Acid dependence and ion pairing in the anation reactions yielding iron(III) monosulfate

1970 ◽  
Vol 48 (19) ◽  
pp. 3100-3103 ◽  
Author(s):  
F. L. Baker ◽  
W. MacF. Smith

Stopped-flow studies of the kinetics of the a nation reaction yielding iron(III) monosulfate indicate a significant dependence of rate constant on acidity and also a dependence on iron concentrations. This is consistent with association constants for outer ion pair formation between the reactants which have about three times the Fuoss values.

2018 ◽  
Vol 47 (16) ◽  
pp. 5850-5859 ◽  
Author(s):  
Sandra Pérez ◽  
Pablo J. Sanz Miguel ◽  
Ramón Macías

A proton tautomerism is revealed to control ion-pair formation and proton transfer between a Proton-Sponge cation, [HPS]+, and a 10-vertex decaborane anion, [nido-B10H13]−.


2019 ◽  
Vol 21 (35) ◽  
pp. 19172-19180
Author(s):  
Stephen M. Baumler ◽  
William H. Hartt V. ◽  
Heather C. Allen

Ferric ion hydration differences are governed by ion pair formation uniquely affected by anion identity.


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