Steroids and Steroidases. XIV. Studies on the Reactions of 2-Lithio-1,3-dithianes with Steroids Possessing Spiroepoxide Functions at C-32

1972 ◽  
Vol 50 (9) ◽  
pp. 1407-1413 ◽  
Author(s):  
J. Bryan Jones ◽  
Roger Grayshan
Keyword(s):  
Androstane Series ◽  
C 32

The scope of the reactions of lithio-dithianes with spiro-epoxides for various stereospecific functionalizations of alicyclic systems has been illustrated by their application to spiro-3α- and -3β-oxiranes of the 5α-cholestane and 5α-androstane series.

scholarly journals Effect of thermal stimulation on gonad maturation in sea cucumber Phyllophorus sp. (Grube, 1840)

2018 ◽  
Vol 23 ◽  
pp. 39-46
Author(s):  
S Andriyono ◽  
N Masruroh ◽  
ED Masithah ◽  
J Triastuti ◽  
D Winarni
Keyword(s):  
Sea Cucumber ◽  
Histological Analysis ◽  
Temperature Treatment ◽  
Thermal Stimulation ◽  
Gonad Maturation ◽  
Marine Animals ◽  
Sea Cucumbers ◽  
Fishery Products ◽  
C 32 ◽  
The Ideal

Sea cucumbers, marine animals from the class Holothuroidea, have been widely known as fishery products for consumption in Indonesia. The Madura Strait is productive waters for sea cucumbers in eastern Indonesia, including sea cucumber species Phyllophorus sp. The exploitation of it mainly for consumption even though there are pharmaceutical beneficial of sea cucumber already known. The study of temperature effect is ideal inducement method for sea cucumber, but less research about this stimulation for Phyllophorus sp. for domestication purposes. The research showed that thermal stimulation treatment at the temperature of 30°C, 32°C and 34°C were in contrast to the that of control histological analysis proof that some of Phyllophorus sp. showed altered levels of gonadal maturation toward growth and advanced growth phase after thermal stimulation, respectively. The ideal stimulation treatment for gonad maturation was shown with stimulated temperature treatment of 32°C.J. bio-sci. 23: 39-46, 2015

scholarly journals Development and health status of Centropomus undecimalisparasitized by Rhabdosynochus rhabdosynochus (Monogenea) under different salinity and temperature conditions

2015 ◽  
Vol 24 (3) ◽  
pp. 350-356 ◽  
Author(s):  
Giovanni Lemos de Mello ◽  
Gabriela Tomas Jerônimo ◽  
Karen Roberta Tancredo ◽  
Jéssica Brol ◽  
Evelyn Jacques de Almeida ◽  
...  
Keyword(s):  
Hematological Parameters ◽  
Hemoglobin Concentration ◽  
Economic Losses ◽  
Mean Corpuscular Hemoglobin ◽  
Experimental Conditions ◽  
Different Temperatures ◽  
The Mean ◽  
Positive Correlations ◽  
C 32 ◽  
Wbc Count

This study evaluated the correlation of hematological parameters with the mean abundance of the monogenean helminth Rhabdosynochus rhabdosynochus in Centropomus undecimalis reared at different temperatures and salinities. The experimental conditions were: 28 °C/0 ppt (parts per thousand); 28 °C/15 ppt; 28 °C/32 ppt; 25 °C/0 ppt; 25 °C/15 ppt; and 25 °C/32 ppt. The prevalence was 100.0% in fish at 28 °C/15 ppt, 28 °C/32 ppt and 25 °C/15 ppt, which was significantly different (p < 0.05) from those at 25 °C/32 ppt. The red blood cell (RBC) count, hematocrit and total leukocyte (WBC) count were significantly higher in fish at 28 °C/15 ppt and 28 °C/32 ppt. The mean abundance of R. rhabdosynochus, hematocrit and RBC showed positive correlations (P < 0.05) with temperature (ρ= 0.3908; ρ= 0.4771 and ρ = 0.2812). Mean abundance showed negative correlations with hemoglobin (ρ= -0.3567) and mean corpuscular hemoglobin concentration (MCHC) (ρ = -0.2684). No correlation between abundance and salinity was detected among the experimental conditions (ρ = -0.0204). The low numbers of monogeneans recorded (min -1 and max -33) explain the few changes to fish health. This suggests that these experimental conditions may be recommended for development of rearing of C. undecimalis in Brazil, without any influence or economic losses from R. rhabdosynochus.

TABLE 3 Major Commercial Fermentation Conditions for Cereal Foods Fermentation conditions Bread Beer Whiskey Soy sauce Miso Main starters Baker's yeast Brewer's yeast Distillery yeast Molds Molds (Saccharomyces (Saccharomyces (Saccharomyces (Aspergillus spp.) (Aspergillus spp.) cerevisiae) cerevisiae) cerevisiae) Saccharomyces rouxii Lactic acid bacteria Lactobacillus delbrueckii Cereals Milled wheat Barley (malted) Corn Soybeans (defatted) Rice Milled rye Sorghum Rye (malted or not) Wheat Barley Minor: Minor: Barley (malted) Minor: Soybeans Barley (malted) Corn Wheat Barley flour Wheat (malted) Rice Wheat Other ingredients Water Water Water Water Salt Salt Hops Salt Hot pepper Sugar Adjuncts Fat (corn syrup, sugar Emulsifiers or starch) Dough strengtheners Preservatives Enzymes Fermentation 1-6h2-10 days 2-3 days (Koji: 3 days at 30°C) (Koji: 2 days at 30°C) conditions 20-42°C 3-24°C 32-35°C 3-12 months 2 days to 1 year Aging: Aging: 15-30°C 30-50°C 3 days-1 month 2-3 years or more 0-13°C 21-30°C baker's yeast is probably the most common of these microorganisms that may be a problem are bacteria (usual-starters; it is commercially produced in liquid, paste (com-ly spore-forming or lactic acid bacteria, especially in some pressed), or dry form. Recently, commercial lactic acid yeast fermentations), wild yeasts, and molds. bacteria starters have been introduced for cereal fermenta-Several spore-forming bacteria (e.g., Bacillus spp.) may tions, but this application is less frequent than their regular produce amylases and degrade hydrated starchy materials. use in dairy or meat fermentations. A close control of the In bread, heat-tolerant spores of Bacillus subtilis (formerly performance of commercial starters is important, since it Bacillus mesentericus) survive the baking process; after a has a major effect on the final products. few days in bread, they produce a spoilage called ropiness, characterized by yellow spots on crumb, putrid pineapple aroma, and stringiness when breaking a piece of bread. The spores of these species, when contaminating flour, may Considering the diversity of the microbial flora that may cause a major problem in bakeries since they are highly re-be present in cereals to be fermented, undesirable microor-sistant in the environment and difficult to eliminate. How-ganisms are likely to be part of this flora and may produce ever, these bacterial infections have become rare in recent problems in the main fermentation process with subse-years, presumably due to improved sanitation. In beer, un-quent adverse effects on the final product. Nowadays these desirable microbial contamination is exhibited by viscosity, problems are lessened by good sanitary practices. Sources appearance, as well as aroma and flavor problems. of these organisms may be the cereals themselves, soil, as Microbial pathogens are usually not a problem for fer-well as any particular ingredient, surface contamination, mented cereals because of the inhibition brought about by and unsanitary handling. acids and ethanol generated by fermenting organisms. A Table 4 summarizes microbial problems likely to occur large proportion of fermented cereals are also eaten shortly during major cereal fermentations. In general, undesirable after complete cooking. However, the biggest problem

2000 ◽  
pp. 765-770
Keyword(s):  
Lactic Acid ◽  
Lactic Acid Bacteria ◽  
Baker’S Yeast ◽  
Lactobacillus Delbrueckii ◽  
Hot Pepper ◽  
Baker's Yeast ◽  
Fermentation Conditions ◽  
C 32 ◽  
C 30 ◽  
Water Water Water

scholarly journals The Application of Adiabatic Film Cooling Effectiveness to Non-Adiabatic Blade Cooling Design

1983 ◽  
Author(s):  
C. P. Lee ◽  
J. C. Han
Keyword(s):  
Heat Transfer ◽  
Film Cooling ◽  
Heat Transfer Analysis ◽  
Adiabatic Wall ◽  
Cooling Effectiveness ◽  
Film Cooling Effectiveness ◽  
Transfer Parameter ◽  
Adiabatic Effectiveness ◽  
C 32 ◽  
Heat Transfer Parameter

The effect of heat transfer on film cooling has been studied analytically. The proposed model shows that the non-adiabatic film cooling effectiveness will increase with increasing of the heat transfer parameter, Ū / (ρVCp)2, on the convex, the flat and the concave walls over the entire range of film cooling parameter, X/MS. On the convex wall with a blowing rate, M, of 0.51 and a heat transfer parameter of 10−3 at the typical engine conditions, the non-adiabatic effectiveness can be higher than the adiabatic effectiveness by 45% at a film cooling parameter of 103; while the film temperature can be lower than the adiabatic wall by 18°C (32°F) at a dimensionless distance of 500. The model can be extended and applied to the heat transfer analysis for any kind of turbine blade with film cooling.

scholarly journals Low-voltage-area ablation in paroxysmal atrial fibrillation: Extended follow-up results of the VOLCANO trial

2021 ◽  
Author(s):  
Masaharu Masuda ◽  
Mitsutoshi Asai ◽  
Osamu Iida ◽  
Shin Okamoto ◽  
Takayuki Ishihara ◽  
...  
Keyword(s):  
Atrial Fibrillation ◽  
Paroxysmal Atrial Fibrillation ◽  
Low Voltage ◽  
Recurrence Rates ◽  
Group A ◽  
C 32 ◽  
Group B ◽  
Group D

Introduction: The randomized controlled VOLCANO trial demonstrated comparable 1-year rhythm outcomes between patients with and without ablation targeting low-voltage areas (LVAs) in addition to pulmonary vein isolation among paroxysmal atrial fibrillation (AF) patients with LVAs. To compare long-term AF/atrial tachycardia (AT) recurrence rates and types of recurrent-atrial-tachyarrhythmia between treatment cohorts during a > 2-year follow-up period. Methods: An extended-follow-up study of 402 patients enrolled in the VOLCANO trial with paroxysmal AF, divided into 4 groups based on the results of voltage mapping: Group A, no LVA (n=336); group B, LVA ablation (n=30); group C, LVA presence without ablation (n=32); and group D, incomplete voltage map (n=4). Results: At 25 (23, 31) months after the initial ablation, AF/AT recurrence rates were 19% in group A, 57% in group B, 59% in group C, and 100% in group D. Recurrence rates were higher in patients with LVAs than those without (group A vs. B+C, p<0.0001), and were comparable between those with and without LVA ablation (group B vs. C, p=0.83). Among patients who underwent repeat ablation, ATs were more frequently observed in patients with LVAs (Group B+C, 50% vs. A, 14%, p<0.0001). In addition, LVA ablation increased the incidence of AT development (group B, 71% vs. C, 32%, p<0.0001), especially biatrial tachycardia (20% vs. 0%, p=0.01). Conclusion: Patients with LVAs demonstrated poor long-term rhythm outcomes irrespective of LVA ablation. ATs were frequently observed in patients with LVAs, and LVA ablation might exacerbate iatrogenic ATs.

scholarly journals PHYSICAL CHEMICAL STUDIES OF THE SURFACTANT DILAURYLDIMETHYLAMMONIUM BROMIDE (DLDMAB): AGGREGATION AND CATALYTIC PROPERTIES

2009 ◽  
Vol 17 (17) ◽  
pp. 21-32
Author(s):  
Elizabeth Fatima de Souza ◽  
Silvia Dani ◽  
Lavinel G. IONESCU
Keyword(s):  
Thermodynamic Parameters ◽  
Catalytic Properties ◽  
Activation Parameters ◽  
Critical Micellar Concentration ◽  
Physical Chemical ◽  
Chemical Studies ◽  
Diphenyl Phosphate ◽  
C 32 ◽  
Free Energy Of Micellization ◽  
Hydrolysis Of

The micellization of dilauryldimethylammonium bromide (DLDMAB) in water was studied by using surface tension measurements. The critical micellar concentration (CMC) was determined at 25°C, 32°C and 40°C and thermodynamic parameters such as the free energy of micellization (∆G°mic), enthalpy (∆H°mic), and entropy (∆S°mic) of micellization were measured. The CMC at 25°C was 4.93 x 10-5 M and the corresponding values of the thermodynamic parameters were: ∆G°mic = -5.87 kcal/mol; ∆H°mic = -1.12 kcal/mol and ∆S°mic = +16.00 e.u. Micelles of the surfactant DLDMAB act as catalysts for the alkaline hydrolysis of p-nitrophenyl diphenyl phosphate (NPDPP) with a maximum catalytic factor of approximately 120 compared to 80 for CTAB. Typical activation parameters measured for 1.00 x 10-3 M surfactant and 0.005 M NaOH were: Ea = 9.7 kcal/mo/; ∆H°≠ = 9.1 kcal/mol; ∆G°≠ = 19.6 kcal/mol and ∆S°≠ = -33.9 e.u. The kinetic results were also analyzed in terms of the pseudo-phase ion-exchange models (PPIE) and showed that the model is applicable to describe the experimental results.

scholarly journals EFEK PENINGKATAN SUHU AIR TERHADAP PERUBAHAN PERILAKU, PATOLOGI ANATOMI, DAN HISTOPATOLOGI INSANG IKAN NILA (OREOCHROMIS NILOTICUS)

2013 ◽  
Vol 7 (2) ◽  
Author(s):  
Dwinna Aliza ◽  
Winaruddin ◽  
Luky Wahyu Sipahutar
Keyword(s):  
Oreochromis Niloticus ◽  
C 32

Penelitian ini bertujuan mengetahui efek peningkatan suhu terhadap perubahan perilaku, patologi anatomi, dan histopatologi insang ikan  nila. Penelitian ini menggunakan 12 sampel ikan nila yang dibagi atas 4 kelompok. Kelompok I adalah perlakuan kontrol dengan suhu air 28°C, ikan pada kelompok II, III, IV dipelihara pada suhu 30° C, 32° C, dan 34° C selama 6 jam, mulai dari jam 09.00 sampai 15.00 Wib. Perubahan perilaku diamati setiap satu jam selama 6 jam perlakuan. Kemudian insang sampel diambil lalu difiksasi dalam larutan Davidson 10% dilanjutkan dengan pembuatan sediaan histopatologi menggunakan pewarnaan haematoksolin dan eosin (HE). Pengamatan histopatologi  dilakukan dengan mikroskop cahaya biokuler, kemudian dilakukan pemotretan dengan fotomikrograk. Data yang diperoleh dianalisis secara deskriptif. Beberapa perubahan perilaku berupa pergerakan pasif, menurunnya refleks, dan gerakan operculum terjadi lebih cepat pada ikan nila kelompok II, III, dan IV.  Pada pemeriksaan patologi anatomi insang ikan nila didapati perubahan berupa over mucus, perubahan struktur insang, dan perubahan warna. Sementara hasil pemeriksaan histopatologi terhadap insang ikan nila ditemukan adanya epitelium terlepas, hiperplasia lamella primer, hiperplasia lamella sekunder, nekrosa, dan fusi lamella.

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