four-electron nonclassical oxygen atom transfer reaction.

Structure of the activated complex in atom-transfer reactions

1971 ◽  
Vol 93 (11) ◽  
pp. 2819-2820 ◽  
Author(s):  
Charles Sidney Johnson ◽  
Ann B. Gooch ◽  
Robert G. Griffin ◽  
Raymond Chang
Keyword(s):  
Transfer Reactions ◽  
Atom Transfer ◽  
Atom Transfer Reactions ◽  
Activated Complex
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