Electron spin resonance studies of radiation damage. Part II. Gamma-irradiated single crystals of sodium chlorate: The ClO3 radical

1968 ◽  
Vol 46 (10) ◽  
pp. 1818-1819 ◽  
Author(s):  
P. F. Patrick ◽  
F. P. Sargent
Keyword(s):  
Electron Spin Resonance ◽  
Radiation Damage ◽  
Single Crystals ◽  
Electron Spin ◽  
Sodium Chlorate ◽  
Spin Resonance ◽  
Gamma Irradiated

Single crystals of sodium chlorate were gamma irradiated and examined by e.s.r. at −196 °C. One of the species present was identified as ClO3.

Electron spin resonance studies of radiation damage. Part III. Gamma irradiated acetonitrile

1970 ◽  
Vol 48 (11) ◽  
pp. 1780-1781 ◽  
Author(s):  
F. P. Sargent
Keyword(s):  
Electron Spin Resonance ◽  
Radiation Damage ◽  
Electron Spin ◽  
Thermal Decay ◽  
Spin Resonance ◽  
Gamma Irradiated

The effects of photobleaching and thermal decay at 77 and 87 °K on the electron spin resonance spectra of gamma irradiated acetonitrile are reported.

Electron spin resonance studies of radiation damage. Part I. An alternating linewidth effect for the (CH3)2ĊOH radical in gamma-irradiated acetone at low temperatures

1968 ◽  
Vol 46 (6) ◽  
pp. 1029-1031 ◽  
Author(s):  
F. P. Sargent
Keyword(s):  
Electron Spin Resonance ◽  
Temperature Dependence ◽  
Radiation Damage ◽  
Electron Spin ◽  
Low Temperatures ◽  
Methyl Groups ◽  
Oh Groups ◽  
Restricted Rotation ◽  
Spin Resonance ◽  
Gamma Irradiated

The e.s.r. spectrum of the (CH3)2ĊOH radical showed a drastic temperature dependence of linewidth in the range −196 to −100 °C, this being particularly pronounced for the M1 = ±2 lines. Possible mechanisms are discussed in terms of restricted rotation of the methyl groups and of the OH groups.

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