Ion neutralization reactions in irradiated hydrogen chloride, hydrogen bromide, and nitrous oxide

1970 ◽  
Vol 48 (4) ◽  
pp. 598-602 ◽  
Author(s):  
D. E. Wilson ◽  
D. A. Armstrong
Keyword(s):  
Nitrous Oxide ◽  
Hydrogen Chloride ◽  
Hydrogen Bromide ◽  
Recombination Coefficient ◽  
X Rays ◽  
Ion Density ◽  
Ion Recombination ◽  
Three Body

Rates of ion neutralization have been measured in hydrogen chloride, hydrogen bromide, and nitrous oxide by collecting the ions remaining in a defined volume at various times after ionization by a pulse of 120 k.v.p. X-rays. Values of the total homogeneous ion-ion recombination coefficient, a, have been obtained for each gas over a range of pressures in the region 50 to 650 Torr. From a study of the effects of pressure and ion density, the relative rates of wall diffusion, mutual neutralization, and three-body neutralization have been deduced.

Gas phase radiolysis of hydrogen chloride, hydrogen bromide, and nitrous oxide with intense electron pulses

1969 ◽  
Vol 47 (20) ◽  
pp. 3783-3791 ◽  
Author(s):  
C. Willis ◽  
A. W. Boyd ◽  
D. A. Armstrong
Keyword(s):  
Nitrous Oxide ◽  
Dose Rate ◽  
Hydrogen Chloride ◽  
Low Dose ◽  
Hydrogen Bromide ◽  
Negative Ion ◽  
Dose Rates ◽  
Electron Pulses ◽  
Intense Electron ◽  
Very High

Hydrogen chloride and hydrogen bromide have been irradiated with single electron pulses at a very high intensity (1027 eV g−1 s−1) with a Febetron 705. At room temperature the yields of hydrogen from hydrogen chloride and hydrogen bromide, for pressures between 700 and 1200 Torr, are G(H2) = 8.1 ± 0.2 and G(H2) = 9.9 ± 0.3, respectively. These are the same as the yields observed at low dose rates. Detailed lifetime calculations, however, show that the mechanism is significantly different at the higher dose rate. Scavenger experiments with chlorine in hydrogen chloride show that the negative ion intermediates form thermal hydrogen atoms.The value of G(N2) = 12.4 ± 0.2 from nitrous oxide at a dose rate of 1027 eV g−1 s−1 is confirmed and the use of nitrous oxide as a dosimeter for pulsed electron beams is discussed. The higher nitrogen yield at Febetron dose rates appears to be due to changes in the reactions of electrons.

scholarly journals A Spectroscopic Study of a Decaying Hydrogen Plasma

1965 ◽  
Vol 18 (1) ◽  
pp. 23 ◽  
Author(s):  
FE Irons ◽  
DD Millar
Keyword(s):  
Spectroscopic Study ◽  
Hydrogen Plasma ◽  
Experimental Methods ◽  
Recombination Coefficient ◽  
Ion Density ◽  
Temperature Distributions ◽  
Experimental Values ◽  
Three Body ◽  
Body Recombination

A study has been made of the decay of a hydrogen plasma of ion density ~3���1015 cm?3 and temperature ~104�K. Details are presented of the experimental methods used to determine density and temperature distributions in the decaying plasma. The plasma decays by three-body recombination mainly and the experimental values of the recombination coefficient agree with those expected for a plasma opaque to Lyman radiation.

ION–ION RECOMBINATION COEFFICIENT: I. CORRECTION FOR ION DISTRIBUTION AND DIFFUSION LOSSES IN PLANE PARALLEL ION CHAMBERS

1967 ◽  
Vol 45 (2) ◽  
pp. 429-437 ◽  
Author(s):  
S. McGowan
Keyword(s):  
Electrode Spacing ◽  
Recombination Coefficient ◽  
Correction Factors ◽  
Ion Distribution ◽  
Ion Density ◽  
Plane Parallel ◽  
Ion Recombination ◽  
Ion Chambers ◽  
Considerable Range ◽  
And Diffusion

Correction factors to measured values of the ion–ion recombination coefficient, which are required because of nonuniform ion density and diffusion losses, are calculated from computer solutions to the differential equation for simultaneous recombination and diffusion. Results for plane-parallel ion chambers are given as a function of ion age for an initially uniform ion distribution over a considerable range of ion density and electrode spacing, and for a collimated distribution for two particular combinations of ion density and electrode spacing. Corrections to be applied to some reported experimental ion–ion recombination coefficients are estimated.

scholarly journals Fast-Hardening Foam: Fire and Explosion Prevention at Facilities with Hazardous Chemicals

2017 ◽  
Vol 6 (4) ◽  
pp. 56
Author(s):  
Gennady N. Kuprin ◽  
Denis S. Kuprin
Keyword(s):  
Acetic Acid ◽  
Hydrogen Chloride ◽  
Hydrogen Fluoride ◽  
Diesel Fuel ◽  
High Probability ◽  
Hydrogen Bromide ◽  
Screening Method ◽  
Hazardous Chemicals ◽  
Experimental Apparatus ◽  
Fire And Explosion

Analysis of the terroristic attacks in Siria, Afghanistan and other countries has shown high probability of the hazardous chemicals application by the terroristic groups. In the article the most catastrophic accidents which were connected with hazardous chemicals are described.That is why research and developments in the sphere of protection from hazardous chemicals are still actual.This article is dedicated to the new screening method of the spilled hazardous chemicals surface on the example of protection of the factories with these substances. Methodology, experimental apparatus, protective fast-hardening foam features, names of hazardous chemicals are shown.Test were made for such chemicals as: acetic acid, acetone, ammonia, bromine, chlorbenzene, chloroform, hydrogen bromide, hydrogen chloride, hexane, hydrazine, diesel fuel, dichlorethane, kerosene, toluene, phenol, hydrogen fluoride. Fantastic results were achieved in terms of isolating capability of the fast-hardening foam against evaporations of the pointed substances.

scholarly journals The Reaction of Derivatives of D-Xylal and D-Arabinal with Hydrogen Chloride and Hydrogen Bromide.

1969 ◽  
Vol 23 ◽  
pp. 2083-2094 ◽  
Author(s):  
Klaus Bock ◽  
Inge Lundt ◽  
Christian Pedersen ◽  
Tord Holme ◽  
Alf A. Lindberg ◽  
...  
Keyword(s):  
Hydrogen Chloride ◽  
Hydrogen Bromide ◽  
Derivatives Of
Sign in / Sign up

Export Citation Format

Share Document