Translational freezing in free jet expansions, with special reference to molecular beam formation
A theoretical model is described which can be used to calculate the velocity distribution function in the transition region of a free jet expansion. It makes use of a simple mechanism to account for the way in which collisions "perturb" the distribution function which would apply in the absence of collisions. The results are compared with experimental studies of argon beams isolated from free jet sources. If the collision frequency is calculated using a hard sphere collision cross section of (25 ± 5) Å2, good agreement with experimental beam intensity profiles is obtained. In the transition region computed values of the bulk mass velocity, and of the parallel and perpendicular temperatures, are intermediate between the values which would be found if the flow were collision-dominated or free molecular. In particular the perpendicular temperature varies slowly from a dependence on the −4/3 power of the distance from the source, approaching monotonically a −2 power dependence at large distances.