Solvation of the Sodium Ion. Quadrupolar Broadening of the 23Na Nuclear Magnetic Resonance

1972 ◽  
Vol 50 (24) ◽  
pp. 3935-3937 ◽  
Author(s):  
R. D. Green ◽  
John S. Martin

Sodium ion preferentially forms long lived complexes with dimethylsulfoxide or N,N-dimethylformamide, in mixtures of either of these solvents with either ethanenitrile or propanone. No long lived complexes are observed in solvent mixtures of water or methanol with ethanenitrile or propanone.

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