Liquid Bismuth Calorimetry: Enthalpies of Solution of Copper, Indium, and Tellurium, and Enthalpies of Formation of Cuprous Selenides

1973 ◽  
Vol 51 (8) ◽  
pp. 1235-1244 ◽  
Author(s):  
Kenneth Gordon Skeoch ◽  
Robert Donald Heyding
Keyword(s):  
Liquid Metal ◽  
Enthalpies Of Formation ◽  
Enthalpies Of Solution ◽  
Metal Solution ◽  
Liquid Bismuth ◽  
Copper Indium ◽  
Solution Calorimeter ◽  
Liquid Metal Solution

An isoperibol liquid metal solution calorimeter in which samples are introduced below the surface of the melt is described. Enthalpies of solution in liquid bismuth at ca. 625°K in kcal mol−1 were found to be +0.99 ± 0.05 for copper, −1.41 ± 0.08 for indium, and −1.16 ± 0.07 for tellurium.Enthalpies of formation in kcal mol−1 at 625°K of cubic cuprous selenides are −7.98 ± 0.20 for Cu1.80Se; −7.80 ± 0.19 for Cu1.85Se; −5.92 ± 0.20 for Cu1.90Se; −5.29 ± 0.20 for Cu1.95Se; and −5.21 ± 0.14 for Cu2.00Se.

Liquid metal solution calorimeter II

1966 ◽  
Vol 43 (5) ◽  
pp. 306-309 ◽  
Author(s):  
A K Jena ◽  
J S Ll Leach
Keyword(s):  
Liquid Metal ◽  
Metal Solution ◽  
Solution Calorimeter ◽  
Liquid Metal Solution

Liquid Metal Solution Calorimeter

1962 ◽  
Vol 33 (6) ◽  
pp. 619-624 ◽  
Author(s):  
B. W. Howlett ◽  
J. S. Ll. Leach ◽  
L. B. Ticknor ◽  
M. B. Bever
Keyword(s):  
Liquid Metal ◽  
Metal Solution ◽  
Solution Calorimeter ◽  
Liquid Metal Solution

Liquid metal solution calorimeter

1965 ◽  
Vol 42 (4) ◽  
pp. 192-197 ◽  
Author(s):  
S Kravitz ◽  
J S Ll Leach
Keyword(s):  
Liquid Metal ◽  
Metal Solution ◽  
Solution Calorimeter ◽  
Liquid Metal Solution

Twin Liquid Metal Solution Calorimeter

1966 ◽  
Vol 37 (2) ◽  
pp. 164-167 ◽  
Author(s):  
J. B. Darby ◽  
R. Kleb ◽  
O. J. Kleppa
Keyword(s):  
Liquid Metal ◽  
Metal Solution ◽  
Solution Calorimeter ◽  
Liquid Metal Solution

A linear chemical-physical theory model for liquid metal solution thermodynamics

AIChE Journal ◽  
1988 ◽  
Vol 34 (9) ◽  
pp. 1477-1485 ◽  
Author(s):  
Wayne J. Howell ◽  
Carl T. Lira ◽  
Charles A. Eckert
Keyword(s):  
Liquid Metal ◽  
Physical Theory ◽  
Theory Model ◽  
Solution Thermodynamics ◽  
Metal Solution ◽  
Liquid Metal Solution

scholarly journals GaPt Supported Catalytically Active Liquid Metal Solution Catalysis for Propane Dehydrogenation–Support Influence and Coking Studies

ACS Catalysis ◽  
2021 ◽  
pp. 13423-13433
Author(s):  
Narayanan Raman ◽  
Moritz Wolf ◽  
Martina Heller ◽  
Nina Heene-Würl ◽  
Nicola Taccardi ◽  
...  
Keyword(s):  
Liquid Metal ◽  
Propane Dehydrogenation ◽  
Metal Solution ◽  
Catalytically Active ◽  
Active Liquid ◽  
Liquid Metal Solution

Calorimetrie an Lanthantrihalogeniden und Ammoniumlanthanhalogeniden / Calorimetry of Lanthanum Trihalides and of Ammonium Lanthanum Halides

1997 ◽  
Vol 52 (9) ◽  
pp. 1062-1066 ◽  
Author(s):  
H. Oppermann ◽  
A. Morgenstern ◽  
S. Ehrlich
Keyword(s):  
Lanthanum Oxide ◽  
Enthalpies Of Formation ◽  
Enthalpies Of Solution ◽  
Tabulated Data

By determination of the enthalpies of solution of lanthanum oxide and of lanthanum trihalides in 4n HX we derived the enthalpies of formation of the trihalides at 298 K using tabulated data. On the basis of these data and measured enthalpies of solution in 4n HX of diammonium lanthanum pentahalides, the enthalpies of formation of (NH4)2LaX5 were obtained.ΔH°B(LaCl3,f,298) = -258,5 ± 0,8 kcal/mol; ΔH°B((NH4)2LaCl5,f,298) = -411,5 ± 1,4 kcal/mol;ΔH°B(LaBr3,f,298) = -218,7 ± 1,7 kcal/mol; ΔH°B((NH4)2LaBr5,f,298) = -352,8 ± 2,5 kcal/mol; ΔH°B(LaI3,f,298) = -166,9 ± 2,0 kcal/mol; ΔH°B((NH4)2LaI5,f,298) = -264,7 ± 3,0 kcal/mol.

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