The single crystal Raman spectrum of orthorhombic PbCl2

1970 ◽  
Vol 48 (18) ◽  
pp. 2931-2933 ◽  
Author(s):  
G. A. Ozin

The frequencies and symmetries of the even parity lattice vibrations of orthorhombic lead dichloride are determined by means of polarized Raman scattering from an oriented single crystal. The frequencies of the vibrations are interpreted in terms of symmetry co-ordinates and by comparison with the modes of the isomorphous lead dibromide.

1971 ◽  
Vol 49 (7) ◽  
pp. 885-896 ◽  
Author(s):  
N. Krishnamurthy ◽  
V. Soots

The Raman spectrum of an oriented single crystal of CaSO4∙2H2O has been recorded from 20 to 3600 cm−1 at 300 °K and 77 °K using polarized laser excitation. The symmetries of the observed Raman lines have been determined and the spectrum has been analyzed in terms of external lattice vibrations, internal vibrations of the SO4 and H2O groups, hydrogen bond vibrations, and combinations of these vibrations. The translatory and rotatory lattice modes of the H2O molecules have been identified and the latter have been correlated with the principal moments of inertia of the water molecule. The hydrogen bond vibration was observed at 210 cm−1 at 300 °K and 217 cm−1 at 77 °K. The assignments of the internal modes were found to be consistent with the results of previous workers. Several overtone and combination frequencies were observed, especially in the region of the ν1 and ν3 vibrations of H2O.


1996 ◽  
Vol 2 (4) ◽  
pp. 233-242 ◽  
Author(s):  
Akiko Kumakura ◽  
Masamichi Tsuboi ◽  
Koichi Ushizawa ◽  
Toyotoshi Ueda

2015 ◽  
Vol 51 (11) ◽  
pp. 1-4 ◽  
Author(s):  
Guotai Zhou ◽  
Xiaomin Gu ◽  
Weimei Xie ◽  
Tengfei Gao ◽  
J. Peng ◽  
...  

1988 ◽  
Vol 152 (5) ◽  
pp. 491-494 ◽  
Author(s):  
R. Feile ◽  
J. Kowalewski ◽  
W. Assmus

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