Thermal Conductivity, Anomaly in Temperature-dependence for Liquids
Keyword(s):
Most empirical equations express the thermal conductivity of normal simple liquids as linear functions of temperature. The majority of measurements to date, except water, support such a description. Very precise new measurements on toluene over the complete liquid range at 1 atm (0.299 < Tr < 0.645) show a substantial pre-freezing anomaly. At the freezing point (tf) there is a depression of the expected conductivity of 7.9 × 10−3 W/m °K. This tf behavior is attributed to cluster formation.
2010 ◽
Vol 1
(2)
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pp. 167-173
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1998 ◽
Vol 21
(1)
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pp. 124-126
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1977 ◽
Vol 32
(5)
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pp. 530-532
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2021 ◽
1976 ◽
Vol 6
(4)
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pp. 559-565
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