The ionic free energy and enthalpy of In3+ ion, and some other properties of indium trichloride

1976 ◽  
Vol 54 (5) ◽  
pp. 703-705 ◽  
Author(s):  
Alan N. Campbell
Keyword(s):  
Free Energy ◽  
Enthalpy Of Formation ◽  
Ethyl Ether ◽  
Cane Sugar ◽  
Butyl Alcohol ◽  
Hydrolysis Constant ◽  
Alcohol Water ◽  
Partially Miscible ◽  
Entropy Of Formation

The following properties have been investigated: the standard ionic free energy and ionic enthalpy of formation of In3+ ion, in water at 25 °C. They are: ΔG0 = −22.9 ± 0.2 kcal mol−1, ΔH0 = −57.8 ± 0.2 kcal mol−1. The entropy of formation of InCl3(aq) has also been determined.In addition, the partially miscible systems indium trichloride – ethyl ether – water, and indium trichloride – n-butyl alcohol – water have been investigated.A solution of indium trichloride causes the inversion of cane sugar. On the assumption that this is due to hydrolysis, the hydrolysis constant has been calculated.

Freeze-drying of liposomes using tertiary butyl alcohol/water cosolvent systems

2006 ◽  
Vol 312 (1-2) ◽  
pp. 131-136 ◽  
Author(s):  
JingXia Cui ◽  
ChunLei Li ◽  
YingJie Deng ◽  
YongLi Wang ◽  
Wei Wang
Keyword(s):  
Freeze Drying ◽  
Butyl Alcohol ◽  
Tertiary Butyl Alcohol ◽  
Tertiary Butyl ◽  
Alcohol Water

scholarly journals The multivariate calculation of material balances of flowsheets for separating ternary mixtures of different physical-chemical nature

2016 ◽  
Vol 11 (3) ◽  
pp. 47-57 ◽  
Author(s):  
A. V. Frolkova ◽  
M. A. Ablizin ◽  
M. A. Mayevskiy ◽  
A. K. Frolkova
Keyword(s):  
Phase Diagrams ◽  
Chemical Nature ◽  
Material Balance ◽  
Ternary Systems ◽  
Butyl Alcohol ◽  
Ternary Mixtures ◽  
Two Phase ◽  
Physical Chemical ◽  
Alcohol Water

An approach to the determination of free variables required for calculating the material balance of the flowsheet of ternary mixtures separation is presented. Phase diagrams of the considered ternary systems are characterized by the presence of a two-phase splitting area and by the presence of different amounts of azeotropes (classes 3.1.0, 3.1.1, 3.2.1 and 3.3.1). For all the systems flowsheets containing three rectification columns and a florentine vessel for separation were suggested. The multivariance of the solution of the balance problem was shown. The approach was illustrated by the example of real ternary systems characterized by different phase diagrams (methanol - chloroform - water, butyl alcohol - water - toluene, nitromethane - hexane - water). The parameters of the rectification columns were presented.

Diffusive dynamics of water in tert-butyl alcohol/water mixtures

2004 ◽  
Vol 120 (10) ◽  
pp. 4759-4767 ◽  
Author(s):  
Vania Calandrini ◽  
Antonio Deriu ◽  
Giuseppe Onori ◽  
Ruep E. Lechner ◽  
Jörg Pieper
Keyword(s):  
Butyl Alcohol ◽  
Tert Butyl ◽  
Tert Butyl Alcohol ◽  
Alcohol Water ◽  
Diffusive Dynamics

Effect of Different Salts on the Solubilities of Benzene and Diphenyl in t-Butyl Alcohol-Water Mixture and Hydrophobic Interaction

2010 ◽  
Vol 20 (1) ◽  
pp. 1-8
Author(s):  
Li-Zhuang Zou ◽  
Xiao-Ling Wang ◽  
Shu-Quan Zhu ◽  
Bu-Xing Han ◽  
Rui-Lin Liu ◽  
...  
Keyword(s):  
Hydrophobic Interaction ◽  
Butyl Alcohol ◽  
Water Mixture ◽  
Alcohol Water
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