Magnetic resonance studies of metal–olefin complexes. I. Electron spin resonance spectra of γ-irradiated silver perchlorate cycloalkene complexes
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Paramagnetic species have been detected in γ-irradiated polycrystalline silver perchlorate – cycloalkene complexes at room temperature and identified as Ag+ cycloalkenyl radicals, with spin density on Ag decreasing from 4.6 to 1.5% with increasing size of the cycloalkenyl ring. The extent of the spin density on Ag increases with the stability of the parent complexes.
1990 ◽
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