The ternary system silver–indium–aluminum

1970 ◽  
Vol 48 (20) ◽  
pp. 3164-3172 ◽  
Author(s):  
A. N. Campbell ◽  
R. Wagemann

A number of alloys have been examined microscopically. From these observations, from the equilibrium diagrams of the component binary systems, and from the application of the phase rule, a room temperature isothermal section has been deduced. Three vertical sections through the ternary system have been partially constructed from differential thermal analysis. These data show that invariant planes occur at 143, 148, 241, and 506 °C. From the information obtained from the vertical sections and the room temperature isothermal section, isothermal sections have also been proposed at 143 and 148°. The transformation at the 143 °C invariant plane is a ternary eutectic, at 148° a ternary peritectic, and the other transformations at 241 and 506° are also ternary peritectics.Some evidence indicates that the ξ-phase of Ag–Al system and the γ-phase of Ag–In system link up through the ternary system forming a single phase region, and that such may also be the case with the phases µ and α′ of the systems Ag–Al and Ag–In, respectively. The phases ε and [Formula: see text] of the system Ag–In do not appear to be capable of dissolving aluminum appreciably.

1997 ◽  
Vol 481 ◽  
Author(s):  
J.-H. He ◽  
E. Ma

ABSTRACTA model analysis is presented which explains ball-milling induced alloying in positive-heatof- mixing systems in terms of a dynamic balance between externally forced mixing and thermal phase decomposition mediated by deformation-enhanced population of defects. The possibility of eliminating the thermal decomposition to force single phase formation is examined by milling Cu- Fe and Cu-Ta powder mixtures at the liquid nitrogen temperature (LN2T). Over a range of compositions for Cu-Fe and almost the entire composition range for Cu-Ta, the two-phase region observed for room-temperature (RT) milling persisted after cryomilling. The moderate temperature dependence of milling-induced alloying is interpreted by analyzing the dynamics of the generation and annihilation of the nonequilibrium vacancies during deformation and impacts in a SPEX mill.


2019 ◽  
Vol 55 (2) ◽  
pp. 147-156 ◽  
Author(s):  
W.-Q. Ao ◽  
H.-Z. Yu ◽  
F.-L. Liu ◽  
F.-S. Liu ◽  
J.-Q. Li ◽  
...  

The isothermal section of the Ni-Mn-Sb ternary system at 773 K was measured by means of 117 alloys which were analyzed by using X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersion spectroscopy (EDS), and electron probe microanalysis (EPMA) techniques. The existence of 7 binary compounds, namely NiMn, Mn2Sb, MnSb, NiSb2, NiSb, Ni5Sb2, Ni3Sb and 2 ternary compounds, namely Ni2MnSb and NiMnSb were confirmed for this isothermal section. The four binary compounds Ni3Sb (Cu3Ti structure, Pmmn space group), Ni5Sb2 (Ni5Sb2-type structure, C2 space group), NiSb2 (FeS2-type structure, Pnnm space group) and Mn2Sb (Cu2Sb-type structure, P4/nmm space group) in the binary systems Ni-Sb and Mn-Sb were stoichiometric compounds, the homogeneity ranges of which were negligible. However the five single phases in the Ni-Mn system and the two binary compounds MnSb and NiSb showed more or less homogeneity ranges formed by substitution of Mn and Sb for Ni atom. The Heusler compound ? (Ni2MnSb) has L21-type ordered structure with space group Fm-3m, a = 0.6017 nm. And the crystal structure for the Half-Heusler compound ? (NiMnSb) is C1b-type (F-43m) with a = 0.5961 nm. The approximate homogeneity ranges of the two ternary compounds ? and ? at 773 K were investigated.


2011 ◽  
Vol 689 ◽  
pp. 355-360
Author(s):  
Qiu Guo Xiao ◽  
Gang Cheng Ding ◽  
Tang Zhong Long ◽  
Shao Hua Shen

This paper has put forward a high-temperature quantitative X-ray powder diffraction analysis method for the determination of an isothermal section of a ternary system in comparison with a conventional method. In a three-phase region of the isothermal section at 1150 °C of Cu2O(CuO)-Al2O3-SiO2 pseudo-ternary system, the compositions of the solid phase points of three system points are determined according to the quantitative analysis of the crystalline phases in the samples carried out by Rietveld method. Then the liquid phase point of the three-phase region is determined according to the crosspoints of the tie lines of every pair of system point and solid phase point. The precisions of the analytical results have reached to be 0.1 ~ 5.0 %. By comparison, a good result is obtained for the determination of the liquid phase point of the three-phase region in the isothermal section at 1150 °C when the analytical results of high-temperature RQA analysis are used in determination of the isothermal section of the pseudo-ternary system.


2013 ◽  
Vol 284-287 ◽  
pp. 152-157
Author(s):  
Yee Wen Yen ◽  
Yu Pin Hsieh ◽  
Wan Ching Chen ◽  
Chien Chung Jao

With a relatively low liquidus temperature, the eutectic Sn-Zn alloy is suitable replacement for conventional eutectic Sn-Pb solder in the electronic industry. One of the most important materials as a lead-frame is Fe-42Ni alloy (Alloy 42) in the microelectronic packaging. The Sn-Fe-Zn ternary phase diagram is a powerful and useful tool to understand the interfacial reactions between Sn-Zn alloy and Alloy 42 substrate (Fe-rich alloy). The isothermal section of the Sn-Fe-Zn ternary system was experimentally investigated at 270oC in this study. Ternary Sn-Fe-Zn alloys were prepared and annealed at 270 oC to determine the isothermal section of the Sn-Fe-Zn ternary system. The experimental results revealed that no ternary intermetallic compound was formed, and noticeable Zn solubility was observed in the FeSn2 phase. The isothermal section of the Sn-Fe-Zn ternary system consists of nine single-phase areas, thirteen two-phase areas, and seven tie-triangles at 270 oC


2007 ◽  
Vol 61 (3) ◽  
pp. 152-156 ◽  
Author(s):  
Ivana Borisov ◽  
Dragan Manasijevic ◽  
Dragana Zivkovic

The ternary Ag-In-Sb system is a promising candidate for use as a Pb-free solder. The results of phase equilibria calculation by the CALPHAD method are presented in this study. The isothermal section at 400?C was calculated using optimized thermodynamic parameters of the constitutive binary systems. Calculated vertical sections from the indium and antimony corners were compared with the DTA results from this study and from the literature.


2007 ◽  
Vol 561-565 ◽  
pp. 435-438 ◽  
Author(s):  
Tomoaki Sugiura ◽  
Shigehiro Ishikawa ◽  
Takashi Matsuo ◽  
Masao Takeyama

The phase equilibria among α-Fe, γ-Fe and Fe2Ti phases in Fe-Ti-Ni ternary system at 1473 K and 1373 K with Ni (γ former element) addition were examined, by paying attention to the γ+Fe2Ti two-phase region. The Fe2Ti single-phase region extends toward the equal-titanium concentration direction up to about 30 at% Ni, and the Laves phase becomes in equilibrium with γ-Fe by 12 at% Ni addition, but the γ+Fe2Ti two-phase region is limited because of the formation of liquid phase by further Ni addition at 1473 K. With decreasing temperature, a ternary eutectic reaction (L→γ-Fe+Fe2Ti+Ni3Ti) occurs, making the two-phase region wider just below the invariant reaction at 1373 K, and the region becomes narrower again by the enlargement of the three-phases region toward Fe-rich side.


2013 ◽  
Vol 815 ◽  
pp. 3-7
Author(s):  
Shi Ping Guo ◽  
Wei He ◽  
Yun Hong Zhao ◽  
Ling Min Zeng

The isothermal sections of the Er-Cu-V and Dy-Cu-V ternary systems at 773K were investigated by experiments. The isothermal section of Er-Cu-V consists of 8 single-phase regions, 13 two-phase regions and 6 three-phase regions. The binary compounds ErCu5, ErCu2, ErCu, Er2Cu9and Er2Cu7were observed at 773K. The isothermal section of Dy-Cu-V consists of 7 single-phase regions, 11 two-phase regions and 5 three-phase regions. The binary compounds DyCu5, DyCu2, DyCu and Dy2Cu9were confirmed at 773K. No ternary compound was found in the two sections. There is no solubility of V in the Er-Cu and Dy-Cu binary compounds observed.


1992 ◽  
Vol 97 (2) ◽  
pp. 249-256 ◽  
Author(s):  
Manfred Womes ◽  
Josette Olivier-Fourcade ◽  
Jean-Claude Jumas ◽  
Frank Aubertin ◽  
Ulrich Gonser

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