Synthesis and characterization of cyclam complexes of rhodium(III)

1970 ◽  
Vol 48 (10) ◽  
pp. 1481-1491 ◽  
Author(s):  
E. J. Bounsall ◽  
S. R. Koprich
Keyword(s):  
Electronic Spectra ◽  
Single Case ◽  
Synthesis And Characterization ◽  
Trans Isomers ◽  
Trans Effect ◽  
Linkage Isomers ◽  
Cis And Trans Isomers ◽  
Cyclam Complexes ◽  
Cis And Trans

A series of complexes of the type Rh(cyclam)X2+ and Rh(cyclam)XYn+ have been prepared and characterized, where cyclam represents 1,4,8,11-tetraazacyclotetradecane and X and Y represent OH−, H2O, Cl−, Br−, I−, N3−, NCS−, and NO2−. The infrared and electronic spectra are discussed with respect to assignment of the cis and trans isomers, the linkage isomers, and the Rh–ligand stretching frequencies above 250 cm−1. The thermodynamic trans effect is related to shifts in the Rh–ligand stretching frequencies. The intensities of the d–d transitions are related to distortion of the octahedral field to support the cis and trans assignments, and compared to show the decrease in bond constraint for propylene linkages in place of ethylene. Steric constraint accounts for the single case of stereoisomerization by cis-Rh(cyclam)I2+.

Synthesis and characterization of cis and trans isomers of [NiL2(NCS)2] [L=1-(2-aminoethyl)pyrrolidine]: X-ray single-crystal structures

Polyhedron ◽  
2000 ◽  
Vol 19 (15) ◽  
pp. 1803-1807 ◽  
Author(s):  
Inamur Rahaman Laskar ◽  
Tapas Kumar Maji ◽  
Siddhartha Chaudhuri ◽  
Ashutosh Ghosh ◽  
Nirmalendu Ray Chaudhuri
Keyword(s):  
Single Crystal ◽  
Crystal Structures ◽  
Synthesis And Characterization ◽  
Trans Isomers ◽  
X Ray ◽  
Single Crystal Structures ◽  
Cis And Trans Isomers ◽  
Cis And Trans

Syntheses, electrochemistry and photophysical properties of a series ofmeso-pyridylpentafluorophenylporphyrins

2010 ◽  
Vol 14 (11) ◽  
pp. 975-984 ◽  
Author(s):  
Emmanuel Z. Moreira ◽  
Alba D.Q. Ferreira ◽  
Cláudio Roberto Neri ◽  
Sumitra Mukhopadhyay ◽  
Sérgio Dovidauskas ◽  
...  
Keyword(s):  
Electrochemical Properties ◽  
Photophysical Properties ◽  
Synthesis And Characterization ◽  
Redox Potentials ◽  
Trans Isomers ◽  
X Ray ◽  
X Ray Crystallography ◽  
Cis And Trans Isomers ◽  
Cis And Trans

This work presents the synthesis and characterization of a series of substituted pyridylpentafluroporphyrins, including the separation of the cis- and trans-isomers, the latter being characterized by X-ray crystallography. The spectroscopic and electrochemical properties of the series are dependent on the number of electron withdrawing pentafluorophenyl substituent, but they do not depend on the symmetry of the molecule. Ongoing from the monosubstituted to the more substituted pentafluorophenyl porphyrin H2(MPyTFPP) derivative, the Soret bands are slightly red-shifted and their quantum fluorescence yields range from 0.035 to 0.046, consistent with the value of 0.045 for the fully substituted 5,10,15,20-tetrapentafluorophenylporphyrin (dichloromethane solutions). The redox potentials of the reductive processes of monoanion and dianion formation are also sensitive to the number of pentafluoro substituents, shifting 180 mV to more positive values for the P0/P-1process ongoing from the monopentafluoro to the tris-pentafluorophenyl substituted derivative.

Synthesis, isolation, and characterization of the cis and trans isomers of steroidal 20-hydroxy-17(20)-en-21-aldehydes

1989 ◽  
Vol 54 (6) ◽  
pp. 1332-1338 ◽  
Author(s):  
Marvin L. Lewbart ◽  
Carl Monder ◽  
Walter J. Boyko ◽  
Carol J. Singer ◽  
F. Iohan
Keyword(s):  
Trans Isomers ◽  
Isolation And Characterization ◽  
Cis And Trans Isomers ◽  
Cis And Trans

Synthesis and NMR characterization of the cis and trans isomers of [Ptii(N9-adeH)2(pz)2] and X-ray crystallography of the trans isomer

2007 ◽  
pp. 3966 ◽  
Author(s):  
Karel D. Klika ◽  
Henri Kivelä ◽  
Vladimir V. Ovcharenko ◽  
Ville Nieminen ◽  
Reijo Sillanpää ◽  
...  
Keyword(s):  
Trans Isomer ◽  
Trans Isomers ◽  
X Ray ◽  
X Ray Crystallography ◽  
Cis And Trans Isomers ◽  
Nmr Characterization ◽  
Cis And Trans
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