Desorption of Hydrogen from Palladium and Palladium-Silver Alloys followed by Differential Scanning Calorimetry

1972 ◽  
Vol 50 (9) ◽  
pp. 1321-1324 ◽  
Author(s):  
D. Artman ◽  
Ted B. Flanagan
Keyword(s):  
Differential Scanning Calorimetry ◽  
Slow Step ◽  
Differential Scanning Calorimetric ◽  
Solid State Diffusion ◽  
Palladium Alloys ◽  
Scanning Calorimetry ◽  
Silver Alloys ◽  
State Diffusion ◽  
Silver Palladium ◽  
Palladium Silver

Differential scanning calorimetric curves have been obtained corresponding to the desorption of hydrogen from palladium and palladium–silver alloys. There was no evidence for the existence of an exotherm, following the endothermic desorption of hydrogen, which has been previously found and attributed to the relaxation of a metastable, expanded hydrogen-free palladium lattice. Heats of desorption have been evaluated from the areas of the endotherms and these are reasonable in the light of values obtained by other techniques. Comparisons of scanning curves for palladized and unpalladized hydrogen-containing silver–palladium alloys demonstrate that solid-state diffusion cannot be the slow step for the former but may be for the latter.

A Differential Scanning Calorimetric Study of the Mg-Cu-Y System

2012 ◽  
Vol 706-709 ◽  
pp. 1215-1220 ◽  
Author(s):  
Mohammad Mezbahul-Islam ◽  
Elhachmi Essadiqi ◽  
Mamoun Medraj
Keyword(s):  
Differential Scanning Calorimetry ◽  
Metallic Glass ◽  
Thermodynamic Modeling ◽  
Differential Scanning Calorimetric ◽  
Phase Assemblage ◽  
Calorimetric Study ◽  
Solidification Behavior ◽  
Scanning Calorimetry ◽  
Ternary Compounds ◽  
Melting Temperatures

The Mg-Cu-Y system has been experimentally investigated using differential scanning calorimetry (DSC). Vertical sections and phase assemblage diagrams are calculated using thermodynamic modeling. Solidification behavior of the key alloys was discussed in light of the thermodynamic calculation. Melting temperatures of two of the ternary compounds; Mg18CuY and Mg4CuY, are predicted using the modified thermodynamic database of this system. Key words: Mg alloys, Bulk metallic glass, Differential scanning calorimetry, Thermodynamic modeling.

Solid-state Reaction Study on Physically and Tribochemically Prepared BaC2O4-SnC2O4 Mixtures

2012 ◽  
Vol 67 (7) ◽  
pp. 667-672 ◽  
Author(s):  
Vittorio Berbenni ◽  
Chiara Milanese ◽  
Giovanna Bruni ◽  
Alessandro Girella ◽  
Amedeo Marini
Keyword(s):  
Differential Scanning Calorimetry ◽  
Solid State ◽  
Mechanical Activation ◽  
Solid State Reaction ◽  
Differential Scanning Calorimetric ◽  
Temperature Differential ◽  
Scanning Calorimetry ◽  
X Ray ◽  
Reaction Study ◽  
Modulated Temperature

The synthesis of barium metastannate, BaSnO3, by heating mixtures of metal oxalates, either physically mixed or subjected to a phase of mechanical activation, up to temperatures in the range 750- 1200 °C has been studied. Simultaneous thermogravimetric-differential scanning calorimetric (TGDSC) analyses and powder X-ray diffractometry have been applied to check the advancement of the reactions. BaSnO3, though slightly contaminated by BaCO3, can be obtained by heating the activated mixture up to T ≥ 1000 °C while heating a sample of a physical mixture at temperature as high as 1200 °C resulted in a mixture of BaSnO3, SnO2 and Ba2SnO4. The heat capacities of BaSnO3 samples prepared at temperatures between 1000 and 1200 °C have been measured by modulated temperature differential scanning calorimetry (MTDSC) in the temperature range 50-400 °C.

Thermal Stability of N-Heterocycle-Stabilized Iodanes – A Systematic Investigation

2019 ◽  
Author(s):  
Andreas Boelke ◽  
Yulia A. Vlasenko ◽  
Mekhman S. Yusubov ◽  
Boris Nachtsheim ◽  
Pavel Postnikov
Keyword(s):  
Thermal Stability ◽  
Differential Scanning Calorimetry ◽  
Thermogravimetric Analysis ◽  
Systematic Investigation ◽  
Scanning Calorimetry ◽  
Thermal Stability Of

<p>The thermal stability of pseudocyclic and cyclic <i>N</i>-heterocycle-stabilized (hydroxy)aryl- and mesityl(aryl)-l<sup>3</sup>-iodanes (NHIs) through thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) is investigated. NHIs bearing <i>N</i>-heterocycles with a high N/C-ratio such as triazoles show among the lowest descomposition temperatures and the highest decomposition energies. A comparison of NHIs with known (pseudo)cyclic benziodoxolones is made and we further correlated their thermal stability with reactivity in a model oxygenation. </p>

Optimasi Proses Pembuatan dan Karakterisasi Fisik Niosom Sinkonin

2019 ◽  
Vol 16 (2) ◽  
pp. 178
Author(s):  
Hariyanti Hariyanti ◽  
Sophi Damayanti ◽  
Sasanti Tarini
Keyword(s):  
Differential Scanning Calorimetry ◽  
Particle Size ◽  
Hair Follicle ◽  
Scanning Calorimetry ◽  
Span 60

Sinkonin praktis tidak larut dalam air, sedikit larut dalam kloroform dan alkohol. Hal ini berdampak pada rendahnya penetrasi transfollicular sinkonin, karena hanya bahan aktif hidrofilik yang mampu melewati hair follicle. Dengan demikian dibutuhkan satu sistem penghantaran yang mampu menurunkan hidrofobisitas sinkonin untuk meningkatkan penetrasi sinkonin ke follicle. Niosom merupakan vesikel ampifilik dengan struktur lapisan rangkap yang terbentuk dari hidrasi kombinasi surfaktan nonionik dan kolesterol yang mampu menurunkan hidrofobisitas sinkonin. Penelitian ini bertujuan untuk menentukan proses pembuatan niosom sinkonin yang optimum. Pembuatan niosom sinkonin diawali dengan menentukan temperatur gelasi (Tg) dari span 60 dengan Differential Scanning Calorimetry (DSC), kemudian dilanjutkan dengan optimasi proses meliputi: optimasi kecepatan rotavapor pembentukan film lapis tipis, temperatur hidrasi, kecepatan rotavapor hidrasi, waktu hidrasi, dan waktu sonikasi. Karakteristik vesikel niosom yang optimal meliputi: ukuran partikel dan indeks polidispersitas dengan menggunakan Particle Size Analized (PSA) serta efisiensi penjeratan sinkonin dengan menggunakan KCKT. Temperatur gelasi (Tg) span 60 45±2 oC, kecepatan rotavapor pembentukan film lapis tipis niosom 210 rpm, temperatur hidrasi 55±2 oC, kecepatan rotavapor hidrasi 210 rpm, waktu hidrasi 20 menit, waktu sonikasi suspensi niosom 1 menit. Ukuran vesikel yang diperoleh adalah 100–200 nm, indeks polidispersitas 0,2–0,4 dan efisiensi penjeratan niosom sinkonin 84,49±0,0025%. Proses pembuatan niosom sinkonin memiliki pengaruh besar terhadap hasil ukuran vesikel dan efisiensi penjeratan niosom sinkonin.

Improving Wire Sweep Performance by Measuring Degree of Cure of Epoxy Mold Compounds

2011 ◽  
Author(s):  
Sheila Liza B. Dal
Keyword(s):  
Differential Scanning Calorimetry ◽  
Shelf Life ◽  
Trial And Error ◽  
Active Components ◽  
Scanning Calorimetry ◽  
Degree Of Cure ◽  
Electronic Package ◽  
Viscosity Changes ◽  
Epoxy Mold Compounds

Abstract The choice of epoxy mold compound (EMC) for an electronic package is based mostly on how much protection it provides to the active components in the package. But the choice is not a straightforward process. Rather it is mostly trial and error using different assembly parameters to find the most robust material while assembly defects are monitored. One such defect associated to EMC processing is wire sweep, and many studies have shown that it is mainly caused by viscosity changes in the EMC. In this study, samples of EMC in various stages of shelf life and staging times were analyzed for degree of cure using a method called differential scanning calorimetry (DSC). Samples are then processed at assembly for wire sweep measurement. It was found out that degree of cure increases with staging time at different rates for each shelf life. It was also found out that wire sweep did not only increase with degree of cure but it was also found to be predictable with respect to the latter. Using this information, the age and staging limit for each material was identified that would not cause wire sweep issues.

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