Matrix Infrared and Raman Spectroscopic Evidence for Pd(N2)3 in Solid Nitrogen
Keyword(s):
Cocondensation of palladium atoms with 14N2 at 4.2–10 °K leads to the formation of a binary dinitrogen complex. The complex is detected by matrix isolation infrared and Raman spectroscopy. Isotope studies using equimolar 14N2/15N2 mixtures, together with isotope frequency and integrated absorption intensity calculations, suggest that the species is tris-dinitrogen palladium(0), Pd(N2)3.
Hidden Isomer of Trifluoroacetylacetone Revealed by Matrix Isolation Infrared and Raman Spectroscopy
2021 ◽
Vol 125
(11)
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pp. 2249-2266
1997 ◽
Vol 435
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pp. 219-228
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2000 ◽
Vol 26
(1)
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pp. 501-520
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2021 ◽
pp. 119900