Liquid-phase oxidation of 2-butene in the presence of benzaldehyde

1969 ◽  
Vol 47 (17) ◽  
pp. 3191-3197 ◽  
Author(s):  
Fujio Tsuchiya ◽  
Tsuneo Ikawa
Keyword(s):  
Reaction Time ◽  
Liquid Phase ◽  
Co Oxidation ◽  
Experimental Results ◽  
The Other ◽  
Liquid Phase Oxidation ◽  
Perbenzoic Acid ◽  
Phase Oxidation ◽  
Cis And Trans ◽  
Epoxide Formation

The co-oxidation of cis- and trans-2-butene and benzaldehyde at 110 °C has been carried out in benzene and the mechanism of epoxide formation has been investigated by examining the ratio of cis- to trans-epoxides. The results indicate that epoxides were formed by two mechanisms, one involving the benzoylperoxy radical to give about half cis and half trans epoxides and the other by stereospecific epoxidation with perbenzoic acid. Experimental results show that the stereospecific character of epoxidation increases with the reaction time and the concentration of benzaldehyde, but does not depend on the concentration of 2-butene.

Products and reaction paths in the liquid phase oxidation of trans-1,2-dichloroethene with oxygen

1988 ◽  
Vol 66 (6) ◽  
pp. 1366-1370 ◽  
Author(s):  
Karl Griesbaum ◽  
Michael P. Hayes ◽  
Vera Werli
Keyword(s):  
Liquid Phase ◽  
Reaction Scheme ◽  
Liquid Phase Oxidation ◽  
Reaction Paths ◽  
Organic Products ◽  
Phase Oxidation ◽  
Chlorinated Organic ◽  
Cis And Trans ◽  
Oxygenated Products

Ultraviolet initiated liquid phase oxidation of neat trans-1,2-dichloroethene (1a) with oxygen at 30 °C afforded ca. 45% of the combined Cl-products CO, CO2, and phosgene as well as nine oxygenated and nine non-oxygenated chlorinated organic products. Major oxygenated products were cis- and trans-2,3-dichlorooxirane (6a, b) and 1,2,2-trichloroethyl formate (13); minor products were e.g., meso and rac bis(1,2,2-trichloroethyl) ether (11c, d) and dichloromethyl 1,2,2-trichloroethyl ether (12). The mode of formation of all products is rationalized by a unified reaction scheme.

scholarly journals Activation of waste tire char by cyclic liquid-phase oxidation

2014 ◽  
Vol 127 ◽  
pp. 157-162 ◽  
Author(s):  
F. Heras ◽  
D. Jimenez-Cordero ◽  
M.A. Gilarranz ◽  
N. Alonso-Morales ◽  
J.J. Rodriguez
Keyword(s):  
Liquid Phase ◽  
Liquid Phase Oxidation ◽  
Waste Tire ◽  
Phase Oxidation

Liquid-phase oxidation of ethylamine to acetaldehyde oximes over tungsten-doped zeolites

2017 ◽  
Vol 60 (7) ◽  
pp. 942-949 ◽  
Author(s):  
Jianghong Ding ◽  
Hao Xu ◽  
Haihong Wu ◽  
Peng Wu
Keyword(s):  
Liquid Phase ◽  
Liquid Phase Oxidation ◽  
Phase Oxidation

Cobalt pivalate complex as a catalyst for liquid phase oxidation of n-hexane

2015 ◽  
Vol 89 (9) ◽  
pp. 1519-1522 ◽  
Author(s):  
I. F. Moskovskaya ◽  
A. A. Maerle ◽  
N. V. Shvydkiy ◽  
B. V. Romanovsky ◽  
I. I. Ivanova
Keyword(s):  
Liquid Phase ◽  
Liquid Phase Oxidation ◽  
Phase Oxidation
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