Preparation and characterization of some methyl cyanide complexes of Cu(I), Cu(II), and Zn(II) fluorosulfates

1970 ◽  
Vol 48 (1) ◽  
pp. 75-79 ◽  
Author(s):  
J. B. Milne
Keyword(s):  
Infrared Spectrum ◽  
Infrared Spectra ◽  
Strong Interaction ◽  
Strong Association ◽  
Conductivity Measurements ◽  
Methyl Cyanide ◽  
Cyanide Complexes

Tetrakis(methyl cyanide) complexes of Cu(I), Cu(II), and Zn(II) fluorosulfates have been prepared by reactions of anhydrous Cu(II) and Zn(II) fluorosulfates in methyl cyanide. The infrared spectra indicate a strong interaction between the fluorosulfate anion and the complex Cu(II) and Zn(II) cations. Conductivity measurements in methyl cyanide show strong association between the fluorosulfate anion and the dipositive cations. The Cu(I) compound is completely dissociated in methyl cyanide and, according to the infrared spectrum, shows no strong interaction with fluorosulfate anion.

Dimethylgermanium Dinitrate

1971 ◽  
Vol 49 (2) ◽  
pp. 202-206 ◽  
Author(s):  
D. Potts ◽  
A. Walker
Keyword(s):  
Carbon Tetrachloride ◽  
Ethyl Acetate ◽  
Dimethyl Sulfoxide ◽  
Infrared Spectra ◽  
Vibrational Spectra ◽  
Conductivity Measurements ◽  
Alkyl Nitrates ◽  
Methyl Cyanide ◽  
Nitrogen Pentoxide ◽  
Group Iva

Dimethylgermanium dinitrate has been prepared by the reaction of dimethylgermanium dichloride and nitrogen pentoxide in carbon tetrachloride. The properties of this compound have been investigated and compared with those of other known Group IVA alkyl nitrates. The vibrational spectra show that the nitrato groups are covalently bound to the germanium in a unidentate manner. Ultraviolet spectra and conductivity measurements indicate that the compound behaves as a 1:2 electrolyte in water and dimethyl sulfoxide but is a non-electrolyte in methyl cyanide, nitromethane, and ethyl acetate. The complexes Me2Ge(NO3)2•py and Me2Ge(NO3)2•2,2′dipy have been prepared and the infrared spectra of these compounds indicate considerable weakening of the germanium-nitrato bonds.

Characterization of New Ionically Conducting Peo-Based Networks by Diffusion, Elasticity Modulus and Ionic Conductivity Measurements

1992 ◽  
Vol 293 ◽  
Author(s):  
Herve Cheradame ◽  
F. Desbat ◽  
P. Mercier-Niddam ◽  
S. Boileau
Keyword(s):  
Diffusion Coefficient ◽  
Ionic Conductivity ◽  
Elasticity Modulus ◽  
Sol Gel ◽  
Cation Transport ◽  
Lithium Cation ◽  
Conductivity Measurements ◽  
Conducting Materials ◽  
Diffusion Studies

AbstractIonically conducting materials containing PEO were prepared from telechelic di(methyl-diethoxy-silane) PEO, synthesized by the hydrosilylation of telechelic diallyl-PEO with methyldiethoxysilane. The network is obtained by the usual sol-gel chemistry. Then, it is filled with LiClO4 by diffusion of the salt and further drying. A comparison is made with the same kind of materials crosslinked using urethane chemistry. Diffusion studies show that the diffusion coefficient of solvent is similar for both types of materials, whilst the ionic conductivity is higher for the networks crosslinked with siloxane bonds. An experiment of diffusion of LiClO4 without solvent showed that this salt has a diffusion coefficient of the order of 2.10-8 cm2.sec-1 at 34°C. The conductivity calculated from this determination is compatible with the mechanism of lithium cation transport by the diffusion of salt molecules. Elasticity modulus measurements show that the salt aggregates are essentially located within the crosslinks at low concentration, but also in the PEO chains for salt concentrations higher than 1 mol/l.

scholarly journals Exploration of Free Energy Surface and Thermal Effects on Relative Population and Infrared Spectrum of the Be6B11− Fluxional Cluster

Materials ◽  
2020 ◽  
Vol 14 (1) ◽  
pp. 112
Author(s):  
Carlos Emiliano Buelna-Garcia ◽  
José Luis Cabellos ◽  
Jesus Manuel Quiroz-Castillo ◽  
Gerardo Martinez-Guajardo ◽  
Cesar Castillo-Quevedo ◽  
...  
Keyword(s):  
Free Energy ◽  
Infrared Spectrum ◽  
Infrared Spectra ◽  
Thermal Effects ◽  
Global Minimum ◽  
Energy Surface ◽  
Weighted Sums ◽  
Free Energy Surface ◽  
Temperature Dependent ◽  
Relative Population

The starting point to understanding cluster properties is the putative global minimum and all the nearby local energy minima; however, locating them is computationally expensive and difficult. The relative populations and spectroscopic properties that are a function of temperature can be approximately computed by employing statistical thermodynamics. Here, we investigate entropy-driven isomers distribution on Be6B11− clusters and the effect of temperature on their infrared spectroscopy and relative populations. We identify the vibration modes possessed by the cluster that significantly contribute to the zero-point energy. A couple of steps are considered for computing the temperature-dependent relative population: First, using a genetic algorithm coupled to density functional theory, we performed an extensive and systematic exploration of the potential/free energy surface of Be6B11− clusters to locate the putative global minimum and elucidate the low-energy structures. Second, the relative populations’ temperature effects are determined by considering the thermodynamic properties and Boltzmann factors. The temperature-dependent relative populations show that the entropies and temperature are essential for determining the global minimum. We compute the temperature-dependent total infrared spectra employing the Boltzmann factor weighted sums of each isomer’s infrared spectrum and find that at finite temperature, the total infrared spectrum is composed of an admixture of infrared spectra that corresponds to the spectra of the lowest-energy structure and its isomers located at higher energies. The methodology and results describe the thermal effects in the relative population and the infrared spectra.

Diffuse Reflectance FT-IR Characterization of Active Sites under Reaction Conditions: The Production of Oxygenates in the CO/H2 Reaction

1994 ◽  
Vol 48 (10) ◽  
pp. 1208-1212 ◽  
Author(s):  
J. J. Benítez ◽  
I. Carrizosa ◽  
J. A. Odriozola
Keyword(s):  
Infrared Spectra ◽  
Active Sites ◽  
Diffuse Reflectance ◽  
Reaction Conditions ◽  
In Situ Drifts ◽  
Ft Ir

The reactivity of a Lu2O3-promoted Rh/Al2O3 catalyst in the CO/H2 reaction is reported. Methane, heavier hydrocarbons, methanol, and ethanol are obtained. In situ DRIFTS has been employed to record the infrared spectra under the actual reaction conditions. The structure of the observed COads DRIFTS bands has been resolved into its components. The production of oxygenates (methanol and ethanol) has been correlated with the results of the deconvolution calculation. Specific sites for the production of methanol and ethanol in the CO/H2 reaction over a Rh,Lu2O3/Al2O3 catalyst are proposed.

scholarly journals Preparation and Characterization of Magnetic Chitosan Microcapsules

2013 ◽  
Vol 2013 ◽  
pp. 1-8 ◽  
Author(s):  
Xiaopeng Xiong ◽  
Yong Wang ◽  
Weiwei Zou ◽  
Jiangjiang Duan ◽  
Yun Chen
Keyword(s):  
Magnetic Properties ◽  
Strong Interaction ◽  
Liquid Paraffin ◽  
Hollow Microspheres ◽  
Composite Particles ◽  
Cross Link ◽  
Magnetic Chitosan ◽  
Starting Solution ◽  
Dense Shell

By dispersing aqueous precipitant in liquid paraffin to prepare a W/O emulsion then adding chitosan (CS) solution, CS microcapsules have been successfully prepared. It is a facile way to prepare polymer microcapsules by using aqueous precipitant or nonsolvent as template, which avoids the removal of template and would free from the necessity to cross-link the microcapsule as usual methods to directly form dense shell. The hollow feature of the obtained materials is revealed. The diameter of the microcapsules ranges from severalμm to over 100 μm. Magnetic CS microcapsules have been prepared in this way when Fe3+and Fe2+were mixed with CS to prepare a mixture starting solution. The appearance and microstructure of the composite microcapsules were studied. The results indicate that the formed Fe3O4nanoparticles are embedded in the CS matrix evenly due to strong interaction between the Fe3O4nanoparticles and the CS molecules. The Fe3O4content and the magnetic properties of the composite microcapsule were measured. The composite microcapsules were calcined in air at 700°C to prepare pure inorganic hollow microspheres. It is general to prepare hollow polymeric or composite particles by using this method.

Synthesis and Infrared Spectrum Characterization of Phenylalanine Chelated Calcium Complex

2011 ◽  
Vol 396-398 ◽  
pp. 1549-1553
Author(s):  
Yu Qi Wu ◽  
Lian Jin Weng ◽  
Yuan Yuan Han ◽  
Xin Yang ◽  
Di Geng
Keyword(s):  
Infrared Spectrum ◽  
Chelate Ring ◽  
Uniform Design ◽  
Water System ◽  
Experimental Result ◽  
Molar Ratio ◽  
Optimal Parameters ◽  
Single Factor ◽  
Preparation Conditions

The preparation conditions in the water system of phenylalanine chelated calcium complex have been evaluated though single-factor tests and optimized by uniform design. Then the optimal parameters were obtained as follows: reaction temperature is 40 °C, reaction time is 182 min, the molar ratio of phenylalanine to calcium is 4.3 and pH = 9.0. Under the best conditions, the experimental result gives chelating rate = 87.40% that is 17.12% lower than the prediction = 104.52%.The infrared spectrum characterization has confirmed the formation of phenylalanine-Ca2+ chelates and the existence of chelate ring.

Infrared spectra of hexacoordinated cyanide complexes

1958 ◽  
Vol 8 ◽  
pp. 87-92 ◽  
Author(s):  
Vincenzo Caglioti ◽  
Guido Sartori ◽  
Marisa Scrocco
Keyword(s):  
Infrared Spectra ◽  
Cyanide Complexes
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