Essential oils and their constituents. XLII. Isomerization of epoxides on active alumina

1968 ◽  
Vol 46 (21) ◽  
pp. 3419-3419 ◽  
Author(s):  
Ishwar C. Nigam ◽  
Leo Levi

not available

1968 ◽  
Vol 46 (11) ◽  
pp. 1944-1947 ◽  
Author(s):  
Ishwar C. Nigam ◽  
Leo Levi

When chromatographed on active alumina, epoxides isomerize yielding chiefly the corresponding α,β-unsaturated alcohols. Side reactions were observed in some cases. Limonene oxide yielded cis-1 (7), 8 p-menthadien-ol-2, cis- and trans-carveol, perillyl alcohol, trans-8p-menthene-diol-1,2, and cis- and trans-dihydrocarvone. α-Pinene oxide was converted to pinocarveol, cis- and trans-pinocamphone, campholenic aldehyde and an unidentified alcohol. Caryophyllene oxide yielded three isomeric unsaturated alcohols which were converted to a ketone of known structure.


1963 ◽  
Vol 35 (5) ◽  
pp. 5-0 ◽  
Author(s):  
James A. Rogers
Keyword(s):  

1980 ◽  
Vol 19 (5) ◽  
pp. 1537-1539 ◽  
Author(s):  
W Campbell
Keyword(s):  

2007 ◽  
Vol 38 (3) ◽  
pp. 25
Author(s):  
MARY ANN MOON
Keyword(s):  

Planta Medica ◽  
2008 ◽  
Vol 74 (09) ◽  
Author(s):  
T Milošević ◽  
N Nićiforović ◽  
V Mihailović ◽  
S Solujić ◽  
N Vuković

Planta Medica ◽  
2009 ◽  
Vol 75 (09) ◽  
Author(s):  
M Niculae ◽  
M Spînu ◽  
D Şandru ◽  
F Brudaşcă ◽  
D Cadar ◽  
...  

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