Magnetic study of the hexachlororhodate(IV) ion

1968 ◽  
Vol 46 (22) ◽  
pp. 3591-3594 ◽  
Author(s):  
A. D. Westland
Keyword(s):  
Electron Spin Resonance ◽  
Electron Spin ◽  
Coupling Parameter ◽  
Host Lattice ◽  
Spin Orbit Coupling ◽  
Spin Orbit ◽  
Magnetic Susceptibilities ◽  
Spin Resonance ◽  
Powder Samples ◽  
Splitting Parameter

The magnetic susceptibilities and electron spin resonance spectra of solid solutions of cesium hexachlororhodate(IV) in a diamagnetic host lattice were examined over a range of temperatures. The Landé splitting parameter, g, was found to be 1.7545 ± 0.0005. This led to an orbital delocalization factor of 0.81 and a spin-orbit coupling parameter of 554 cm−1. The susceptibility measurements failed to reveal any superexchange in the lattice but the electron spin resonance spectra gave some evidence for such coupling. Powder samples only were examined and these exhibited no hyperfine structure.

Spin-orbit coupling effects in the quantum Hall regime probed by electron spin resonance

2018 ◽  
Vol 98 (24) ◽  
Author(s):  
A. V. Shchepetilnikov ◽  
D. D. Frolov ◽  
Yu. A. Nefyodov ◽  
I. V. Kukushkin ◽  
L. Tiemann ◽  
...  
Keyword(s):  
Electron Spin Resonance ◽  
Electron Spin ◽  
Quantum Hall ◽  
Orbit Coupling ◽  
Spin Orbit Coupling ◽  
Spin Orbit ◽  
Coupling Effects ◽  
Quantum Hall Regime ◽  
Spin Resonance ◽  
Hall Regime

Microscopic Study of Metal Hydrides using Electron Spin resonance

1980 ◽  
Vol 3 ◽  
Author(s):  
E. L. Venturini
Keyword(s):  
Electron Spin Resonance ◽  
Electron Spin ◽  
Metal Hydrides ◽  
Esr Spectra ◽  
Spectroscopic Technique ◽  
Host Lattice ◽  
Hydrogen Ions ◽  
Spin Resonance ◽  
Symmetry Phase ◽  
Paramagnetic Ions

ABSTRACTElectron spin resonance (ESR) of dilute paramagnetic ions in nonmagnetic metallic hydrides provides microscopic information about the hydrogen ions in the immediate vicinity of the impurity. By comparing ESR spectra for different host metals and several hydrogen/metal ratios, one can determine material properties including host lattice symmetry, phase boundaries and occupation of available sites by hydrogen. Examples are presented of ESR of dilute Er in group IIIB and IVB metal hydrides, demonstrating the sensitivity and versatility of ESR as a spectroscopic technique.

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